8954df8eb6d4b595452bf4ec0ab70ded pmc_33499056.pdf 92f1612dcf63059800cbe370c209d9ea7646efbf pmc_33499056.pdf 808bcd0508d4e1e7b285ce636ccba199ea54bb3891a53e7122416965b3c1e456 pmc_33499056.pdf Title: Structural, Wetting and Magnetic Properties of Sputtered Fe70Pd30 Thin Film with Nanostructured Surface Induced by Dealloying Process Subject: FePd alloys in the thin film form represent a multipurpose and versatile material with relevant chemical and physical properties studied in different research fields. Moreover, the ability to manipulate and fine-tune the film surface with nanometric scale precision represents a degree of freedom useful to adapt these thin film properties to the demands of different desired applications. In this manuscript, Fe70Pd30 (at. %) thin films are prepared with a thickness of 50 and 200 nm by means of the widely used co-sputtering deposition technique. Subsequently, selective removal of the iron element from the alloy and the consequent surface diffusion of the palladium was induced by a dealloying treatment under free corrosion conditions in hydrochloric acid. The size and shape of the grains of the as-deposited thin films determine the dissolution rate of the iron element with a direct consequence not only on the surface morphology and the stoichiometry of the alloy but also on the wetting and magnetic properties of the sample. X-ray diffraction, Scanning Electron Microscopy (SEM) images, contact angle and magnetic measurements have been performed to provide a thorough characterisation of the fundamental properties of these nanostructured bimetallic thin films. Keywords: FePd thin film; dealloying process; wettability; magnetic properties Author: Gabriele Barrera, Federica Celegato, Matteo Cialone, Marco Coïsson, Paola Rizzi and Paola Tiberto Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Fri Jan 22 09:59:11 2021 CET ModDate: Fri Jan 22 10:06:21 2021 CET Custom Metadata: no Metadata Stream: no Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 14 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2527452 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- OHKNFJ+VnURWPalladioL Type 1 Custom yes yes no 10 0 WPQSDW+URWPalladioL-Ital Type 1 Custom yes yes no 15 0 XYWBAX+URWPalladioL-Bold Type 1 Custom yes yes no 20 0 CPRTOP+URWPalladioL-Roma Type 1 Custom yes yes no 24 0 NPLVPL+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 32 0 MCBCCI+SourceSansRoman-Regular Type 1C Custom yes yes no 54 0 MCBCCM+SourceSansRoman.613wght Type 1C Custom yes yes no 58 0 MCBCCO+SourceSansRoman-Bold Type 1C Custom yes yes no 62 0 KVEXVN+CMSY10 Type 1 Builtin yes yes no 74 0 ZXDKIP+EURM10 Type 1 Builtin yes yes no 78 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 92 0 KEIIGO+PalatinoLinotype CID TrueType Identity-H yes yes yes 95 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 101 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 104 0 GIGFZE+CMR10 Type 1 Builtin yes yes no 111 0 QSNVKX+PazoMath-Italic Type 1 Builtin yes yes no 115 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 128 0 KEIIGO+PalatinoLinotype CID TrueType Identity-H yes yes yes 131 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 137 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 140 0 KEILEB+TimesNewRoman CID TrueType Identity-H yes yes yes 143 0 KEILHB+CambriaMath CID TrueType Identity-H yes yes yes 149 