e44e3ec5fc3c03e468457ac28e4fabb2 molecules_a2019v24p4169.pdf 0db3e93f54daa582b51228fe98ee32ae77d248b5 molecules_a2019v24p4169.pdf 9cce1bbb2b04e7d91d44d2bb2fb11a4996cdb163d1c9a0637d40d93fdc5a287b molecules_a2019v24p4169.pdf Title: Isonicotinamide-Based Compounds: From Cocrystal to Polymer Subject: The reaction between [Cu(-OAc)(-Pip)(MeOH)]2 (1) (OAc = acetate; Pip = 1,3-benzodioxole- 5-carboxylate) and isonicotinamide (Isn) in MeOH as solvent yielded two mixture pairs of three compounds: {(HPip)2(Isn) (2), [Cu(Pip)2(Isn)2] (3)} and {(3), {[Cu3(Pip)2(OAc)2(-Isn)2(Isn)2(- OCH3)2(MeOH)2]2MeOH}n (4)}. Modifying the reaction conditions (t, T, molar ratio), 2 and 3 have been successfully isolated, whereas 3 and 4 had to be mechanically separated. The recrystallization of 3 in pentanol yielded single crystals of compound [Cu(Pip)2(Isn)2]C5H11OH (3a). The X-ray crystal structure of 2, 3a, and 4 has been elucidated showing a cocrystal, a monomer, and an unusual coordination polymer, respectively. The Pip ligand exhibited a chelate (3a) or a monodentate (4) coordination mode, but the Isonicotinamide (Isn) ligand is the one that promoted the arrangement of different structures and also mainly directs the formation of the 2D and 3D supramolecular assemblies. All the structures have been analyzed by Hirshfeld surface. In addition, the energy frameworks and lattice energy values of 2 and 3a have been calculated. Keywords: cocrystal; Cu(II) compounds; isonicotinamide; amide–amide pattern; coordination polymer Author: Francisco Sánchez-Férez, Daniel Ejarque, Teresa Calvet, Mercè Font-Bardia and Josefina Pons Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.18 CreationDate: Sun Nov 17 11:27:24 2019 CET ModDate: Sun Nov 17 11:27:24 2019 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 18 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 4656715 bytes Optimized: no PDF version: 1.5 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- LOZQEC+URWPalladioL-Ital Type 1 Custom yes yes no 84 0 WVXTJS+URWPalladioL-Bold Type 1 Custom yes yes no 85 0 YOPIAK+VnURWPalladioL-Bold Type 1 Custom yes yes no 86 0 ZZPVGP+URWPalladioL-Roma Type 1 Custom yes yes no 87 0 BQOZAH+VnURWPalladioL Type 1 Custom yes yes no 88 0 NAUELZ+Pxsy Type 1 Builtin yes yes no 89 0 GGBCKI+Rpxr Type 1 Builtin yes yes no 90 0 DRHBDF+EURM10 Type 1 Builtin yes yes no 91 0 PUSVWS+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 96 0 MCBCCI+SourceSansRoman-Regular Type 1C Custom yes yes no 113 0 MCBCCM+SourceSansRoman.613wght Type 1C Custom yes yes no 114 0 MCBCCO+SourceSansRoman-Bold Type 1C Custom yes yes no 115 0 MPUDFL+PazoMath Type 1 Builtin yes yes no 154 0 VMKUOR+URWPalladioL-BoldItal Type 1 Custom yes yes no 155 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 189 0 EODBFF+CambriaMath CID TrueType Identity-H yes yes yes 190 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 191 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 192 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 193 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 194 0 EODAGK+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 195 0 VGNVUX+Rpxb Type 1 Builtin yes yes no 239 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 257 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 258 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 259 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 260 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 261 0 EODAGK+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 262 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 289 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 