04638a8da2f6b546441b490ca1cf6285 inorganics_a2022v10n8p118iENG.pdf c62a5f52fcc240972dbf3b2f91106f51677e8fae inorganics_a2022v10n8p118iENG.pdf 4b388e1a3ed801c88bc1f36e9f024fcaece05405c7f99a198446a1f35c7322d8 inorganics_a2022v10n8p118iENG.pdf Title: Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons Subject: The rational design of heterometallic compounds bearing s-block metal ions have been a difficult task for chemists owing to their lack of preferential geometries. However, some strategies, such as the design of coordinating pockets with different sizes and/or donor atoms, have offered great results. In this work, this strategy has been tested using Ca(II) as an s-block metal ion and a compound previously obtained by our group with the formula [Zn3(-ACA)6(4-phpy)2], which contains tetrahedral N,O- and octahedral O-coordinating pockets as a model structure. From this work, the corresponding heterometallic compound with the formula [Zn2Ca(-ACA)6(4-phpy)2]EtOH (1) has been successfully synthesized, and fully characterized, and its crystal structure has been elucidated. Furthermore, we have compiled all the crystal structures containing [Zn2M] pinwheel secondary building units (SBUs), where M stands for an s-block metal ion, and the observed tendencies, as well as the promising applications as template SBUs for the preparation of 1D–3D coordination polymers, have been discussed. Finally, solid-state UV-Vis and photoluminescence have been recorded and compared with the homometallic [Zn3(-ACA)6(4-phpy)2] compound. Keywords: heterometallic complexes; trinuclear complexes; Zn(II); Ca(II); secondary building unit; X-ray crystal structure; -acetamidocinnamic acid; solid-state photoluminescence Author: Daniel Ejarque, Teresa Calvet, Mercè Font-Bardia and Josefina Pons Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Sun Aug 14 10:45:28 2022 CEST ModDate: Sun Aug 14 10:50:35 2022 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 13 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2481741 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- WYEKQU+VnURWPalladioL-Bold Type 1 Custom yes yes no 10 0 FCMYYM+EURM10 Type 1 Builtin yes yes no 15 0 IMNEMZ+URWPalladioL-Bold Type 1 Custom yes yes no 19 0 FSELEV+URWPalladioL-Roma Type 1 Custom yes yes no 24 0 MEVUAL+URWPalladioL-Ital Type 1 Custom yes yes no 28 0 QCJLZP+CMSY10 Type 1 Builtin yes yes no 32 0 DQHEJR+VnURWPalladioL Type 1 Custom yes yes no 36 0 XQOHOC+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 54 0 XQZHNR+PazoMath-Italic Type 1 Builtin yes yes no 79 0 MPUDFL+PazoMath Type 1 Builtin yes yes no 89 0 MEKGLG+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 96 0 MEKGLH+PalatinoLinotype CID TrueType Identity-H yes yes yes 99 0 MEKGLI+PalatinoLinotype TrueType WinAnsi yes yes no 105 0 MEKGLK+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 108 0 MEKLON+PalatinoLinotype,BoldItalic TrueType WinAnsi yes yes no 111 0 MEKGLG+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 148 0 MEKGLI+PalatinoLinotype TrueType WinAnsi yes yes no 151 0 MEKGLK+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 154 0 XHAQEC+CMBSY10 Type 1 Builtin yes yes no 161 0 MEKGLG+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 176 0 MEKGLH+PalatinoLinotype CID TrueType Identity-H yes yes yes 179 0 MEKGLI+PalatinoLinotype TrueType WinAnsi yes yes no 185 0 MEKGLK+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 188 0 MEKGLG+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 226 0 MEKGLH+PalatinoLinotype CID TrueType Identity-H yes yes yes 229 0 MEKGLI+PalatinoLinotype TrueType WinAnsi yes yes no 235 0 MEKGLK+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 238 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2023-06-28 02:29:24 CEST RepresentationInformation: inorganics_a2022v10n8p118iENG.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2023-06-27 12:22:51 CEST Size: 2481741 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 463 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@44c8afef Item: Title: Experimental Section Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7b69c6ba Children: Item: Title: Materials and General Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@46daef40 Item: Title: Synthesis of [Zn2Ca(-ACA)6(4-phpy)2]EtOH (1) Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@12f41634 Item: Title: X-ray Crystallographic Data Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Children: Item: Title: Synthesis and Characterization of 1 Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: Structural Description and Hirshfeld Surface Analysis of 1C Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: CSD Study of Heterometallic [Zn2M] Pinwheel SBUs (M = S-Block Metal) Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Photophysical Properties Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Info: Title: Synthesis of a Heterometallic [Zn2Ca] Pinwheel Array Stabilized by Amide-Amide Synthons Author: Daniel Ejarque, Teresa Calvet, Mercè Font-Bardia and Josefina Pons Subject: The rational design of heterometallic compounds bearing s-block metal ions have been a difficult task for chemists owing to their lack of preferential geometries. However, some strategies, such as the design of coordinating pockets with different sizes and/or donor atoms, have offered great results. In this work, this strategy has been tested using Ca(II) as an s-block metal ion and a compound previously obtained by our group with the formula [Zn3(-ACA)6(4-phpy)2], which contains tetrahedral N,O- and octahedral O-coordinating pockets as a model structure. From this work, the corresponding heterometallic compound with the formula [Zn2Ca(-ACA)6(4-phpy)2]EtOH (1) has been successfully synthesized, and fully characterized, and its crystal structure has been elucidated. Furthermore, we have compiled all the crystal structures containing [Zn2M] pinwheel secondary building units (SBUs), where M stands for an s-block metal ion, and the observed tendencies, as well as the promising applications as template SBUs for the preparation of 1D 3D coordination polymers, have been discussed. Finally, solid-state UV-Vis and photoluminescence have been recorded and compared with the homometallic [Zn3(-ACA)6(4-phpy)2] compound. 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