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 166 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 169 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 172 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 186 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 189 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 192 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 208 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 211 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 214 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 228 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 231 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 234 0 KEILHB+CambriaMath CID TrueType Identity-H yes yes yes 237 0 KEIIGN+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 254 0 KEIIGP+PalatinoLinotype TrueType WinAnsi yes yes no 257 0 KEIIIB+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 260 0 Jhove (Rel. 1.28.0, 2023-05-18) Date: 2024-10-02 03:33:44 CEST RepresentationInformation: pmc_33499056.pdf ReportingModule: PDF-hul, Rel. 1.12.4 (2023-03-16) LastModified: 2023-03-31 12:08:40 CEST Size: 2527452 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 483 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: section.1 Item: Title: Materials and Methods Destination: section.2 Item: Title: Results and Discussion Destination: section.3 Children: Item: Title: As-Deposited FePd Thin Film Destination: subsection.3.1 Item: Title: Dealloying Process FePd Thin Film Destination: subsection.3.2 Item: Title: Conclusions Destination: section.4 Item: Title: References Destination: section.4 Info: Title: Structural, Wetting and Magnetic Properties of Sputtered Fe70Pd30 Thin Film with Nanostructured Surface Induced by Dealloying Process Author: Gabriele Barrera, Federica Celegato, Matteo Cialone, Marco Coïsson, Paola Rizzi and Paola Tiberto Subject: FePd alloys in the thin film form represent a multipurpose and versatile material with relevant chemical and physical properties studied in different research fields. Moreover, the ability to manipulate and fine-tune the film surface with nanometric scale precision represents a degree of freedom useful to adapt these thin film properties to the demands of different desired applications. In this manuscript, Fe70Pd30 (at. %) thin films are prepared with a thickness of 50 and 200 nm by means of the widely used co-sputtering deposition technique. Subsequently, selective removal of the iron element from the alloy and the consequent surface diffusion of the palladium was induced by a dealloying treatment under free corrosion conditions in hydrochloric acid. The size and shape of the grains of the as-deposited thin films determine the dissolution rate of the iron element with a direct consequence not only on the surface morphology and the stoichiometry of the alloy but also on the wetting and magnetic properties of the sample. X-ray diffraction, Scanning Electron Microscopy (SEM) images, contact angle and magnetic measurements have been performed to provide a thorough characterisation of the fundamental properties of these nanostructured bimetallic thin films. Keywords: FePd thin film; dealloying process; wettability; magnetic properties Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Fri Jan 22 09:59:11 CET 2021 ModDate: Fri Jan 22 10:06:21 CET 2021 ID: 0x5e17224334f20898de738b00807df671, 