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Item: Title: Structural and electrical characterization. Item: Title: Acknowledgements Item: Title: Figure 1 (a) XRD θ-2θ scans of the BTO/LNO/CeO2/YSZ/Si(001) series. Item: Title: Figure 2 Dependence with the deposition temperature of BTO on LNO/CeO2/YSZ/Si(001) of (a) intensity ratio between the BTO(002) and YSZ(002) peaks (black circles, left axis), and full width at half maximum of the 2θ- scan (red squares, right axis), and ω-s Item: Title: Figure 3 Topographic AFM images, 5 μm × 5 μm in size (inset: 1 μm × 1 μm) of the (a) Ts = 375 °C (z-scale: 7 nm), (b) Ts = 400 °C (z-scale: 40 nm), and (c) Ts = 700 °C (z-scale: 7 nm) BTO films on LNO/CeO2/YSZ/Si(001). Item: Title: Figure 4 (a) Ferroelectric polarization loops of the Ts = 425 °C, 550 °C, 650 °C and 750 °C BTO films on LNO/CeO2/YSZ/Si(001), with the current (I) – electric field (E) curve corresponding to the Ts = 425 °C sample in the inset. Item: Title: Figure 5 (a) Leakage current curves of the BTO films on LNO/CeO2/YSZ/Si(001). Item: Title: Figure 6 Schematics of the influence of the deposition temperature on the crystallinity and properties of BaTiO3 thin films on LNO/CeO2/YSZ/Si(001). Item: Title: Figure 7 Dependence with the deposition temperature of the photocurrent (left axis, open black squares) and the out-of-plane lattice parameter (right axis, solid blue triangles). Item: Title: Figure 8 (a) XRD θ-2θ scans of the films deposited on LNO/LaAlO3(001) at Ts = 550 °C (black line) and Ts = 675 °C (red line). 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