fa7a146a5995b5d03cc1779f3452e041 pmc_34066792.pdf 9210cf737ef6dcb26cec3e87278dd5a2c73033c4 pmc_34066792.pdf c76cf4029dd68ecbf85a4933f80cf3ea677976d8a197cb61673b4fb5080da715 pmc_34066792.pdf Title: A Theoretical Perspective of the Photochemical Potential in the Spectral Performance of Photovoltaic Cells Subject: We present a novel theoretical approach to the problem of light energy conversion in thermostated semiconductor junctions. Using the classical model of a two-level atom, we deduced formulas for the spectral response and the quantum efficiency in terms of the input photons' non-zero chemical potential. We also calculated the spectral entropy production and the global efficiency parameter in the thermodynamic limit. The heat transferred to the thermostat results in a dissipative loss that appreciably controls the spectral quantities' behavior and, therefore, the cell's performance. The application of the obtained formulas to data extracted from photovoltaic cells enabled us to accurately interpolate experimental data for the spectral response and the quantum efficiency of cells based on Si-, GaAs, and CdTe, among others. Keywords: PVC; spectral response; quantum efficiency; spectral entropy production; photochemical potential; two-level atom model Author: Agustin Pérez-Madrid and Ivan Santamaría-Holek Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Mon May 17 08:16:41 2021 CEST ModDate: Mon May 17 08:16:41 2021 CEST Custom Metadata: yes Metadata Stream: no Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 17 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 4447786 bytes Optimized: no PDF version: 1.5 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- ZUIOSW+URWPalladioL-Ital Type 1 Custom yes yes no 261 0 JBMWMC+URWPalladioL-Bold Type 1 Custom yes yes no 262 0 KJRMVA+URWPalladioL-Roma Type 1 Custom yes yes no 263 0 IFXPBB+PazoMath-Italic Type 1 Builtin yes yes no 266 0 WFMTKF+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 272 0 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