382238eead6d3ce31ed998bd08a0d2a9 pmc_28772402.pdf 1d0737293c5d00f082df606590eb8aa329b37b92 pmc_28772402.pdf b6af1d3eea180463b5bbba0c77929be15fa3a56bc2ca5f049cebf8c37b23e44a pmc_28772402.pdf Title: Electrochemical Synthesis of Bismuth Particles: Tuning Particle Shape through Substrate Type within a Narrow Potential Window Subject: Bismuth (Bi) electrodeposition was studied on Si/Ti/Au, FTO-, and ITO-coated glasses from acidic nitrate solutions with and without gluconate within a narrow potential window (E = 80 mV). This potential range was sufficient to observe a change in particle shape, from polyhedrons (including hexagons) to dendrites, the trend being slightly different depending on substrate activity. In all cases, though, the formation of dendrites was favoured as the applied potential was made more negative. Bi particles were more uniformly distributed over the substrate when sodium gluconate was added to the electrolyte. X-ray diffraction analyses of dendrites grown at -0.28 V indicated that they exhibit the rhombohedral phase of Bi and are predominantly oriented along the (003) plane. This orientation is exacerbated at the lowest applied potential (-0.20 V vs. Ag|AgCl) on glass/ITO substrate, for which completed and truncated hexagons are observed from the top view scanning electron microscopy images. Keywords: bismuth; electrodeposition; X-ray diffraction Author: Doga Bilican, Jordina Fornell, Jordi Sort and Eva Pellicer Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.15 CreationDate: Fri Jan 6 10:10:49 2017 CET ModDate: Fri Jan 6 10:10:49 2017 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 10 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 6380120 bytes Optimized: no PDF version: 1.5 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- IYLDYI+URWPalladioL-Ital Type 1 Custom yes yes no 57 0 SFNOAC+URWPalladioL-Bold Type 1 Custom yes yes no 58 0 PFSSQX+URWPalladioL-Roma Type 1 Custom yes yes no 59 0 ROWTUD+PazoMath Type 1 Builtin yes yes no 60 0 OJYQXC+CMSY10 Type 1 Builtin yes yes no 61 0 YOTXCC+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 66 0 SHEBIB+EURM10 Type 1 Builtin yes yes no 98 0 CEPJIM+PalatinoLinotype CID 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