d4dad4f243a98853e46d102930447c7b pmc_32784822.pdf 011c445f2eec565e939f2fa81dd980960f6577c5 pmc_32784822.pdf c3ca988d4740bff29a32be7213a954be959e81ad08adb5c7f8a39fc202797883 pmc_32784822.pdf Title: Construction of Zn(II) Linear Trinuclear Secondary Building Units from A Coordination Polymer Based on -Acetamidocinnamic Acid and 4-Phenylpyridine Subject: The synthesis and characterization of one coordination polymer and two trinuclear complexes are presented. The coordination polymer [Zn2(-O,O’-ACA)2(ACA)2(4-Phpy)2]n (1) has been obtained by the reaction between Zn(OAc)22H2O, -acetamidocinnamic acid (HACA), and 4-phenylpyridine (4-Phpy) using EtOH as solvent. Its recrystallization in CH3CN or EtOH yields two trinuclear complexes, both having pinwheel arrays with formulas [Zn3(-ACA)6(4-Phpy)2]4CH3CN (24CH3CN) and [Zn3(-ACA)6(EtOH)2]4EtOH (34EtOH), respectively. These trinuclear species, unavoidably lose their solvent co-crystallized molecules at RT yielding the complexes [Zn3(-ACA)6(4-Phpy)2] (2) and [Zn3(-ACA)6(EtOH)2] (3). In addition, compound 2 has also been obtained reacting Zn(OAc)22H2O, HACA, and 4-Phpy in a 1:2:2 ratio using CH3CN as solvent. Compounds 1–3 have been characterized by analytical and spectroscopic techniques. Furthermore, single crystals suitable for X-ray diffraction method for compounds 1, 24CH3CN, and 34EtOH were obtained and their supramolecular interactions have been studied and discussed, showing 2D supramolecular planes for the trinuclear complexes and a 3D supramolecular network for the coordination polymer. Finally, the supramolecular interactions of 24CH3CN and 34EtOH have been compared using Hirshfeld surface analysis and electrostatic potential calculations. Keywords: Zn(II); -acetamidocinnamic acid; coordination polymer; trinuclear complexes; secondary building unit; X-ray crystal structures; hirshfeld surface analysis; electrostatic surface potential Author: Daniel Ejarque, Teresa Calvet, Mercè Font-Bardia and Josefina Pons Creator: LaTeX with hyperref package Producer: pdfTeX-1.40.18 CreationDate: Sun Aug 9 07:42:00 2020 CEST ModDate: Sun Aug 9 07:42:00 2020 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 23 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 5920513 bytes Optimized: no PDF version: 1.5 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- QQPOHV+URWPalladioL-Ital Type 1 Custom yes yes no 96 0 GGOLZP+URWPalladioL-Bold Type 1 Custom yes yes no 97 0 CZOINJ+EURB10 Type 1 Builtin yes yes no 98 0 WYEKQU+VnURWPalladioL-Bold Type 1 Custom yes yes no 99 0 EAIZRS+URWPalladioL-Roma Type 1 Custom 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VSHNAE+Rpcxr Type 1 Builtin yes yes no 764 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2020-11-18 06:15:15 CET RepresentationInformation: pmc_32784822.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2020-09-07 03:36:03 CEST Size: 5920513 Format: PDF Version: 1.5 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 0 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: ViewerPreferences: HideToolbar: false HideMenubar: false HideWindowUI: false FitWindow: true CenterWindow: false DisplayDocTitle: false NonFullScreenPageMode: UseNone Direction: L2R ViewArea: CropBox ViewClip: CropBox PrintArea: CropBox PageClip: CropBox PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: ぉのぴひはつふっぴどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸲ Item: Title: げづびふぬぴびぜ〴ぜ〰ちのつぜ〴ぜ〰いどびっふびびどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮ㄩ‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㈩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰〱ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㌩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰こぴひふっぴふひづびぜ〴ぜ〰〲〴ぃえ〳ぃぎぜ〴ぜ〰ちのつぜ〴ぜ〰〳〴ぅぴくえぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㐩‾㸊⡜㌷㙜㌷㝜〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづびぜ〴ぜ〰はてぜ〴ぜ〰〲〴ぃえ〳ぃぎぜ〴ぜ〰ちのつぜ〴ぜ〰〳〴ぅぴくえぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづぜ〴ぜ〰ぁのちぬべびどびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Children: Item: Title: こべのぴとづびどびぜ〴ぜ〰ちのつぜ〴ぜ〰ぃとちひちっぴづひどぺちぴどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㈩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰ちのつぜ〴ぜ〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづぜ〴ぜ〰はてぜ〴ぜ〰〱ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㌩‾㸊⡜㌷㙜㌷㝜〰ぃひべびぴちぬぜ〴ぜ〰こぴひふっぴふひづびぜ〴ぜ〰〲〴ぃえ〳ぃぎぜ〴ぜ〰ちのつぜ〴ぜ〰〳〴ぅぴくえぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㐩‾㸊⡜㌷㙜㌷㝜〰ぅへぴづのつづつぜ〴ぜ〰こぴひふっぴふひづびぜ〴ぜ〰はてぜ〴ぜ〰〲〴ぃえ〳ぃぎぜ〴ぜ〰ちのつぜ〴ぜ〰〳〴ぅぴくえぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㈮㔩‾㸊⡜㌷㙜㌷㝜〰えどひびとてづぬつぜ〴ぜ〰こふひてちっづぜ〴ぜ〰ぁのちぬべびどびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸳ Item: Title: 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ぅへばづひどねづのぴちぬぜ〴ぜ〰こづっぴどはのぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮ㄩ‾㸊⡜㌷㙜㌷㝜〰きちぴづひどちぬびぜ〴ぜ〰ちのつぜ〴ぜ〰きづぴとはつびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㈩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〲ぜ〵ぜ〰〭く〬くぜ〳ㅜ〰〭ぁぃぁぜ〵ㅜ〰〲ぜ〵ぜ〰ぁぃぁぜ〵ㅜ〰〲ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そのぜ〴ぜ〰ぜ〵ぜ〰〱ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㌩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〲ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㐩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰ぅぴくえぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〳ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸵ Children: Item: Title: きちぴづひどちぬびぜ〴ぜ〰ちのつぜ〴ぜ〰きづぴとはつびぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㈩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〲ぜ〵ぜ〰〭く〬くぜ〳ㅜ〰〭ぁぃぁぜ〵ㅜ〰〲ぜ〵ぜ〰ぁぃぁぜ〵ㅜ〰〲ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そのぜ〴ぜ〰ぜ〵ぜ〰〱ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㌩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〲ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㐩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰ぅぴくえぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〳ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸵ Item: Title: こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〲ぜ〵ぜ〰〭く〬くぜ〳ㅜ〰〭ぁぃぁぜ〵ㅜ〰〲ぜ〵ぜ〰ぁぃぁぜ〵ㅜ〰〲ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そのぜ〴ぜ〰ぜ〵ぜ〰〱ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㌩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〲ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㐩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰ぅぴくえぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〳ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸵ Item: Title: こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰〴〭ぐとばべぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〲ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳畢獥捴楯渮㐮㐩‾㸊⡜㌷㙜㌷㝜〰こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰ぅぴくえぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〳ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸵ Item: Title: こべのぴとづびどびぜ〴ぜ〰はてぜ〴ぜ〰せずの〳ぜ〵ぜ〰〭ぁぃぁぜ〵ㅜ〰〶ぜ〵ぜ〰ぅぴくえぜ〵ㅜ〰〲そぜ〴ぜ〰ぜ〵ぜ〰〳ぜ〵ㅜ〰ぜ〴〩਼㰠⽓ 䝯呯 䐠⡳散瑩潮⸵ Item: Title: じ〭ひちべぜ〴ぜ〰ぃひべびぴちぬぬはでひちばとどっぜ〴ぜ〰いちぴちぜ〴〩਼㰠⽓ 䝯呯 䐠⡴慢汥⹣慰瑩潮⸱㘩‾㸊⡜㌷㙜㌷㝜〰げづてづひづのっづび Item: Title: げづてづひづのっづび Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: QQPOHV+URWPalladioL-Ital FontSubset: true FirstChar: 39 LastChar: 122 FontDescriptor: FontName: QQPOHV+URWPalladioL-Ital Flags: Symbolic FontBBox: -170, -305, 1010, 941 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: 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