A                 10000
                                                                                                                                                B     10000




                                                                                                                                                                                                                                                                              AGGs
                                                                                                                                   AGGs
                                         HCP1-H6                    MCP3-H6                    PLD-H6 **

                        1000                                                                                                                                 1000
                                                                              430.29                             **                                                                                  Heating                                               Cooling




                                                                                                                                                                                                                                                                              MPs
                                                                                                                                   MPs
                Size (nm)




                                                                                                                                                 Size (nm)
                                                                                                                                                                                                                                                   48.94         52.29
                            100                                                                                                                               100                              23.69                             *                  ** *             *
                                       29.49
                                                                                                                                                                                               * * *




                                                                                                                                                                                                                                                                              NPs
                                                                                                                                   NPs
                                                                                                                                                                                                *
                                       8.65                                          8.52
                             10                                                                                                                                     10            3.71




                                                                                                                                                                                                                                                                              BBs
                                                                                                                                   BBs
                                                                                                3.96
                                       3.95
                              1                                                            x                                                                            1

  C                  10000
                                   0                     20
                                                     Temperature (ºC)
                                                                                                40                           60
                                                                                                                                                D     10000
                                                                                                                                                                                  37 40 45 50 55 60 65 70 37 25 10
                                                                                                                                                                                                        Temperature (ºC)



                                                                                                                                   AGGs




                                                                                                                                                                                                                                                                              AGGs
                            1000                                                                                                                             1000
                                                                              430.29
                                                                                                                       *            MPs




                                                                                                                                                                                                                                                                              MPs
                Size (nm)




                                                                                                                                                 Size (nm)
                             100                                                                                                                              100
                                                                                                                                                                                  33.75                                                     27.88
                                                                                                                                    NPs




                                                                                                                                                                                                                                                                              NPs
                                                                                          45.85
                              10                                                                                                                                    10
                                                                                                                                                                                  8.69                                                        8.32
                                                                                                                                    BBs




                                                                                                                                                                                                                                                                              BBs
                                               + ZnCl2                                                                                                                                    + ZnCl2
                               1                                                            x                                                                           1                                                              x
                                   0                      20                                    40                           60
  E
                                                                                                                                                                             0                            20                                       40                    60
                                                         Temperature (ºC)                                                                                                                               Temperature (ºC)
           1000                                                                                                                  1000                                                                                   1000                                             *
                                                                                                                                                                                               MPs




                                                                                                                                                                                                                                                                                 MPs
                                                                                                                 MPs




                                                                                                                                                                                                                                                                       281.3
                                                                                                                                                                                                                                                                   *
                                                                                                                                                                                                                                                                 132.1
                100                                                                                                                     100                             *           *                                        100
                                                                                                                                                                                  49.9
                                                                                                                            Size (nm)
    Size (nm)




                                                                                                                                                                                                                Size (nm)

                                                                                                    *                                                              44.9
                                                                                                                                                                                               NPs




                                                                                                                                                                                                                                                                                 NPs
                                                                                                                 NPs




                                                                                      *          34.9
                                                                         *           23.6                                                       27.8
                                                                     14.7
                                    *
                                   8.6
                   10                                                                                                                    10                                                                                      10
                                                                                                                                                                                                                                               4.1
                                                                                                                                                                                               BBs




                                                                                                                                                                                                                                                                                 BBs
                                                                                                                 BBs




                       1                                                                                                                  1                                                                                            1


F          355
                                                ZnCl2 (mM)
                                                                                                                355
                                                                                                                                                 ZnCl2 (mM)
                                                                                                                                                                                                                355              365
                                                                                                                                                                                                                                                    ZnCl2 (mM)

                                                                                                                                                                                                                                 360
CSM (nm)




                                                                                                     CSM (nm)




                                                                                                                                                                                                     CSM (nm)




                                                                                                                                                                                                                                 355


                                                                                                                                                                                                                                 350


                                                                                                                                                                                                                                 345
                                                                                                                                                                                                                                       20     40     60     80
           350                                                                                                  350                                          360
                                                                                                                                                                                                                350
                                                         365


                                                         360
                                                                                                                                                             355

                                                         355
                                                                                                                                                             350
                                                         350

                                   + ZnCl2               345                                                                                                 345
                                                                                                                                                                   20        40     60    80
           345                                                 20        40     60        80
                                                                                                                345                                                                                             345
                      20                  30                        40                         50                     20                   30                           40                     50                           20                       30                40              50
                                         Temperature (ºC)                                                                                 Temperature (ºC)                                                                                         Temperature (ºC)
G                                             Z-Potential                                                                                     Z-Potential                                                                                                 Z-Potential
                             Building blocks Nanoparticles                                                                 Building blocks                      Nanoparticles                                                     Building blocks Nanoparticles
                             -6.376 ± 0.355 -7.906 ± 0.343                                                                 -17.066 ± 1.927                     -13.666 ± 0.371                                                    -13.933 ± 1.166 -11.366 ± 0.566