117dd8eb9574c9375b388883bb0cbfb9 Min_a2021v11n12p1382.pdf d50ed92d058b218e2801a8dc1617e26938437976 Min_a2021v11n12p1382.pdf a08886fd7c20a0ce5acdc19350bf58a8af2b3da4f13d287f32b93487094dd9c7 Min_a2021v11n12p1382.pdf Title: Origin of the Coloured Karst Fills in the Neogene Extensional System of NE Iberia (Spain) Subject: Karst fills from the onshore Penedès Basin and offshore València Trough display red, pink, orange and ochre colours. Their Mössbauer spectra indicate that Fe3+ contained in goethite is the dominant species in reddish-pink fills, whereas Fe2+ contained in dolomite and clays is more dominant in the orange and ochre ones. The lower 13C values and higher 87Sr/86Sr ratios of the karst fills with respect to their host carbonates can reflect the input of soil-derived CO2 and an external radiogenic source into the karst system. This geochemical composition, together with the non-carbonate fraction of the fills, consists of authigenic and transported illite, illite-smectite interlayers, as well as kaolinite, chlorite, pyrite, quartz, ilmenite, magnetite, apatite and feldspar, account for a mixed residual-detrital origin of fills. This polygenic origin agrees with that of the terra rossa sediments described worldwide. The different colours of karst fills are attributed to fluctuations in the water table, which control the Eh/pH conditions in the karst system. Thus, reddish colours reflect low water table levels and oxidising episodes, and orange and ochre ones reflect high water table levels and more reducing episodes. The greenish colours of fills could be related to fluctuations in the Fe3+/Fe2+ ratio. Keywords: carbonate diagenesis; coloured karst fills; fracture and vug porosity; geochemistry Author: Anna Travé, Noelia Rodríguez-Morillas, Vinyet Baqués, Elisabet Playà, Lluís Casas, Irene Cantarero, Juan Diego Martín-Martín, Enrique Gómez-Rivas, Mar Moragas and David Cruset Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Wed Dec 8 07:31:04 2021 CET ModDate: Wed Dec 8 09:01:44 2021 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 28 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 11327872 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- KORLVE+VnURWPalladioL Type 1 Custom yes yes no 10 0 VZHZPL+EURM10 Type 1 Builtin yes yes no 15 0 JQXHPU+URWPalladioL-Ital Type 1 Custom yes yes no 19 0 ALDMFC+URWPalladioL-Bold Type 1 Custom yes yes no 24 0 HWGJXQ+URWPalladioL-Roma Type 1 Custom yes yes 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Identity-H yes yes yes 333 0 NGIEKH+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 339 0 CHGGKZ+PazoMath-Italic Type 1 Builtin yes yes no 347 0 NGIEJD+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 354 0 NGIEJE+PalatinoLinotype CID TrueType Identity-H yes yes yes 357 0 NGIEJF+PalatinoLinotype TrueType WinAnsi yes yes no 363 0 NGIEKH+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 366 0 NGIEJD+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 376 0 NGIEJE+PalatinoLinotype CID TrueType Identity-H yes yes yes 379 0 NGIEJF+PalatinoLinotype TrueType WinAnsi yes yes no 385 0 NGIEKH+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 388 0 NGIEJD+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 408 0 NGIEJE+PalatinoLinotype CID TrueType Identity-H yes yes yes 411 0 NGIEJF+PalatinoLinotype TrueType WinAnsi yes yes no 417 0 NGIEKH+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 420 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2023-11-25 02:41:21 CET RepresentationInformation: Min_a2021v11n12p1382.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2023-11-24 15:07:23 CET Size: 11327872 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 723 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4d3167f4 Item: Title: Geological Setting Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@ed9d034 Item: Title: Study Areas Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@6121c9d6 Children: Item: Title: Casablanca-1A Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@87f383f Item: Title: Amposta Marino C2 Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4eb7f003 Item: Title: The Penedès Basin Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@eafc191 Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@612fc6eb Item: Title: Petrology of Host Carbonates and Karst Fills Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1060b431 Children: Item: Title: Casablanca-1A Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@612679d6 Item: Title: Amposta Marino C2 Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@11758f2a