382238eead6d3ce31ed998bd08a0d2a9 materials_2017v10n1p43.pdf 1d0737293c5d00f082df606590eb8aa329b37b92 materials_2017v10n1p43.pdf b6af1d3eea180463b5bbba0c77929be15fa3a56bc2ca5f049cebf8c37b23e44a materials_2017v10n1p43.pdf Title: Electrochemical Synthesis of Bismuth Particles: Tuning Particle Shape through Substrate Type within a Narrow Potential Window Subject: Bismuth (Bi) electrodeposition was studied on Si/Ti/Au, FTO-, and ITO-coated glasses from acidic nitrate solutions with and without gluconate within a narrow potential window (E = 80 mV). This potential range was sufficient to observe a change in particle shape, from polyhedrons (including hexagons) to dendrites, the trend being slightly different depending on substrate activity. In all cases, though, the formation of dendrites was favoured as the applied potential was made more negative. Bi particles were more uniformly distributed over the substrate when sodium gluconate was added to the electrolyte. X-ray diffraction analyses of dendrites grown at -0.28 V indicated that they exhibit the rhombohedral phase of Bi and are predominantly oriented along the (003) plane. This orientation is exacerbated at the lowest applied potential (-0.20 V vs. Ag|AgCl) on glass/ITO substrate, for which completed and truncated hexagons are observed from the top view scanning electron microscopy images. Keywords: bismuth; electrodeposition; X-ray diffraction Author: Doga Bilican, Jordina Fornell, Jordi Sort and Eva Pellicer Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.15 CreationDate: Fri Jan 6 17:10:49 2017 ModDate: Fri Jan 6 17:10:49 2017 Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 10 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 6380120 bytes Optimized: no PDF version: 1.5 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- IYLDYI+URWPalladioL-Ital Type 1 Custom yes yes no 57 0 SFNOAC+URWPalladioL-Bold Type 1 Custom yes yes no 58 0 PFSSQX+URWPalladioL-Roma Type 1 Custom yes yes no 59 0 ROWTUD+PazoMath Type 1 Builtin yes yes no 60 0 OJYQXC+CMSY10 Type 1 Builtin yes yes no 61 0 YOTXCC+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 66 0 SHEBIB+EURM10 Type 1 Builtin yes yes no 98 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 117 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 118 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 119 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 120 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 121 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 163 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 164 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 165 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 166 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 167 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 205 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 206 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 207 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 208 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 209 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 235 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 236 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 237 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 238 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 239 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 270 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 271 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 272 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 273 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 274 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 310 0 CFAAHH+Calibri CID TrueType Identity-H yes yes yes 311 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 312 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 313 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 314 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 315 0 HYYHEA+CMBSY10 Type 1 Builtin yes yes no 353 0 CEPJIM+PalatinoLinotype CID TrueType Identity-H yes yes yes 358 0 CFABMB+TimesNewRoman,Bold TrueType WinAnsi yes yes no 359 0 CEPJJM+PalatinoLinotype TrueType WinAnsi yes yes no 360 0 CEPJNN+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 361 0 CEPJON+PalatinoLinotype,Bold CID TrueType Identity-H yes yes yes 362 0 CEPJOO+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 363 0 CEPKDN+Symbol CID TrueType Identity-H yes yes yes 364 0 CEPKIN+TimesNewRoman TrueType WinAnsi yes yes no 365 0 JJBTPS+URWPalladioL-BoldItal Type 1 Custom yes yes no 402 0 IHGURL+EURM7 Type 1 Builtin yes yes no 403 0 edu.harvard.hul.ois.jhove.module.pdf.PdfMalformedException: Invalid object number or object stream at edu.harvard.hul.ois.jhove.module.PdfModule.getObject(PdfModule.java:2356) at edu.harvard.hul.ois.jhove.module.PdfModule.resolveIndirectObject(PdfModule.java:2292) at edu.harvard.hul.ois.jhove.module.PdfModule.readDocCatalogDict(PdfModule.java:1284) at edu.harvard.hul.ois.jhove.module.PdfModule.parse(PdfModule.java:525) at edu.harvard.hul.ois.jhove.JhoveBase.processFile(JhoveBase.java:825) at edu.harvard.hul.ois.jhove.JhoveBase.process(JhoveBase.java:614) at edu.harvard.hul.ois.jhove.JhoveBase.dispatch(JhoveBase.java:465) at Jhove.main(Jhove.java:296) Jhove (Rel. 1.6, 2011-01-04) Date: 2017-02-15 02:25:52 CET RepresentationInformation: materials_2017v10n1p43.pdf ReportingModule: BYTESTREAM, Rel. 1.3 (2007-04-10) LastModified: 2017-02-14 15:30:34 CET Size: 6380120 Format: bytestream Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/octet-stream Checksum: 5387fd48 Type: CRC32 Checksum: 382238eead6d3ce31ed998bd08a0d2a9 Type: MD5 Checksum: 1d0737293c5d00f082df606590eb8aa329b37b92 Type: SHA-1