0x5e17224334f20898de738b00807df671 Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: QSNVKX+PazoMath-Italic FontSubset: true FirstChar: 103 LastChar: 113 FontDescriptor: FontName: QSNVKX+PazoMath-Italic Flags: Symbolic FontBBox: -70, -277, 902, 733 FontFile: true Font: BaseFont: XYWBAX+URWPalladioL-Bold FontSubset: true FirstChar: 3 LastChar: 239 FontDescriptor: FontName: XYWBAX+URWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: CPRTOP+URWPalladioL-Roma FontSubset: true FirstChar: 2 LastChar: 252 FontDescriptor: FontName: CPRTOP+URWPalladioL-Roma Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: OHKNFJ+VnURWPalladioL FontSubset: true FirstChar: 129 LastChar: 226 FontDescriptor: FontName: OHKNFJ+VnURWPalladioL Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: KVEXVN+CMSY10 FontSubset: true FirstChar: 0 LastChar: 20 FontDescriptor: FontName: KVEXVN+CMSY10 Flags: Symbolic FontBBox: -29, -960, 1116, 775 FontFile: true Font: BaseFont: ZXDKIP+EURM10 FontSubset: true FirstChar: 11 LastChar: 22 FontDescriptor: FontName: ZXDKIP+EURM10 Flags: Symbolic FontBBox: -32, -243, 1060, 720 FontFile: true Font: BaseFont: WPQSDW+URWPalladioL-Ital FontSubset: true FirstChar: 44 LastChar: 151 FontDescriptor: FontName: WPQSDW+URWPalladioL-Ital Flags: Symbolic FontBBox: -170, -305, 1010, 941 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: GIGFZE+CMR10 FontSubset: true FirstChar: 40 LastChar: 61 FontDescriptor: FontName: GIGFZE+CMR10 Flags: Symbolic FontBBox: -40, -250, 1009, 750 FontFile: true Pages: Page: Sequence: 1 Annotations: Annotation: Subtype: Link Rect: 35, 759, 171, 795 Annotation: Subtype: Link Rect: 515, 759, 560, 795 Annotation: Subtype: Link Rect: 124, 641, 135, 654 Annotation: Subtype: Link Rect: 307, 641, 318, 654 Annotation: Subtype: Link Rect: 395, 641, 406, 654 Annotation: Subtype: Link Rect: 467, 641, 478, 654 Annotation: Subtype: Link Rect: 81, 322, 154, 331 Annotation: Subtype: Link Rect: 35, 311, 106, 319 Annotation: Subtype: Link Rect: 35, 162, 97, 184 Annotation: Subtype: Link Rect: 153, 89, 154, 98 Annotation: Subtype: Link Rect: 35, 77, 147, 86 Annotation: Subtype: Link Rect: 539, 252, 546, 261 ActionDest: 271 Annotation: Subtype: Link Rect: 549, 252, 556, 261 ActionDest: 271 Annotation: Subtype: Link Rect: 199, 214, 206, 223 ActionDest: 271 Annotation: Subtype: Link Rect: 206, 214, 213, 223 ActionDest: 271 Annotation: Subtype: Link Rect: 424, 202, 431, 211 ActionDest: 271 Annotation: Subtype: Link Rect: 434, 201, 441, 211 ActionDest: 271 Annotation: Subtype: Link Rect: 532, 164, 544, 173 ActionDest: 271 Annotation: Subtype: Link Rect: 544, 164, 556, 173 ActionDest: 274 Annotation: Subtype: Link Rect: 474, 126, 486, 135 ActionDest: 274 Annotation: Subtype: Link Rect: 264, 101, 271, 110 ActionDest: 271 Annotation: Subtype: Link Rect: 272, 101, 284, 110 ActionDest: 274 Annotation: Subtype: Link Rect: 284, 101, 296, 110 ActionDest: 274 Annotation: Subtype: Link Rect: 283, 89, 295, 98 ActionDest: 274 Annotation: Subtype: Link Rect: 420, 76, 432, 85 ActionDest: 274 Annotation: Subtype: Link Rect: 432, 76, 444, 85 ActionDest: 274 Annotation: Subtype: Link Rect: 132, 17, 274, 28 Annotation: Subtype: Link Rect: 384, 17, 558, 28 Annotation: Subtype: Link Rect: 35, 423, 87, 442 Page: Sequence: 2 Annotations: Annotation: Subtype: Link Rect: 354, 711, 366, 721 ActionDest: 274 Annotation: Subtype: Link Rect: 369, 712, 381, 721 ActionDest: 274 