290 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 291 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 292 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 293 0 EODAGK+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 294 0 EODIAN+Symbol Type 1C Custom yes yes yes 336 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 337 0 EODBFF+CambriaMath CID TrueType Identity-H yes yes yes 338 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 339 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 340 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 341 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 342 0 EODAGK+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 343 0 UIKTCS+Pxbsy Type 1 Builtin yes yes no 394 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 402 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 403 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 404 0 EOCOMA+PalatinoLinotype,Bold CID TrueType Identity-H yes yes yes 405 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 406 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 407 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 444 0 EODBFF+CambriaMath CID TrueType Identity-H yes yes yes 445 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 446 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 447 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 448 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 449 0 EODAGK+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 450 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 497 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 498 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 499 0 EOCOMA+PalatinoLinotype,Bold CID TrueType Identity-H yes yes yes 500 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 501 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 502 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 541 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 542 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 543 0 EOCOMA+PalatinoLinotype,Bold CID TrueType Identity-H yes yes yes 544 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 545 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 546 0 CZKGAS+CMR10 Type 1 Builtin yes yes no 588 0 SJRYNK+Pxex Type 1 Builtin yes yes no 589 0 EOCODP+PalatinoLinotype CID TrueType Identity-H yes yes yes 595 0 EODBFF+CambriaMath CID TrueType Identity-H yes yes yes 596 0 EOCOEA+PalatinoLinotype TrueType WinAnsi yes yes no 597 0 EOCOLP+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 598 0 EOCOMB+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 599 0 EOCPLM+TimesNewRoman CID TrueType Identity-H yes yes yes 600 0 EODAGK+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 601 0 UATPUP+Rpxmi Type 1 Builtin yes yes no 650 0 BFHCIC+Rpxi Type 1 Builtin yes yes no 651 0 VSHNAE+Rpcxr Type 1 Builtin yes yes no 716 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2020-02-26 05:33:40 CET RepresentationInformation: molecules_a2019v24p4169.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2020-01-14 11:31:31 CET Size: 4656715 Format: PDF Version: 1.5 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 0 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: ViewerPreferences: HideToolbar: false HideMenubar: false HideWindowUI: false FitWindow: true CenterWindow: false DisplayDocTitle: false NonFullScreenPageMode: UseNone Direction: L2R ViewArea: CropBox ViewClip: CropBox PrintArea: CropBox PageClip: CropBox PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: ぉのぴひはつふっぴどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸲ Item: Title: げづびふぬぴびぜ〴ぜ〰ちのつぜ〴ぜ〰いどびっふびびどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮ㄩ‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴ぜ〰はてぜ〴ぜ〰ぃはっひべびぴちぬぜ〴ぜ〰〲ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㈩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〲ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㌩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴ぜ〰はてぜ〴ぜ〰ぴとづぜ〴ぜ〰ぃははひつどのちぴどはのぜ〴ぜ〰ぃはねばぬづへづびぜ〴ぜ〰〳ぜ〴ぜ〰ちのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㐩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〳ちぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㘩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Children: Item: Title: こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴ぜ〰はてぜ〴ぜ〰ぃはっひべびぴちぬぜ〴ぜ〰〲ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㈩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〲ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㌩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴ぜ〰はてぜ〴ぜ〰ぴとづぜ〴ぜ〰ぃははひつどのちぴどはのぜ〴ぜ〰ぃはねばぬづへづびぜ〴ぜ〰〳ぜ〴ぜ〰ちのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㐩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〳ちぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㘩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: ぃひべびぴちぬぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〲ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㌩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴ぜ〰はてぜ〴ぜ〰ぴとづぜ〴ぜ〰ぃははひつどのちぴどはのぜ〴ぜ〰ぃはねばぬづへづびぜ〴ぜ〰〳ぜ〴ぜ〰ちのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㐩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〳ちぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㘩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴ぜ〰はてぜ〴ぜ〰ぴとづぜ〴ぜ〰ぃははひつどのちぴどはのぜ〴ぜ〰ぃはねばぬづへづびぜ〴ぜ〰〳ぜ〴ぜ〰ちのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㐩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〳ちぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㘩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〳ちぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㘩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰ぃはねばはふのつぜ〴ぜ〰〴ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㘩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: えどひびとてづぬつぜ〴ぜ〰こふひてちっづびぜ〴ぜ〰ぁのちぬべびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぅのづひでべぜ〴ぜ〰うひちねづぷはひにびぜ〴ぜ〰ぃちぬっふぬちぴどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: ぃはのっぬふびどはのびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸴ Item: Title: ぅへばづひどねづのぴちぬぜ〴ぜ〰こづっぴどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸵ Item: Title: ぃひべびぴちぬぬはでひちばとどっぜ〴ぜ〰いちぴちぜ〴〩਼㰠⽓ 䝯呯 䐠⡴慢汥⹣慰瑩潮⸱㜩‾㸊⡜㌷㙜㌷㝜〰げづてづひづのっづび Item: Title: げづてづひづのっづび Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: UIKTCS+Pxbsy FontSubset: true FirstChar: 14 LastChar: 14 FontDescriptor: FontName: UIKTCS+Pxbsy Flags: Symbolic FontBBox: 5, -978, 1382, 913 FontFile: true Font: BaseFont: UATPUP+Rpxmi FontSubset: true FirstChar: 11 LastChar: 22 FontDescriptor: FontName: UATPUP+Rpxmi Flags: Symbolic FontBBox: -70, -289, 949, 802 FontFile: true Font: BaseFont: BFHCIC+Rpxi FontSubset: true FirstChar: 124 LastChar: 124 FontDescriptor: FontName: BFHCIC+Rpxi Flags: Symbolic FontBBox: -162, -280, 856, 733 FontFile: true Font: BaseFont: CZKGAS+CMR10 FontSubset: true FirstChar: 40 LastChar: 61 FontDescriptor: FontName: CZKGAS+CMR10 Flags: Symbolic FontBBox: -40, -250, 1009, 750 FontFile: true Font: BaseFont: VSHNAE+Rpcxr FontSubset: true FirstChar: 169 LastChar: 169 FontDescriptor: FontName: VSHNAE+Rpcxr Flags: Symbolic FontBBox: -212, -286, 1344, 973 FontFile: true Font: BaseFont: SJRYNK+Pxex FontSubset: true FirstChar: 88 LastChar: 88 FontDescriptor: FontName: SJRYNK+Pxex Flags: Symbolic FontBBox: -5, -3116, 1694, 792 FontFile: true Font: BaseFont: VGNVUX+Rpxb FontSubset: true FirstChar: 61 LastChar: 62 FontDescriptor: FontName: VGNVUX+Rpxb Flags: Symbolic FontBBox: -57, -266, 932, 729 FontFile: true Font: BaseFont: LOZQEC+URWPalladioL-Ital FontSubset: true FirstChar: 40 LastChar: 122 FontDescriptor: FontName: LOZQEC+URWPalladioL-Ital Flags: Symbolic FontBBox: -170, -305, 1010, 941 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: WVXTJS+URWPalladioL-Bold FontSubset: true FirstChar: 2 LastChar: 197 FontDescriptor: FontName: WVXTJS+URWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: YOPIAK+VnURWPalladioL-Bold FontSubset: true FirstChar: 161 LastChar: 178 FontDescriptor: FontName: YOPIAK+VnURWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: ZZPVGP+URWPalladioL-Roma FontSubset: true FirstChar: 1 LastChar: 252 FontDescriptor: FontName: ZZPVGP+URWPalladioL-Roma Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: BQOZAH+VnURWPalladioL FontSubset: true FirstChar: 146 LastChar: 226 FontDescriptor: FontName: BQOZAH+VnURWPalladioL Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: NAUELZ+Pxsy FontSubset: true FirstChar: 0 LastChar: 48 FontDescriptor: FontName: NAUELZ+Pxsy Flags: Symbolic FontBBox: -21, -994, 1292, 912 FontFile: true Font: BaseFont: GGBCKI+Rpxr FontSubset: true FirstChar: 11 LastChar: 124 FontDescriptor: FontName: GGBCKI+Rpxr Flags: Symbolic FontBBox: -40, -283, 904, 728 FontFile: true Font: BaseFont: MPUDFL+PazoMath FontSubset: true FirstChar: 68 LastChar: 68 FontDescriptor: FontName: MPUDFL+PazoMath Flags: Symbolic FontBBox: -40, -283, 878, 946 FontFile: true Font: BaseFont: DRHBDF+EURM10 FontSubset: true FirstChar: 11 LastChar: 34 FontDescriptor: FontName: DRHBDF+EURM10 Flags: Symbolic FontBBox: -32, -243, 1060, 720 FontFile: true Font: BaseFont: VMKUOR+URWPalladioL-BoldItal FontSubset: true FirstChar: 50 LastChar: 72 FontDescriptor: FontName: VMKUOR+URWPalladioL-BoldItal Flags: Symbolic FontBBox: -170, -300, 1073, 935 FontFile: true EncodingDictionary: Differences: true Pages: Page: Sequence: 1 Annotations: Annotation: Subtype: Link Rect: 75, 757, 219, 793 Annotation: Subtype: Link Rect: 474, 757, 519, 793 Annotation: Subtype: Link Rect: 192, 660, 203, 674 Annotation: Subtype: Link Rect: 282, 660, 293, 674 Annotation: Subtype: Link Rect: 149, 647, 160, 660 Annotation: Subtype: Link Rect: 466, 532, 518, 551 Annotation: Subtype: Link Rect: 395, 235, 402, 244 ActionDest: 668 Annotation: Subtype: Link Rect: 403, 235, 410, 244 ActionDest: 668 Annotation: Subtype: Link Rect: 165, 208, 172, 217 ActionDest: 668 Annotation: Subtype: Link Rect: 172, 208, 179, 217 ActionDest: 668 Annotation: Subtype: Link Rect: 509, 195, 516, 204 ActionDest: 668 Annotation: Subtype: Link Rect: 160, 168, 167, 177 ActionDest: 668 Annotation: Subtype: Link Rect: 168, 168, 175, 177 ActionDest: 668 Annotation: Subtype: Link Rect: 197, 100, 204, 109 ActionDest: 668 Annotation: Subtype: Link Rect: 275, 87, 282, 96 ActionDest: 668 Annotation: Subtype: Link Rect: 175, 38, 272, 50 Annotation: Subtype: Link Rect: 395, 38, 519, 50 Page: Sequence: 2 Annotations: Annotation: Subtype: Link Rect: 155, 715, 167, 725 ActionDest: 668 Annotation: Subtype: Link Rect: 167, 715, 179, 725 ActionDest: 668 Annotation: Subtype: Link Rect: 464, 688, 476, 698 ActionDest: 668 Annotation: Subtype: Link Rect: 476, 688, 488, 698 ActionDest: 691 Annotation: Subtype: Link Rect: 426, 661, 438, 671 ActionDest: 691 Annotation: Subtype: Link Rect: 113, 607, 125, 617 ActionDest: 691 Annotation: Subtype: Link Rect: 126, 607, 138, 617 ActionDest: 691 