2025-11-13
14:53 |
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37 p, 4.2 MB |
Mechanistic Insights and Technical Challenges in Sulfur-Based Batteries : A Comprehensive In Situ/Operando Monitoring Toolbox
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Yu, Jing (Institut de Recerca en Energia de Catalunya) ;
Pinto-Huguet, Ivan (Institut Català de Nanociència i Nanotecnologia) ;
Zhang, Chao Yue (Lanzhou University) ;
Zhou, Yingtang (Zhejiang Ocean University) ;
Xu, Yaolin (Helmholtz-Zentrum Berlin für Materialien und Energie) ;
Vizintin, Alen (National Institute of Chemistry) ;
Velasco-Vélez, Juan-Jesús (ALBA Laboratori de Llum de Sincrotró) ;
Qi, Xueqiang (Chongqing University of Technology) ;
Pan, Xiaobo (Lanzhou University) ;
Oney, Gozde (Univ. Grenoble Alpes) ;
Olgo, Annabel (Univ. Grenoble Alpes) ;
Märker, Katharina (Univ. Grenoble Alpes) ;
M. Da Silva, Leonardo (Federal University of Jequitinhonha e Mucuri) ;
Luo, Yufeng (Hong Kong Polytechnic University) ;
Lu, Yan (Helmholtz-Zentrum Berlin für Materialien und Energie) ;
Huang, Chen (Universitat de Barcelona) ;
Härk, Eneli (Helmholtz-Zentrum Berlin für Materialien und Energie) ;
Fleming, Joe (Coventry University) ;
Chenevier, Pascale (Univ. Grenoble Alpes) ;
Cabot i Codina, Andreu (Institut de Recerca en Energia de Catalunya) ;
Bai, Yunfei (Lanzhou University) ;
Botifoll, Marc (Institut Català de Nanociència i Nanotecnologia) ;
Black Serra, Ashley Phillip (Institut de Ciència de Materials de Barcelona) ;
An, Qi (Yunnan University) ;
Amietszajew, Tazdin (Coventry University) ;
Arbiol i Cobos, Jordi (Institut Català de Nanociència i Nanotecnologia)
Batteries based on sulfur cathodes offer a promising energy storage solution due to their potential for high performance, cost-effectiveness, and sustainability. However, commercial viability is challenged by issues such as polysulfide migration, volume changes, uneven phase nucleation, limited ion transport, and sluggish sulfur redox kinetics. [...]
2024 -  10.1021/acsenergylett.4c02703
ACS energy letters, Vol. 9, Issue 12 (December 2024) , p. 6178-6214
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2025-11-11
15:45 |
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15 p, 5.6 MB |
Promoting Electrochemical Reactions with Dual-Atom Catalysts for High-Rate Lithium-Sulfur Batteries
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Yu, Jing (Institut Català de Nanociència i Nanotecnologia) ;
Usoltsev, Oleg (ALBA Laboratori de Llum de Sincrotró) ;
Martynova, Irina (Institut de Recerca en Energia de Catalunya) ;
Huang, Cheng (Universitat de Barcelona) ;
Liang, Zhifu (College of Ocean Science and Engineering. Shanghai Maritime University) ;
Pinto-Huguet, Ivan (Institut Català de Nanociència i Nanotecnologia) ;
Li, Canhuang (Institut de Recerca en Energia de Catalunya) ;
Lu, Liqiang (Helmholtz-Zentrum Berlin für Materialien und Energie) ;
Zhang, Chaoqi (Fuzhou University) ;
Lu, Xuan (Institut de Recerca en Energia de Catalunya) ;
Gupta, Kapil (Institut Català de Nanociència i Nanotecnologia) ;
Botifoll, Marc (Institut Català de Nanociència i Nanotecnologia) ;
Simonelli, Laura (ALBA Laboratori de Llum de Sincrotró) ;
Fauth, François (ALBA Laboratori de Llum de Sincrotró) ;
Zhou, Jin Yuan (Lanzhou University) ;
Llorca, Jordi (Universitat Politècnica de Catalunya) ;
Lu, Yan (Helmholtz-Zentrum Berlin für Materialien und Energie) ;
Zhang, Chao Yue (University of California) ;
Arbiol i Cobos, Jordi (Institut Català de Nanociència i Nanotecnologia) ;
Cabot i Codina, Andreu (Institut de Recerca en Energia de Catalunya)
Sulfur cathodes offer a promising solution for high-energy-density, cost-effective, and sustainable energy storage. However, their practical application is limited by sluggish and complex multistep sulfur redox reactions (SRRs), involving both electrochemical and chemical processes. [...]
