c724af349ee500d35680b8914c56d4f5 coatings_a2019v9p189.pdf b55b3ec499d602ab65616047260c6ac5cca03218 coatings_a2019v9p189.pdf f8db1766c599b56b56be6f2dc0767627561952d06bc30573a05bd5aa8abed004 coatings_a2019v9p189.pdf Title: Electrodeposition of Nanocrystalline Fe-P Coatings: Influence of Bath Temperature and Glycine Concentration on Structure, Mechanical and Corrosion Behavior Subject: A detailed electrochemical study and investigation of a Fe-P glycine bath as a function of the temperature and glycine concentrations and current density, and their resulting corrosion and mechanical behavior is presented. A low addition of glycine to the electrolyte led to a drastic increase of the P content. At low Fe-P deposition rates, heterogeneous rough deposits with morphological bumps and pores were observed. By increasing the Fe-P deposition rate, the number of pores were reduced drastically, resulting in smooth coatings. Increasing the P content led to the formation of nanocrystalline grains from an “amorphous-like” state. Coatings with higher P contents exhibited better corrosion resistance and hardening, most likely attributed to grain boundary strengthening. Keywords: electrodeposition; iron-phosphorous alloys; temperature; glycine additive; corrosion; hardness; friction; wear Author: Natalia Kovalska, Natalia Tsyntsaru, Henrikas Cesiulis, Annet Gebert, Jordina Fornell, Eva Pellicer, Jordi Sort, Wolfgang Hansal and Wolfgang Kautek Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.18 CreationDate: Wed Mar 13 11:28:15 2019 CET ModDate: Wed Mar 13 11:28:15 2019 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 12 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 3810498 bytes Optimized: no PDF version: 1.5 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- IOOWZW+URWPalladioL-Ital Type 1 Custom yes yes no 74 0 BPVCWQ+URWPalladioL-Bold Type 1 Custom yes yes no 75 0 GKLSCY+URWPalladioL-Roma Type 1 Custom yes yes no 76 0 MWHIBA+VnURWPalladioL Type 1 Custom yes yes no 77 0 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