Annotation: Subtype: Link Rect: 277, 540, 289, 549 ActionDest: 691 Annotation: Subtype: Link Rect: 292, 540, 304, 549 ActionDest: 691 Annotation: Subtype: Link Rect: 395, 526, 407, 535 ActionDest: 691 Annotation: Subtype: Link Rect: 407, 526, 419, 535 ActionDest: 691 Annotation: Subtype: Link Rect: 465, 486, 477, 495 ActionDest: 691 Annotation: Subtype: Link Rect: 477, 486, 489, 495 ActionDest: 691 Annotation: Subtype: Link Rect: 299, 432, 311, 441 ActionDest: 691 Annotation: Subtype: Link Rect: 446, 361, 453, 373 ActionDest: 182 Annotation: Subtype: Link Rect: 177, 258, 189, 267 ActionDest: 691 Annotation: Subtype: Link Rect: 189, 258, 201, 267 ActionDest: 691 Annotation: Subtype: Link Rect: 451, 190, 463, 199 ActionDest: 691 Page: Sequence: 3 Annotations: Annotation: Subtype: Link Rect: 436, 742, 448, 752 ActionDest: 691 Annotation: Subtype: Link Rect: 107, 634, 119, 644 ActionDest: 691 Annotation: Subtype: Link Rect: 411, 142, 418, 151 ActionDest: 668 Annotation: Subtype: Link Rect: 419, 142, 431, 151 ActionDest: 691 Annotation: Subtype: Link Rect: 293, 128, 305, 138 ActionDest: 691 Page: Sequence: 4 Annotations: Annotation: Subtype: Link Rect: 404, 740, 411, 752 ActionDest: 235 Annotation: Subtype: Link Rect: 349, 715, 361, 725 ActionDest: 691 Annotation: Subtype: Link Rect: 250, 500, 262, 509 ActionDest: 691 Annotation: Subtype: Link Rect: 472, 473, 484, 482 ActionDest: 691 Annotation: Subtype: Link Rect: 510, 443, 517, 455 ActionDest: 235 Annotation: Subtype: Link Rect: 108, 430, 115, 442 ActionDest: 249 Annotation: Subtype: Link Rect: 326, 419, 338, 428 ActionDest: 691 Annotation: Subtype: Link Rect: 510, 376, 517, 388 ActionDest: 235 Annotation: Subtype: Link Rect: 109, 362, 116, 374 ActionDest: 249 Page: Sequence: 5 Annotations: Annotation: Subtype: Link Rect: 359, 475, 366, 487 ActionDest: 249 Annotation: Subtype: Link Rect: 437, 461, 444, 473 ActionDest: 249 Page: Sequence: 6 Annotations: Annotation: Subtype: Link Rect: 124, 675, 136, 684 ActionDest: 713 Annotation: Subtype: Link Rect: 347, 621, 359, 630 ActionDest: 691 Annotation: Subtype: Link Rect: 251, 540, 263, 549 ActionDest: 713 Annotation: Subtype: Link Rect: 423, 454, 430, 466 ActionDest: 328 Annotation: Subtype: Link Rect: 256, 402, 268, 412 ActionDest: 713 Annotation: Subtype: Link Rect: 268, 402, 280, 412 ActionDest: 713 Annotation: Subtype: Link Rect: 400, 103, 412, 112 ActionDest: 713 Annotation: Subtype: Link Rect: 412, 103, 424, 112 ActionDest: 713 Annotation: Subtype: Link Rect: 104, 73, 111, 85 ActionDest: 391 Page: Sequence: 7 Annotations: Annotation: Subtype: Link Rect: 508, 517, 515, 529 ActionDest: 391 Annotation: Subtype: Link Rect: 503, 436, 510, 448 ActionDest: 391 Annotation: Subtype: Link Rect: 405, 422, 412, 434 ActionDest: 391 Page: Sequence: 8 Annotations: Annotation: Subtype: Link Rect: 110, 693, 118, 705 ActionDest: 436 Annotation: Subtype: Link Rect: 234, 653, 241, 665 ActionDest: 436 Annotation: Subtype: Link Rect: 137, 612, 144, 624 ActionDest: 436 Annotation: Subtype: Link Rect: 250, 168, 257, 180 ActionDest: 489 Annotation: Subtype: Link Rect: 162, 157, 174, 166 ActionDest: 691 Annotation: Subtype: Link Rect: 136, 143, 148, 153 ActionDest: 713 Page: Sequence: 9 Annotations: Annotation: Subtype: Link Rect: 205, 378, 217, 387 ActionDest: 713 Annotation: Subtype: Link Rect: 503, 351, 515, 360 ActionDest: 713 Annotation: Subtype: Link Rect: 302, 321, 309, 333 ActionDest: 489 Page: Sequence: 10 Annotations: Annotation: Subtype: Link Rect: 110, 713, 117, 725 ActionDest: 532 Annotation: Subtype: Link Rect: 502, 686, 509, 698 ActionDest: 532 Annotation: Subtype: Link Rect: 263, 645, 