2025 - 10.1002/adma.202511345
Advanced materials, (September 2025) , art. e11345
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2025-10-21
06:05 |
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12 p, 2.5 MB |
Tuning Li occupancy and local structures for advanced Co-free Ni-rich positive electrodes
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Li, Hang (Institute for Applied Materials) ;
Liu, Hao (Institute for Applied Materials) ;
Luo, Shunrui (Institut Català de Nanociència i Nanotecnologia) ;
Arbiol i Cobos, Jordi (Institut Català de Nanociència i Nanotecnologia) ;
Suard, Emmanuelle (Institute Laue-Langevin) ;
Bergfeldt, Thomas (Institute for Applied Materials) ;
Missyul, Alexander (ALBA Laboratori de Llum de Sincrotró) ;
Baran, Volodymyr (Deutsches Elektronen-Synchrotron) ;
Mangold, Stefan (Institute for Photon Science and Synchrotron Radiation) ;
Zhang, Yongchao (Institut Català de Nanociència i Nanotecnologia) ;
Hua, Weibo (Xi'an Jiaotong University) ;
Knapp, Michael (Institute for Applied Materials) ;
Ehrenberg, Helmut (Institute for Applied Materials) ;
Pan, Feng (Peking University Shenzhen Graduate School) ;
Indris, Sylvio (Université Mohammed VI Polytechnique)
Structure evolution and surface reactivity have long been regarded as the most crucial points for studying Ni-rich positive electrodes for Li-ion batteries. Unfortunately, the influence of Li occupancy as a single factor on electro-chemomechanical stability has been overlooked and is missing, owing to the challenge of Li determination in the lattice. [...]
2025 - 10.1038/s41467-025-57063-7
Nature communications, Vol. 16 (March 2025) , art. 2203
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2025-09-30
07:39 |
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12 p, 7.3 MB |
Merging and Clipping Nets for the Synthesis of Three- and Two-Merged Net Metal-Organic Frameworks
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Yang, Yunhui (Institut Català de Nanociència i Nanotecnologia) ;
Fernández-Seriñán, Pilar (Universitat Autònoma de Barcelona. Departament de Química) ;
Ortín-Rubio, Borja (Institut Català de Nanociència i Nanotecnologia) ;
Samanta, Partha (Universitat Autònoma de Barcelona. Departament de Química) ;
Gándara, Felipe (Instituto de Ciencia de Materiales de Madrid) ;
Proserpio, Davide M. (Università degli Studi di Milano) ;
Nam, Dongsik (Institut Català de Nanociència i Nanotecnologia) ;
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ;
Imaz, Inhar (Universitat Autònoma de Barcelona. Departament de Química) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein, we report how merging and clipping nets in metal-organic frameworks (MOFs) can be controlled in a single-crystal-to-single-crystal fashion using three different approaches-the merged net, clip-off chemistry, and linker reinstallation-to design and synthesize three- and two-merged net MOFs. [...]
2025 - 10.1021/jacs.4c15936
Journal of the American Chemical Society, Vol. 147, Issue 1 (January 2025) , p. 1344-1355
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2025-09-23
02:28 |
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7 p, 3.4 MB |
Isolation of the Secondary Building Unit of a 3D Metal-Organic Framework through Clip-Off Chemistry, and Its Reuse To Synthesize New Frameworks by Dynamic Covalent Chemistry
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Nam, Dongsik (Institut Català de Nanociència i Nanotecnologia) ;
Albalad Alcala, Jorge (Universitat Autònoma de Barcelona. Departament de Química) ;
Sánchez-Naya, Roberto (Universitat Autònoma de Barcelona. Departament de Química) ;
Ruiz-Relaño, Sara (Universitat Autònoma de Barcelona. Departament de Química) ;
Cortés-Martínez, Alba (Institut Català de Nanociència i Nanotecnologia) ;
Yang, Yunhui (Institut Català de Nanociència i Nanotecnologia) ;
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein, we present a novel methodology for synthesizing metal clusters or secondary building units (SBUs) that are subsequently employed to construct innovative metal-organic frameworks (MOFs) via dynamic covalent chemistry. [...]
