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Mechanical Properties and Corrosion Behaviour of Nanostructured Cu-rich CuNi Electrodeposited Films
Varea Espelt, Aïda (Universitat Autònoma de Barcelona. Departament de Física)
Suriñach, Santiago (Suriñach Cornet) (Universitat Autònoma de Barcelona. Departament de Física)

Data: 2012
Resum: Nanocrystalline Cu-rich CuNi alloy thin films (with copper content ranging from 22 to 97 at%) have been grown by electrodeposition, using galvanostatic conditions in an electrolytic bath containing Ni and Cu sulphates with a [Ni(II)]/[Cu(II)] molar ratio of 11. The Cu content is tuned by varying the applied current density during deposition. The nanoscrystalline nature of Cu-rich CuNi thin films has been achieved using saccharine as a grain refinement agent, although for high Cu content (> 90 at%) the refinement effect is less pronounced. Due to the nanocrystalline character of the films, low surface roughness, good compactness, and outstanding mechanical properties (e. g. nanoindentation hardness values off approximately 7 GPa) are obtained, particularly for Cu percentages below 70 at%. The presence of stacking faults also contributes to the observed high strength. The films show good corrosion protective behaviour in a 3. 5 wt% NaCl medium, with corrosion potentials more positive than the bare substrate (pure-Cu) and lower corrosion current density values ranging from 1. 8 to 5. 4 [mi]A/square centimeters.
Nota: Número d'acord de subvenció MINECO/MAT2011-27380-C02-01
Nota: Número d'acord de subvenció AGAUR/2009/SGR-1292
Drets: Tots els drets reservats.
Llengua: Anglès.
Document: article ; publishedVersion
Matèria: Nanoestructures
Publicat a: International journal of electrochemical science, Vol. 7, N. 2 (2012) , p. 1288-1302, ISSN 1452-3981

15 p, 770.0 KB

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