Annotation: Subtype: Link Rect: 327, 686, 339, 695 ActionDest: 274 Annotation: Subtype: Link Rect: 339, 686, 351, 695 ActionDest: 274 Annotation: Subtype: Link Rect: 354, 686, 366, 695 ActionDest: 274 Annotation: Subtype: Link Rect: 342, 674, 354, 683 ActionDest: 274 Annotation: Subtype: Link Rect: 357, 674, 369, 683 ActionDest: 274 Annotation: Subtype: Link Rect: 225, 661, 237, 670 ActionDest: 274 Annotation: Subtype: Link Rect: 238, 661, 250, 670 ActionDest: 274 Annotation: Subtype: Link Rect: 233, 649, 245, 658 ActionDest: 274 Annotation: Subtype: Link Rect: 245, 649, 257, 658 ActionDest: 274 Annotation: Subtype: Link Rect: 348, 649, 360, 658 ActionDest: 274 Annotation: Subtype: Link Rect: 360, 649, 372, 658 ActionDest: 274 Annotation: Subtype: Link Rect: 460, 649, 472, 658 ActionDest: 274 Annotation: Subtype: Link Rect: 321, 624, 333, 633 ActionDest: 274 Annotation: Subtype: Link Rect: 475, 598, 487, 608 ActionDest: 274 Annotation: Subtype: Link Rect: 204, 548, 216, 557 ActionDest: 274 Annotation: Subtype: Link Rect: 217, 548, 229, 557 ActionDest: 274 Annotation: Subtype: Link Rect: 229, 548, 241, 557 ActionDest: 277 Annotation: Subtype: Link Rect: 457, 523, 469, 532 ActionDest: 277 Annotation: Subtype: Link Rect: 410, 498, 422, 507 ActionDest: 277 Annotation: Subtype: Link Rect: 425, 498, 437, 507 ActionDest: 277 Annotation: Subtype: Link Rect: 474, 460, 481, 469 ActionDest: 271 Annotation: Subtype: Link Rect: 481, 461, 493, 469 ActionDest: 277 Annotation: Subtype: Link Rect: 494, 460, 506, 469 ActionDest: 277 Page: Sequence: 3 Annotations: Annotation: Subtype: Link Rect: 211, 405, 218, 417 ActionDest: 82 Annotation: Subtype: Link Rect: 413, 395, 425, 404 ActionDest: 274 Annotation: Subtype: Link Rect: 426, 395, 438, 404 ActionDest: 277 Annotation: Subtype: Link Rect: 526, 369, 538, 379 ActionDest: 274 Annotation: Subtype: Link Rect: 520, 150, 527, 162 ActionDest: 108 Annotation: Subtype: Link Rect: 250, 103, 262, 112 ActionDest: 277 Annotation: Subtype: Link Rect: 262, 103, 274, 112 ActionDest: 277 Annotation: Subtype: Link Rect: 515, 100, 522, 112 ActionDest: 108 Page: Sequence: 4 Annotations: Annotation: Subtype: Link Rect: 217, 424, 229, 433 ActionDest: 277 Annotation: Subtype: Link Rect: 229, 424, 241, 433 ActionDest: 277 Annotation: Subtype: Link Rect: 404, 411, 416, 420 ActionDest: 277 Annotation: Subtype: Link Rect: 470, 409, 477, 421 ActionDest: 108 Annotation: Subtype: Link Rect: 540, 321, 547, 333 ActionDest: 156 Annotation: Subtype: Link Rect: 329, 123, 341, 132 ActionDest: 277 Page: Sequence: 5 Annotations: Annotation: Subtype: Link Rect: 240, 438, 247, 450 ActionDest: 156 Annotation: Subtype: Link Rect: 528, 375, 535, 387 ActionDest: 156 Annotation: Subtype: Link Rect: 200, 287, 207, 299 ActionDest: 156 Annotation: Subtype: Link Rect: 215, 237, 221, 249 ActionDest: 108 Annotation: Subtype: Link Rect: 466, 76, 478, 85 ActionDest: 277 Page: Sequence: 6 Annotations: Annotation: Subtype: Link Rect: 322, 720, 328, 732 ActionDest: 156 Annotation: Subtype: Link Rect: 545, 722, 557, 731 ActionDest: 277 Annotation: Subtype: Link Rect: 214, 682, 221, 694 ActionDest: 156 Annotation: Subtype: Link Rect: 526, 669, 533, 681 ActionDest: 156 Annotation: Subtype: Link Rect: 245, 609, 257, 618 ActionDest: 274 Annotation: Subtype: Link Rect: 340, 609, 352, 618 ActionDest: 277 Annotation: Subtype: Link Rect: 312, 546, 324, 556 ActionDest: 277 Annotation: Subtype: Link Rect: 262, 534, 274, 543 ActionDest: 277 Annotation: Subtype: Link Rect: 549, 481, 556, 493 ActionDest: 176 Annotation: Subtype: Link Rect: 526, 159, 538, 168 ActionDest: 274 Annotation: Subtype: Link Rect: 539, 159, 551, 168 ActionDest: 277 Page: Sequence: 7 Annotations: Annotation: Subtype: Link Rect: 209, 720, 216, 732 ActionDest: 196 Annotation: Subtype: Link Rect: 248, 707, 255, 719 ActionDest: 108 Annotation: Subtype: Link Rect: 196, 682, 203, 694 ActionDest: 196 Annotation: Subtype: Link Rect: 326, 619, 333, 631 ActionDest: 196 Annotation: Subtype: Link Rect: 197, 594, 204, 606 ActionDest: 176 Annotation: Subtype: Link Rect: 445, 569, 452, 581 ActionDest: 176 Annotation: Subtype: Link Rect: 425, 170, 432, 182 ActionDest: 196 Annotation: Subtype: Link Rect: 443, 158, 450, 170 ActionDest: 108 Annotation: Subtype: Link Rect: 339, 120, 346, 132 ActionDest: 108 Annotation: Subtype: Link Rect: 446, 120, 453, 132 ActionDest: 196 Annotation: Subtype: Link Rect: 254, 108, 261, 120 ActionDest: 196 Annotation: Subtype: Link Rect: 352, 83, 359, 95 ActionDest: 176 Page: Sequence: 8 Annotations: Annotation: Subtype: Link Rect: 378, 697, 389, 706 ActionDest: 277 Annotation: Subtype: Link Rect: 390, 697, 402, 706 ActionDest: 277 Annotation: Subtype: Link Rect: 405, 697, 417, 706 ActionDest: 277 Annotation: Subtype: Link Rect: 263, 669, 270, 681 ActionDest: 218 Annotation: Subtype: Link Rect: 348, 607, 355, 619 ActionDest: 176 Annotation: Subtype: Link Rect: 410, 559, 422, 568 ActionDest: 277 Annotation: Subtype: Link Rect: 422, 559, 434, 568 ActionDest: 277 Annotation: Subtype: Link Rect: 437, 559, 449, 568 ActionDest: 277 Annotation: Subtype: Link Rect: 316, 534, 327, 543 ActionDest: 277 Annotation: Subtype: Link Rect: 328, 534, 340, 543 ActionDest: 277 Annotation: Subtype: Link Rect: 340, 534, 352, 543 ActionDest: 277 Annotation: Subtype: Link Rect: 335, 484, 347, 493 ActionDest: 277 Annotation: Subtype: Link Rect: 492, 471, 504, 480 ActionDest: 277 Annotation: Subtype: Link Rect: 485, 82, 492, 94 ActionDest: 244 Annotation: Subtype: Link Rect: 257, 60, 269, 69 ActionDest: 274 Page: Sequence: 9 Annotations: Annotation: Subtype: Link Rect: 447, 308, 459, 317 ActionDest: 277 Annotation: Subtype: Link Rect: 210, 295, 222, 304 ActionDest: 274 Annotation: Subtype: Link Rect: 342, 295, 354, 304 ActionDest: 277 Annotation: Subtype: Link Rect: 200, 230, 207, 242 ActionDest: 244 Annotation: Subtype: Link Rect: 524, 167, 531, 179 ActionDest: 244 Annotation: Subtype: Link Rect: 543, 67, 550, 79 ActionDest: 244 Page: Sequence: 10 Annotations: Annotation: Subtype: Link Rect: 316, 484, 328, 493 ActionDest: 277 Annotation: Subtype: Link Rect: 330, 418, 337, 430 ActionDest: 244 Annotation: Subtype: Link Rect: 328, 280, 335, 292 ActionDest: 244 Annotation: Subtype: Link Rect: 276, 117, 283, 129 ActionDest: 176 Annotation: Subtype: Link Rect: 548, 92, 555, 104 ActionDest: 176 Page: Sequence: 11 Annotations: Annotation: Subtype: Link Rect: 361, 644, 368, 656 ActionDest: 244 Annotation: Subtype: Link Rect: 196, 569, 203, 581 ActionDest: 176 Page: Sequence: 12 Annotations: Annotation: Subtype: Link Rect: 426, 570, 560, 581 Annotation: Subtype: Link Rect: 166, 558, 239, 569 Annotation: Subtype: Link Rect: 211, 286, 249, 297 Annotation: Subtype: Link Rect: 190, 264, 227, 274 Annotation: Subtype: Link Rect: 198, 229, 235, 240 Annotation: Subtype: Link Rect: 