2024 - 10.1021/jacs.4c09077
Journal of the American Chemical Society, Vol. 146, Issue 40 (September 2024) , p. 27255-27261
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2025-06-30
14:57 |
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14 p, 7.2 MB |
Trace elements, maturation processes and diagenesis in human deciduous incisors
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Martirosyan, Ani (Universitat Autònoma de Barcelona. Departament de Biologia Animal, de Biologia Vegetal i d'Ecologia) ;
Jordana Comín, Xavier (Universitat Autònoma de Barcelona. Departament de Biologia Animal, de Biologia Vegetal i d'Ecologia) ;
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ;
Cotte, Marine (European Synchrotron Radiation Facility) ;
Molist, Núria (Museu d'Arqueologia de Catalunya) ;
Irurita Olivares, Javier (Universidad de Granada. Departamento de Medicina Legal, Toxicología y Antropología Física) ;
Pereira dos Santos, Cristina Maria (Universitat Autònoma de Barcelona. Departament de Biologia Animal, de Biologia Vegetal i d'Ecologia) ;
Malgosa Morera, Assumpció (Universitat Autònoma de Barcelona. Departament de Biologia Animal, de Biologia Vegetal i d'Ecologia) ;
Mahoney, Patrick (University of Kent) ;
Molera, Judith (Universitat de Vic)
Post-mortem alteration of trace elements can complicate the interpretation of original biogenic signals related to diet, environment and enamel maturation processes. This study describes gradients in element concentrations for modern and archaeological deciduous incisor teeth to identify diagenetic variations in specific elements. [...]
2025 - 10.1016/j.jas.2025.106274
Journal of archaeological science, Vol. 180 (August 2025) ,art. 106274
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2025-06-06
09:33 |
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12 p, 9.5 MB |
Electronic Structure Dimensionality of the Quantum-Critical Ferromagnet YbNi4 P2
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Dai, Ji (ALBA Laboratori de Llum de Sincrotró) ;
Antezak, Alexandre (Centre National de la Recherche Scientifique. Université Paris-Saclay) ;
Broad, W. (University of Bristol. HH Wills Physics Laboratory) ;
Thees, Maximilian (Centre National de la Recherche Scientifique. Université Paris-Saclay) ;
Zatko, V. (Institut Català de Nanociència i Nanotecnologia) ;
Bouwmeester, Rosa Luca (University of Twente. MESA+ Institute for Nanotechnology) ;
Fortuna, F. (Centre National de la Recherche Scientifique. Université Paris-Saclay) ;
Le Fèvre, Patrick (Centre National de la Recherche Scientifique. Université de Rennes) ;
Rault, J.E. (Synchrotron SOLEIL (France)) ;
Horiba, K. (High Energy Accelerator Research Organization (KEK). Institute of Materials Structure Science (Japan)) ;
Vyalikh, Denis (IKERBASQUE. Basque Foundation for Science) ;
Kumigashira, Hiroshi (High Energy Accelerator Research Organization (KEK). Institute of Materials Structure Science (Japan)) ;
Kliemt, Kristin (Goethe-Universität Frankfurt. Physikalisches Institut) ;
Friedemann, Sven (University of Bristol. HH Wills Physics Laboratory) ;
Krellner, Cornelius (Goethe-Universität Frankfurt. Physikalisches Institut) ;
Frantzeskakis, Emmanouil (Centre National de la Recherche Scientifique. Université Paris-Saclay) ;
Santander-Syro, A.F. (Centre National de la Recherche Scientifique. Université Paris-Saclay)
YbNi4P2 is the first known ferromagnetic metal showing a second-order quantum phase transition. Current theoretical understanding rules out second-order ferromagnetic quantum criticality in centrosymmetric two- and three-dimensional (2D and 3D) metals. [...]
