b3427436066e379b5a99505672fee830 catalysts_a2021v11n8p880.pdf c57fbe159a9dc9d6eecc7082083d2da207f129ff catalysts_a2021v11n8p880.pdf 5895443253263e27032559f546115a16ea0df10ad2a5a3190ffad0b2bccd197b catalysts_a2021v11n8p880.pdf Title: Electrochemical Incorporation of Carbon Dioxide into Fluorotoluene Derivatives under Mild Conditions Subject: One of the main challenges to combat climate change is to eliminate or reuse Carbon dioxide (CO2), the largest contributor to the greenhouse gases that cause global warming. It is also important to synthesize compounds through greener technologies in order to obtain more environmentally friendly solutions. This study describes the electrocarboxylation process of ,,-trifluorotoluene using different working electrodes (glassy carbon, silver and copper) and electrolytes (polar aprotic solvent and ionic liquid). Carboxylated compounds were obtained in the same way in both electrolytic medias with more than 80% conversion rates, high yields, good selectivity, and moderate efficiencies using silver and copper as cathodes in organic electrolytes and ionic liquids. Keywords: ionic liquids; electrocarboxylation; CO2 valorization; ,,-trifluorotoluene Author: Silvia Mena, Jesus Bernad and Gonzalo Guirado Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Thu Jul 22 10:28:37 2021 CEST ModDate: Thu Jul 22 11:12:02 2021 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 13 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2549898 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- YLNFLJ+EURM10 Type 1 Builtin yes yes no 10 0 QRGHKD+URWPalladioL-Ital Type 1 Custom yes yes no 14 0 GIHEGJ+URWPalladioL-Bold Type 1 Custom yes yes no 19 0 REOPER+URWPalladioL-Roma Type 1 Custom yes yes no 23 0 TRXZTX+CMSY10 Type 1 Builtin yes yes no 27 0 CMFVHJ+VnURWPalladioL Type 1 Custom yes yes no 31 0 CGDLTM+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 40 0 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(2019-04-17) LastModified: 2023-03-31 11:58:17 CEST Size: 2549898 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 670 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@44c8afef Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7b69c6ba Children: Item: Title: Electrochemical Reduction of ,,-trifluorotoluene under an Inert Atmosphere Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@46daef40 Children: Item: Title: Electrochemical Reduction Mechanism of ,,-trifluorotoluene in a Polar Aprotic Solvent Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@12f41634 Item: Title: Electrochemical Reduction Mechanism of ,,-trifluorotoluene in Ionic Liquid Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Item: Title: Electrochemical Study of ,,-trifluorotoluene in a Saturated CO2 Atmosphere Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Children: Item: Title: CO2 Electrochemical Reduction Mechanism in DMF/0.1M TBA PF6 and BMPyr TFSI Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: Electrocarboxylation of ,,-trifluorotoluene in DMF/0.1M TBA PF6 and BMPyr TFSI Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Children: Item: Title: Materials Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: Electrochemical Experiments Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: Determination of the CO2 Concentration in Solution Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1a3869f4 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@a38d7a3 Info: Title: Electrochemical Incorporation of Carbon Dioxide into Fluorotoluene Derivatives under Mild Conditions Author: Silvia Mena, Jesus Bernad and Gonzalo Guirado Subject: One of the main challenges to combat climate change is to eliminate or reuse Carbon dioxide (CO2), the largest contributor to the greenhouse gases that cause global warming. It is also important to synthesize compounds through greener technologies in order to obtain more environmentally friendly solutions. This study describes the electrocarboxylation process of ,,-trifluorotoluene using different working electrodes (glassy carbon, silver and copper) and electrolytes (polar aprotic solvent and ionic liquid). Carboxylated compounds were obtained in the same way in both electrolytic medias with more than 80% conversion rates, high yields, good selectivity, and moderate efficiencies using silver and copper as cathodes in organic electrolytes and ionic liquids. 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