2e446ac59159b6e39dc803be526e8e66 catalysts_a2020v10n10p1195.pdf be4a2208fa61d27828847deca30a8d6d5fdf2bbf catalysts_a2020v10n10p1195.pdf 4c039a5e2f064ce1eee0de3c36404415240d645197bea53e1c7ae1044ac271ce catalysts_a2020v10n10p1195.pdf Title: Rhodium Nanoparticles Stabilized by PEG-Tagged Imidazolium Salts as Recyclable Catalysts for the Hydrosilylation of Internal Alkynes and the Reduction of Nitroarenes Subject: PEGylated imidazolium (bromide and tetrafluoroborate) and tris-imidazolium (bromide) salts containing triazole linkers have been used as stabilizers for the preparation of water-soluble rhodium(0) nanoparticles by reduction of rhodium trichloride with sodium borohydride in water at room temperature. The nanomaterials have been characterized (Transmission Electron Microscopy, Electron Diffraction, X-ray Photoelectron Spectroscopy, Inductively Coupled Plasma-Optical Emission Spectroscopy). They proved to be efficient and recyclable catalysts for the stereoselective hydrosilylation of internal alkynes, in the presence or absence of solvent, and in the reduction of nitroarenes to anilines with ammonia-borane as hydrogen donor in aqueous medium (1:4 tetrahydrofuran/water). Keywords: alkynes; catalysis; hydrosilylation; nitroarenes; recycling; reduction; rhodium nanoparticles Author: Guillem Fernández and Roser Pleixats Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.18 CreationDate: Tue Oct 20 16:50:55 2020 CEST ModDate: Tue Oct 20 16:57:45 2020 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 18 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 8717949 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- VAUHDS+URWPalladioL-Ital Type 1 Custom yes yes no 10 0 RPMKYT+URWPalladioL-Bold Type 1 Custom yes yes no 15 0 NTRZDY+URWPalladioL-Roma Type 1 Custom yes yes no 19 0 QANVCD+Rpxr Type 1 Builtin yes yes no 23 0 LEVXPH+EURM10 Type 1 Builtin yes yes no 27 0 AIQCCL+VnURWPalladioL-Bold Type 1 Custom yes yes no 31 0 SXQPWE+VnURWPalladioL Type 1 Custom yes yes no 36 0 CGDLTM+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 44 0 MCBCCI+SourceSansRoman-Regular Type 1C Custom yes yes no 66 0 MCBCCM+SourceSansRoman.613wght Type 1C Custom yes yes no 70 0 MCBCCO+SourceSansRoman-Bold Type 1C Custom yes yes no 74 0 XYBOVT+Rpxb Type 1 Builtin yes yes no 93 0 AHFNNV+Pxsy Type 1 Builtin yes yes no 97 0 WCJNTK+URWPalladioL-BoldItal Type 1 Custom yes yes no 119 0 *Minion Pro-849-Identity-H CID Type 0C Identity-H yes no yes 150 0 *Tahoma-848-Identity-H CID Type 0C Identity-H yes no yes 156 0 *Minion Pro-Identity-H CID Type 0C Identity-H yes no yes 162 0 *Times New Roman-Italic-847-Identity-H CID Type 0C Identity-H yes no yes 168 0 *Times New Roman-846-Identity-H CID Type 0C Identity-H yes no yes 174 0 NZPZOQ+Pxbsy Type 1 Builtin yes yes no 295 0 XLLNJL+VnURWPalladioL-Italic Type 1 Custom yes yes no 459 0 GBLQZB+Rpxi Type 1 Builtin yes yes no 496 0 VSHNAE+Rpcxr Type 1 Builtin yes yes no 506 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2020-11-18 07:09:25 CET RepresentationInformation: catalysts_a2020v10n10p1195.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2020-11-17 11:11:00 CET Size: 8717949 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 743 FreeObjects: 89 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Children: Item: Title: Preparation and Characterization of Rhodium Nanoparticles Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: Hydrosilylation of Alkynes under Catalysis by Rhodium Nanoparticles Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: Reduction of Nitroarenes under Catalysis by Rhodium Nanoparticles Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Children: Item: Title: General Remarks Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: General Procedure for the Preparation of Rh NPs (M1A, Table 1, Entry 1) Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Item: Title: General Procedure for the Hydrosilylation of Alkynes by Rh NPs under Neat Conditions (Method A) Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1a3869f4 Item: Title: General Procedure for the Hydrosilylation of Alkynes by Rh NPs in THF (Method B) Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@a38d7a3 Item: Title: General Procedure for the Reduction of Nitroarenes by Rh NPs with Ammonia Borane Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77f99a05 Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@63440df3 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@3aeaafa6 Info: Title: Rhodium Nanoparticles Stabilized by PEG-Tagged Imidazolium Salts as Recyclable Catalysts for the Hydrosilylation of Internal Alkynes and the Reduction of Nitroarenes Author: Guillem Fernández and Roser Pleixats Subject: PEGylated imidazolium (bromide and tetrafluoroborate) and tris-imidazolium (bromide) salts containing triazole linkers have been used as stabilizers for the preparation of water-soluble rhodium(0) nanoparticles by reduction of rhodium trichloride with sodium borohydride in water at room temperature. The nanomaterials have been characterized (Transmission Electron Microscopy, Electron Diffraction, X-ray Photoelectron Spectroscopy, Inductively Coupled Plasma-Optical Emission Spectroscopy). They proved to be efficient and recyclable catalysts for the stereoselective hydrosilylation of internal alkynes, in the presence or absence of solvent, and in the reduction of nitroarenes to anilines with ammonia-borane as hydrogen donor in aqueous medium (1:4 tetrahydrofuran/water). Keywords: alkynes; catalysis; hydrosilylation; nitroarenes; recycling; reduction; rhodium nanoparticles Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.18 CreationDate: Tue Oct 20 16:50:55 CEST 2020 ModDate: Tue Oct 20 16:57:45 CEST 2020 ID: 0xbece27130d8a0fe39931f1d76bf1c172, 0xbece27130d8a0fe39931f1d76bf1c172 Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: AHFNNV+Pxsy FontSubset: true FirstChar: 1 LastChar: 14 FontDescriptor: FontName: AHFNNV+Pxsy Flags: Symbolic FontBBox: -21, -994, 1292, 912 FontFile: true Font: BaseFont: SXQPWE+VnURWPalladioL FontSubset: true FirstChar: 160 LastChar: 243 FontDescriptor: FontName: SXQPWE+VnURWPalladioL Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: NZPZOQ+Pxbsy FontSubset: true FirstChar: 48 LastChar: 48 FontDescriptor: FontName: NZPZOQ+Pxbsy Flags: Symbolic FontBBox: 5, -978, 1382, 913 FontFile: true Font: BaseFont: VAUHDS+URWPalladioL-Ital 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