90644719512491d3242fecd38315b974 pmc_32830762.pdf 5d729c78d511c56db542f7e9df5046be0dc275af pmc_32830762.pdf de97b3f81bfe6a0114be424a0d66ed301076a6ffaa5ab7f2aba63e80073ae62e pmc_32830762.pdf Title: Pristine and hydrated fluoroapatite (0001) Creator: pdftk 1.44 - www.pdftk.com Producer: International Union of Crystallography CreationDate: ModDate: Fri Oct 4 12:01:31 2019 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 9 Encrypted: no Page size: 609.675 x 793.701 pts Page rot: 0 File size: 1479098 bytes Optimized: yes PDF version: 1.4 /usr/bin/iconv: illegal input sequence at position 482 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- JLPPMK+AdvOpti-B Type 1C WinAnsi yes yes no 118 0 JLPPMM+AdvOpti-R Type 1C WinAnsi yes yes no 120 0 JLPPMO+AdvOpti-I Type 1C WinAnsi yes yes no 122 0 JLPPNG+Advt93-r Type 1C MacRoman yes yes no 124 0 JLPPNM+Advt93-i Type 1C WinAnsi yes yes 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work is licensed under a <a rel="license" href="http://creativecommons.org/licenses/by/2.0/uk/">Creative Commons Attribution 2.0 UK: England & Wales License</a>. This work is licensed under a <a rel="license" href="http://creativecommons.org/licenses/by/2.0/uk/">Creative Commons Attribution 2.0 UK: England & Wales License</a>. 2019-09-10 true 10.1107/S2052520619010412 10.1107/S2052520619010412 noindex 2019-09-10 true iucr.org iucr.org 10.1107/S2052520619010412 VoR doi:10.1107/S2052520619010412 Acta Cryst (2019). B75, 830-838 [doi:10.1107/S2052520619010412] research papers application/pdf Pristine and hydrated fluoroapatite (0001) en The surface structure of fluoro­apatite (0001) (FAp0001) under quasi-dry and humid conditions has been probed with surface X-ray diffraction (SXRD). Lateral and perpendicular atomic relaxations corresponding to the FAp0001 termination before and after H2O exposure and the location of the adsorbed water molecules have been determined from experimental analysis of the crystal truncation rod (CTR) intensities. The surface under dry conditions exhibits a bulk termination with relaxations in the outermost atomic layers. The hydrated surface is formed by a disordered partially occupied H2O layer containing one water molecule (33% surface coverage) adsorbed at each of the three surface Ca atoms, and is coupled with one OH group randomly bonded to each of the three topmost P atoms with a 33% surface coverage. 2019-09-10 International Union of Crystallography FLUOROAPATITE (0001) WATER INTERFACE SURFACE STRUCTURE MINERALOGY SURFACE X-RAY DIFFRACTION Torrelles, X. Nadeem, I.M. Kupka, A. Crespo-Villanueva, A. Meis, S. Gies, H. 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