2025 - 10.1103/PhysRevLett.134.126401
Physical review letters, Vol. 134, Issue 12 (March 2025) , art. 126401
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2025-06-05
07:17 |
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17 p, 6.8 MB |
Tailoring the Lithium Concentration in Thin Lithium Ferrite Films Obtained by Dual Ion Beam Sputtering
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Prieto Vives, Pilar 1965- (Universidad Autónoma de Madrid) ;
Hernández-Gómez, Cayetano (Universidad Autónoma de Madrid) ;
Román-Sánchez, Sara (Instituto de Cerámica y Vidrio (CSIC)) ;
París Ogáyar, Marina (Universidad Autónoma de Madrid) ;
Gorni, Giulio (ALBA Laboratori de Llum de Sincrotró) ;
Prieto, José Emilio (Instituto de Química Física Blas Cabrera) ;
Serrano, Aida (Departamento de Electrocerámica, Instituto de Cerámica y Vidrio)
Thin films of lithium spinel ferrite, LiFeO, have attracted much scientific attention because of their potential for efficient excitation, the manipulation and propagation of spin currents due to their insulating character, high-saturation magnetization, and Curie temperature, as well as their ultra-low damping value. [...]
2024 - 10.3390/nano14141220
Nanomaterials, Vol. 14, Num. 14 (July 2024) , art. 1220
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2025-06-04
06:12 |
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15 p, 9.7 MB |
Beam Effects in Synchrotron Radiation Operando Characterization of Battery Materials : X-Ray Diffraction and Absorption Study of LiNi0.33Mn0.33Co0.33O2 and LiFePO4 Electrodes
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Black Serra, Ashley Phillip (Institut de Ciència de Materials de Barcelona) ;
Escudero, Carlos (ALBA Laboratori de Llum de Sincrotró) ;
Fauth, François (ALBA Laboratori de Llum de Sincrotró) ;
Fehse, Marcus (Alianza Vasca de Investigación y Tecnología. Centro de Investigación Cooperativa en Energías Alternativas (CIC energiGUNE)) ;
Agostini, Giovanni (ALBA Laboratori de Llum de Sincrotró) ;
Reynaud, Marine (Alianza Vasca de Investigación y Tecnología. Centro de Investigación Cooperativa en Energías Alternativas (CIC energiGUNE)) ;
Houdeville, Raphaelle G. (Institut de Ciència de Materials de Barcelona) ;
Chatzogiannakis, Dimitrios (Institut de Ciència de Materials de Barcelona) ;
Orive, Joseba (Alianza Vasca de Investigación y Tecnología. Centro de Investigación Cooperativa en Energías Alternativas (CIC energiGUNE)) ;
Ramo-Irurre, Alejandro (Institut de Ciència de Materials de Barcelona) ;
Casas-Cabanas, Montse (IKERBASQUE. Basque Foundation for Science) ;
Palacín, M. Rosa (Institut de Ciència de Materials de Barcelona)
Operando synchrotron radiation-based techniques are a precious tool in battery research, as they enable the detection of metastable intermediates and ensure characterization under realistic cycling conditions. [...]
2024 - 10.1021/acs.chemmater.4c00597
Chemistry of materials, Vol. 36, Issue 11 (June 2024) , p. 5596-5610
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2025-05-19
14:34 |
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12 p, 4.5 MB |
Magneto-Ionic Engineering of Antiferromagnetically RKKY-Coupled Multilayers
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Ma, Zheng (Universitat Autònoma de Barcelona. Departament de Física) ;
Arredondo-López, Aitor (Universitat Autònoma de Barcelona. Departament de Física) ;
Wrona, Jerzy (Singulus Technologies AG (Alemanya)) ;
Herrero-Martín, Javier (ALBA Laboratori de Llum de Sincrotró) ;
Langer, Juergen (Singulus Technologies AG (Alemanya)) ;
Berthold, Ocker (Singulus Technologies AG (Alemanya)) ;
Pellicer Vilà, Eva Maria (Universitat Autònoma de Barcelona. Departament de Física) ;
Menéndez Dalmau, Enric (Universitat Autònoma de Barcelona. Departament de Física) ;
Sort Viñas, Jordi (Universitat Autònoma de Barcelona. Departament de Física)
Voltage-driven ion motion offers a powerful means to modulate magnetism and spin phenomena in solids, a process known as magneto-ionics, which holds great promise for developing energy-efficient next-generation micro- and nano-electronic devices. [...]
2025 - 10.1002/adma.202415393
Advanced materials, Vol. 37, Issue 19 (May 2025) , art. 2415393
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