dd14f7ee730dcff8d8625fafd714710e catalysts_a2021v11n6p754.pdf 401973468d0ed3bf6ea6da4d9549ab694fd6c905 catalysts_a2021v11n6p754.pdf 682208d938a1a27760aba9da0ef45f066cd3ffe6340461f21b2ba2f981bcd0d1 catalysts_a2021v11n6p754.pdf Title: Light-Driven Hydrogen Evolution Assisted by Covalent Organic Frameworks Subject: Covalent organic frameworks (COFs) are crystalline porous organic polymers built from covalent organic blocks that can be photochemically active when incorporating organic semiconducting units, such as triazine rings or diacetylene bridges. The bandgap, charge separation capacity, porosity, wettability, and chemical stability of COFs can be tuned by properly choosing their constitutive building blocks, by extension of conjugation, by adjustment of the size and crystallinity of the pores, and by synthetic post-functionalization. This review focuses on the recent uses of COFs as photoactive platforms for the hydrogen evolution reaction (HER), in which usually metal nanoparticles (NPs) or metallic compounds (generally Pt-based) act as co-catalysts. The most promising COF-based photocatalytic HER systems will be discussed, and special emphasis will be placed on rationalizing their structure and light-harvesting properties in relation to their catalytic activity and stability under turnover conditions. Finally, the aspects that need to be improved in the coming years will be discussed, such as the degree of dispersibility in water, the global photocatalytic efficiency, and the robustness and stability of the hybrid systems, putting emphasis on both the COF and the metal co-catalyst. Keywords: covalent organic framework; covalent triazine framework; photocatalysis; hydrogen evolution; metal nanoparticle; co-catalyst; Pt-doped COF; bandgap; charge separation; apparent quantum efficiency Author: Nuria Romero, Roger Bofill, Laia Francàs, Jordi García-Antón and Xavier Sala Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Tue Jun 22 05:06:46 2021 CEST ModDate: Tue Jun 22 05:23:10 2021 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 17 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2158185 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- ESYGMN+VnURWPalladioL Type 1 Custom yes yes no 10 0 HIBWHU+URWPalladioL-Ital Type 1 Custom yes yes no 15 0 FJMQMT+URWPalladioL-Bold Type 1 Custom yes yes no 20 0 IWLSJY+URWPalladioL-Roma Type 1 Custom yes yes no 24 0 YUWHZX+CMSY10 Type 1 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edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@44c8afef Item: Title: Crucial Aspects Determining the Photocatalytic Hydrogen Evolution Performance of COF-Mediated Systems Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7b69c6ba Children: Item: Title: Common Synthetic Pathways to Build Efficient and Robust COFs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@46daef40 Item: Title: Secondary Interactions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@12f41634 Item: Title: Electronic Effects Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Children: Item: Title: Charge Separation and Transfer Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Charge Generation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: Stabilization of Key Intermediates Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: Heterojunctions and Encapsulation of COFs with Other Materials Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Choice of Metal Co-Catalyst Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: Final Remarks Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Info: Title: Light-Driven Hydrogen Evolution Assisted by Covalent Organic Frameworks Author: Nuria Romero, Roger Bofill, Laia Francàs, Jordi García-Antón and Xavier Sala Subject: Covalent organic frameworks (COFs) are crystalline porous organic polymers built from covalent organic blocks that can be photochemically active when incorporating organic semiconducting units, such as triazine rings or diacetylene bridges. The bandgap, charge separation capacity, porosity, wettability, and chemical stability of COFs can be tuned by properly choosing their constitutive building blocks, by extension of conjugation, by adjustment of the size and crystallinity of the pores, and by synthetic post-functionalization. This review focuses on the recent uses of COFs as photoactive platforms for the hydrogen evolution reaction (HER), in which usually metal nanoparticles (NPs) or metallic compounds (generally Pt-based) act as co-catalysts. The most promising COF-based photocatalytic HER systems will be discussed, and special emphasis will be placed on rationalizing their structure and light-harvesting properties in relation to their catalytic activity and stability under turnover conditions. Finally, the aspects that need to be improved in the coming years will be discussed, such as the degree of dispersibility in water, the global photocatalytic efficiency, and the robustness and stability of the hybrid systems, putting emphasis on both the COF and the metal co-catalyst. Keywords: covalent organic framework; covalent triazine framework; photocatalysis; hydrogen evolution; metal nanoparticle; co-catalyst; Pt-doped COF; bandgap; charge separation; apparent quantum efficiency Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Tue Jun 22 05:06:46 CEST 2021 ModDate: Tue Jun 22 05:23:10 CEST 2021 ID: 0x458418ce9f3c004ff9e5787350b08f8f, 0x458418ce9f3c004ff9e5787350b08f8f Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: BFLBCP+EURM10 FontSubset: true FirstChar: 11 LastChar: 25 FontDescriptor: FontName: BFLBCP+EURM10 Flags: Symbolic FontBBox: -32, -243, 1060, 720 FontFile: true Font: BaseFont: RSYDPD+VnURWPalladioL-Bold FontSubset: true FirstChar: 160 LastChar: 226 FontDescriptor: FontName: RSYDPD+VnURWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: FJMQMT+URWPalladioL-Bold FontSubset: true FirstChar: 2 LastChar: 121 FontDescriptor: FontName: 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