Item: Title: Penedès Basin Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@e720b71 Item: Title: Geochemistry of the Karst Fills and Host Rocks Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1b26f7b2 Children: Item: Title: Fe Oxidation State (Mössbauer Spectrometry) Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@491cc5c9 Children: Item: Title: Casablanca-1A Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@74ad1f1f Item: Title: Penedès Basin Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@6a1aab78 Item: Title: Minor and Trace Elements Content Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@462d5aee Children: Item: Title: Casablanca-1A Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@69b0fd6f Item: Title: Amposta Marino C2 Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@757942a1 Item: Title: Penedès Basin Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4a87761d Item: Title: 18O, 13C and 87Sr/ 86Sr Isotope Geochemistry Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@66d1af89 Children: Item: Title: Casablanca-1A Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@8646db9 Item: Title: Amposta Marino C2 Well Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@37374a5e Item: Title: Penedès Basin Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4671e53b Item: Title: Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@2db7a79b Children: Item: Title: Detrital Versus Residual Origin of Karst Fills Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@6950e31 Item: Title: Significance of the Colour of the Karst Fillls Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@b7dd107 Item: Title: Depositional Environment of Karst Fills Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@42eca56e Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@52f759d7 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7cbd213e Info: Title: Origin of the Coloured Karst Fills in the Neogene Extensional System of NE Iberia (Spain) Author: Anna Travé, Noelia Rodríguez-Morillas, Vinyet Baqués, Elisabet Playà, Lluís Casas, Irene Cantarero, Juan Diego Martín-Martín, Enrique Gómez-Rivas, Mar Moragas and David Cruset Subject: Karst fills from the onshore Penedès Basin and offshore València Trough display red, pink, orange and ochre colours. Their Mössbauer spectra indicate that Fe3+ contained in goethite is the dominant species in reddish-pink fills, whereas Fe2+ contained in dolomite and clays is more dominant in the orange and ochre ones. The lower 13C values and higher 87Sr/86Sr ratios of the karst fills with respect to their host carbonates can reflect the input of soil-derived CO2 and an external radiogenic source into the karst system. This geochemical composition, together with the non-carbonate fraction of the fills, consists of authigenic and transported illite, illite-smectite interlayers, as well as kaolinite, chlorite, pyrite, quartz, ilmenite, magnetite, apatite and feldspar, account for a mixed residual-detrital origin of fills. This polygenic origin agrees with that of the terra rossa sediments described worldwide. The different colours of karst fills are attributed to fluctuations in the water table, which control the Eh/pH conditions in the karst system. Thus, reddish colours reflect low water table levels and oxidising episodes, and orange and ochre ones reflect high water table levels and more reducing episodes. The greenish colours of fills could be related to fluctuations in the Fe3+/Fe2+ ratio. 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Annotation: Subtype: Link Rect: 421, 248, 433, 260 ActionDest: 279 Annotation: Subtype: Link Rect: 191, 238, 198, 248 ActionDest: 279 Page: Sequence: 16 Page: Sequence: 17 Annotations: Annotation: Subtype: Link Rect: 195, 720, 202, 732 ActionDest: 279 Annotation: Subtype: Link Rect: 230, 644, 237, 656 ActionDest: 279 Annotation: Subtype: Link Rect: 286, 493, 293, 505 ActionDest: 279 Annotation: Subtype: Link Rect: 320, 330, 327, 342 ActionDest: 279 Annotation: Subtype: Link Rect: 491, 242, 502, 254 ActionDest: 315 Page: Sequence: 18 Page: Sequence: 19 Annotations: Annotation: Subtype: Link Rect: 458, 604, 470, 618 ActionDest: 344 Annotation: Subtype: Link Rect: 424, 592, 435, 605 ActionDest: 370 Page: Sequence: 20 Annotations: Annotation: Subtype: Link Rect: 179, 357, 190, 365 ActionDest: 430 Page: Sequence: 21 Annotations: Annotation: Subtype: Link Rect: 264, 583, 276, 592 ActionDest: 427 Annotation: Subtype: Link Rect: 275, 508, 287, 517 ActionDest: 430 Annotation: Subtype: Link 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