270, 657 ActionDest: 532 Annotation: Subtype: Link Rect: 308, 645, 315, 657 ActionDest: 532 Annotation: Subtype: Link Rect: 401, 101, 413, 110 ActionDest: 713 Page: Sequence: 11 Annotations: Annotation: Subtype: Link Rect: 109, 280, 116, 292 ActionDest: 584 Annotation: Subtype: Link Rect: 109, 253, 115, 265 ActionDest: 584 Annotation: Subtype: Link Rect: 153, 240, 160, 252 ActionDest: 584 Annotation: Subtype: Link Rect: 227, 186, 234, 200 ActionDest: 584 Page: Sequence: 12 Annotations: Annotation: Subtype: Link Rect: 496, 265, 508, 275 ActionDest: 713 Page: Sequence: 13 Annotations: Annotation: Subtype: Link Rect: 224, 261, 236, 271 ActionDest: 691 Annotation: Subtype: Link Rect: 236, 262, 248, 271 ActionDest: 691 Page: Sequence: 14 Page: Sequence: 15 Annotations: Annotation: Subtype: Link Rect: 274, 688, 286, 698 ActionDest: 713 Annotation: Subtype: Link Rect: 346, 645, 353, 657 ActionDest: 647 Annotation: Subtype: Link Rect: 184, 621, 196, 630 ActionDest: 713 Annotation: Subtype: Link Rect: 197, 621, 209, 630 ActionDest: 713 Annotation: Subtype: Link Rect: 324, 621, 336, 630 ActionDest: 713 Page: Sequence: 16 Annotations: Annotation: Subtype: Link Rect: 331, 740, 518, 751 Annotation: Subtype: Link Rect: 186, 407, 223, 417 Annotation: Subtype: Link Rect: 252, 381, 290, 391 Annotation: Subtype: Link Rect: 403, 367, 519, 378 Annotation: Subtype: Link Rect: 97, 354, 237, 365 Annotation: Subtype: Link Rect: 332, 328, 369, 339 Annotation: Subtype: Link Rect: 150, 303, 187, 313 Annotation: Subtype: Link Rect: 213, 278, 250, 288 Annotation: Subtype: Link Rect: 480, 212, 516, 223 Annotation: Subtype: Link Rect: 255, 135, 292, 146 Annotation: Subtype: Link Rect: 273, 96, 311, 107 Annotation: Subtype: Link Rect: 298, 70, 336, 81 Page: Sequence: 17 Annotations: Annotation: Subtype: Link Rect: 200, 728, 238, 738 Annotation: Subtype: Link Rect: 297, 688, 334, 699 Annotation: Subtype: Link Rect: 100, 663, 137, 673 Annotation: Subtype: Link Rect: 136, 625, 174, 635 Annotation: Subtype: Link Rect: 318, 585, 355, 596 Annotation: Subtype: Link Rect: 370, 559, 407, 570 Annotation: Subtype: Link Rect: 458, 533, 496, 544 Annotation: Subtype: Link Rect: 255, 482, 293, 493 Annotation: Subtype: Link Rect: 100, 405, 137, 415 Annotation: Subtype: Link Rect: 242, 366, 280, 376 Annotation: Subtype: Link Rect: 145, 328, 183, 338 Annotation: Subtype: Link Rect: 355, 301, 393, 312 Annotation: Subtype: Link Rect: 202, 263, 240, 273 Annotation: Subtype: Link Rect: 238, 186, 275, 196 Annotation: Subtype: Link Rect: 245, 160, 282, 170 Annotation: Subtype: Link Rect: 326, 120, 363, 131 Annotation: Subtype: Link Rect: 181, 95, 219, 105 Annotation: Subtype: Link Rect: 329, 69, 367, 80 Page: Sequence: 18 Annotations: Annotation: Subtype: Link Rect: 414, 688, 451, 699 Annotation: Subtype: Link Rect: 207, 651, 245, 661 Annotation: Subtype: Link Rect: 251, 651, 287, 661 Annotation: Subtype: Link Rect: 145, 625, 183, 635 Annotation: Subtype: Link Rect: 332, 598, 370, 609 Annotation: Subtype: Link Rect: 232, 547, 269, 557 Annotation: Subtype: Link Rect: 410, 521, 447, 531 Annotation: Subtype: Link Rect: 207, 483, 245, 493 Annotation: Subtype: Link Rect: 200, 418, 238, 428 Annotation: Subtype: Link Rect: 100, 392, 137, 402 Annotation: Subtype: Link Rect: 470, 366, 508, 376 Annotation: Subtype: Link Rect: 379, 327, 416, 338 Annotation: Subtype: Link Rect: 290, 301, 385, 312 Annotation: Subtype: Link Rect: 76, 259, 166, 290 Annotation: Subtype: Link Rect: 234, 253, 407, 264 Checksum: f8f0f5b9 Type: CRC32 Checksum: e44e3ec5fc3c03e468457ac28e4fabb2 Type: MD5 Checksum: 0db3e93f54daa582b51228fe98ee32ae77d248b5 Type: SHA-1