396, 206, 433, 217 Annotation: Subtype: Link Rect: 173, 183, 210, 194 Annotation: Subtype: Link Rect: 104, 160, 142, 171 Annotation: Subtype: Link Rect: 113, 126, 150, 136 Annotation: Subtype: Link Rect: 327, 102, 365, 113 Annotation: Subtype: Link Rect: 59, 68, 97, 79 Page: Sequence: 13 Annotations: Annotation: Subtype: Link Rect: 436, 721, 473, 732 Annotation: Subtype: Link Rect: 59, 699, 97, 709 Annotation: Subtype: Link Rect: 227, 663, 264, 674 Annotation: Subtype: Link Rect: 59, 630, 97, 640 Annotation: Subtype: Link Rect: 136, 607, 173, 617 Annotation: Subtype: Link Rect: 163, 583, 200, 594 Annotation: Subtype: Link Rect: 366, 560, 403, 571 Annotation: Subtype: Link Rect: 482, 548, 519, 559 Annotation: Subtype: Link Rect: 203, 526, 240, 536 Annotation: Subtype: Link Rect: 402, 502, 439, 513 Annotation: Subtype: Link Rect: 167, 479, 205, 490 Annotation: Subtype: Link Rect: 413, 456, 450, 467 Annotation: Subtype: Link Rect: 457, 456, 493, 467 Annotation: Subtype: Link Rect: 156, 434, 194, 444 Annotation: Subtype: Link Rect: 520, 422, 557, 433 Annotation: Subtype: Link Rect: 366, 399, 404, 410 Annotation: Subtype: Link Rect: 410, 399, 446, 410 Annotation: Subtype: Link Rect: 446, 376, 483, 387 Annotation: Subtype: Link Rect: 273, 353, 310, 364 Annotation: Subtype: Link Rect: 484, 330, 521, 341 Annotation: Subtype: Link Rect: 405, 261, 442, 272 Annotation: Subtype: Link Rect: 243, 238, 281, 249 Annotation: Subtype: Link Rect: 488, 215, 526, 226 Annotation: Subtype: Link Rect: 439, 192, 477, 203 Annotation: Subtype: Link Rect: 223, 169, 261, 180 Annotation: Subtype: Link Rect: 213, 146, 251, 157 Annotation: Subtype: Link Rect: 264, 123, 301, 134 Annotation: Subtype: Link Rect: 307, 123, 343, 134 Annotation: Subtype: Link Rect: 314, 100, 351, 111 Annotation: Subtype: Link Rect: 295, 77, 332, 88 Page: Sequence: 14 Annotations: Annotation: Subtype: Link Rect: 520, 721, 557, 732 Annotation: Subtype: Link Rect: 369, 698, 407, 709 Annotation: Subtype: Link Rect: 167, 676, 205, 686 Annotation: Subtype: Link Rect: 393, 652, 431, 663 Annotation: Subtype: Link Rect: 516, 640, 553, 651 Annotation: Subtype: Link Rect: 430, 629, 467, 640 Annotation: Subtype: Link Rect: 95, 607, 133, 617 Annotation: Subtype: Link Rect: 506, 583, 543, 594 Annotation: Subtype: Link Rect: 456, 560, 493, 571 Annotation: Subtype: Link Rect: 150, 538, 188, 548 Annotation: Subtype: Link Rect: 326, 514, 363, 525 Annotation: Subtype: Link Rect: 163, 492, 201, 502 Annotation: Subtype: Link Rect: 170, 468, 207, 479 Annotation: Subtype: Link Rect: 104, 446, 141, 456 Annotation: Subtype: Link Rect: 519, 422, 557, 433 Annotation: Subtype: Link Rect: 475, 399, 512, 410 Annotation: Subtype: Link Rect: 59, 365, 97, 375 Annotation: Subtype: Link Rect: 103, 365, 139, 375 Annotation: Subtype: Link Rect: 136, 331, 173, 341 Annotation: Subtype: Link Rect: 484, 318, 522, 329 Annotation: Subtype: Link Rect: 59, 285, 97, 295 Annotation: Subtype: Link Rect: 103, 285, 139, 295 Annotation: Subtype: Link Rect: 95, 262, 133, 272 Annotation: Subtype: Link Rect: 500, 238, 538, 249 Annotation: Subtype: Link Rect: 104, 192, 142, 203 Annotation: Subtype: Link Rect: 113, 158, 150, 168 Checksum: 69dce378 Type: CRC32 Checksum: 8954df8eb6d4b595452bf4ec0ab70ded Type: MD5 Checksum: 92f1612dcf63059800cbe370c209d9ea7646efbf Type: SHA-1 Checksum: 808bcd0508d4e1e7b285ce636ccba199ea54bb3891a53e7122416965b3c1e456 Type: SHA-256