622cfbc291bbdad64602b5223c977bef minerals_a2022v12n8p954iENG.pdf 454b72c18f90face38ee8e297207114aa08cc734 minerals_a2022v12n8p954iENG.pdf 37aae0ab9658adc5a5caed267c9e3ad69e8aaae68abc61484152166067395cfe minerals_a2022v12n8p954iENG.pdf Title: Allanite in Variscan Post-Collisional Lamprophyre Dykes from Les Guilleries (NE Iberia) as a Part of Rare Earth Elements Recycling in Collisional Orogens Subject: Recent studies of Late Permian calc-alkaline lamprophyre dykes located in the Les Guilleries Paleozoic massif of the Catalan Coastal Range have revealed that allanite is present as the main REE-bearing accessory phase, which is the object of this study. The lamprophyre dykes are amphibole–plagioclase-dominated spessartites with a wide variety of accessory phases, including titanite, ilmenite, allanite, fluorapatite, spinel, zircon, and sulfides, and show complex alteration textures related to secondary albite, chlorite, epidote, titanite and calcite. The allanite crystal composition, analyzed by SEM-EPMA and LA-ICP-MS, evidences the solid solution between epidote and allanite with a ferriallanite component, similar to what is found in Variscan post-collisional granitoids from western Europe. However, heterogeneity in crystal shapes, sizes, type of zoning, dissolution embayment textures, growth of epidote coronas, mineral paragenesis, and the unique geochemical characteristics of allanite crystals suggest multiple crystallization events. At least two types of allanite–epidote composite grains have been identified: allanite Type I, with regular allanite–epidote core-to-rim zoning and a secondary allanite rim; and allanite Type II, with anhedral allanite cores surrounded by epidote coronas. Additionally, irregular zoning, complex dissolution textures and REE redistribution suggest the occurrence of deuteric and/or post-magmatic processes, which are also common in Variscan post-collisional plutons from the Catalan Coastal Range and nearby Paleozoic massifs. Multivariate statistical analyses of major elements in allanite–epidote composite grains show a relationship between major textural and geochemical variations for three out of ten principal components, mainly related to cationic substitutions between ferriallanite-(Ce) and epidote, but also involving Mn and Ti(REE3+ + Fe2+ + Ti4+ + Mg2+ + Mn2+ = Al3+ + Ca2+ + Fe3+). The allanite U-Pb-Th- weighted mean age of 265 15 Ma (MSWD = 0.57) is roughly similar to the age of emplacement of the lamprophyres in the upper crust in the mid–late Permian, and coincides with the period following the main tectonometamorphic and magmatic events of the post-collisional evolution in the Catalan Coastal Range. Th/U and La/Sm ratios suggest a metamorphic origin for most allanite grains, but a combination of metamorphic processes prior to partial melting, early–late magmatic crystallization, and/or post-magmatic hydrothermal processes is the most plausible explanation to account for the diversity of allanite grains in Les Guilleries lamprophyres. Keywords: allanite; geochemistry; EPMA; calc-alkaline lamprophyre; geochemistry; Les Guilleries massif; Variscan orogeny; U-Pb ages Author: Esteban Mellado, Mercè Corbella and Andrew Kylander-Clark Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Tue Aug 2 12:59:51 2022 CEST ModDate: Tue Aug 2 13:03:38 2022 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 17 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 5262437 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- KORLVE+VnURWPalladioL Type 1 Custom yes yes no 10 0 EFDERE+URWPalladioL-Bold Type 1 Custom yes yes no 15 0 VDJERP+URWPalladioL-Roma Type 1 Custom yes yes no 20 0 XBYYUV+URWPalladioL-Ital Type 1 Custom yes yes no 24 0 VYVZGZ+CMSY10 Type 1 Builtin yes yes no 28 0 WYEKQU+VnURWPalladioL-Bold Type 1 Custom yes yes no 32 0 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TrueType Identity-H yes yes yes 328 0 JNLIOJ+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 334 0 JNLJAJ+PalatinoLinotype-Italic CID TrueType Identity-H yes yes yes 340 0 JNLJAK+PalatinoLinotype-Italic TrueType WinAnsi yes yes no 346 0 JNLJAL+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 349 0 JNLJAM+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 352 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2023-06-28 02:29:11 CEST RepresentationInformation: minerals_a2022v12n8p954iENG.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2023-06-27 12:19:52 CEST Size: 5262437 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 552 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@44c8afef Item: Title: Geological Setting Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7b69c6ba Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@46daef40 Item: Title: Results Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@12f41634 Children: Item: Title: Petrography Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Item: Title: Microprobe Chemistry Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Principal Component Analyses Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: LA-ICP-MS In Situ U-Th-Pb Ages Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Info: Title: Allanite in Variscan Post-Collisional Lamprophyre Dykes from Les Guilleries (NE Iberia) as a Part of Rare Earth Elements Recycling in Collisional Orogens Author: Esteban Mellado, Mercè Corbella and Andrew Kylander-Clark Subject: Recent studies of Late Permian calc-alkaline lamprophyre dykes located in the Les Guilleries Paleozoic massif of the Catalan Coastal Range have revealed that allanite is present as the main REE-bearing accessory phase, which is the object of this study. The lamprophyre dykes are amphibole plagioclase-dominated spessartites with a wide variety of accessory phases, including titanite, ilmenite, allanite, fluorapatite, spinel, zircon, and sulfides, and show complex alteration textures related to secondary albite, chlorite, epidote, titanite and calcite. The allanite crystal composition, analyzed by SEM-EPMA and LA-ICP-MS, evidences the solid solution between epidote and allanite with a ferriallanite component, similar to what is found in Variscan post-collisional granitoids from western Europe. However, heterogeneity in crystal shapes, sizes, type of zoning, dissolution embayment textures, growth of epidote coronas, mineral paragenesis, and the unique geochemical characteristics of allanite crystals suggest multiple crystallization events. At least two types of allanite epidote composite grains have been identified: allanite Type I, with regular allanite epidote core-to-rim zoning and a secondary allanite rim; and allanite Type II, with anhedral allanite cores surrounded by epidote coronas. Additionally, irregular zoning, complex dissolution textures and REE redistribution suggest the occurrence of deuteric and/or post-magmatic processes, which are also common in Variscan post-collisional plutons from the Catalan Coastal Range and nearby Paleozoic massifs. Multivariate statistical analyses of major elements in allanite epidote composite grains show a relationship between major textural and geochemical variations for three out of ten principal components, mainly related to cationic substitutions between ferriallanite-(Ce) and epidote, but also involving Mn and Ti(REE3+ + Fe2+ + Ti4+ + Mg2+ + Mn2+ = Al3+ + Ca2+ + Fe3+). The allanite U-Pb-Th- weighted mean age of 265 15 Ma (MSWD = 0.57) is roughly similar to the age of emplacement of the lamprophyres in the upper crust in the mid late Permian, and coincides with the period following the main tectonometamorphic and magmatic events of the post-collisional evolution in the Catalan Coastal Range. Th/U and La/Sm ratios suggest a metamorphic origin for most allanite grains, but a combination of metamorphic processes prior to partial melting, early late magmatic crystallization, and/or post-magmatic hydrothermal processes is the most plausible explanation to account for the diversity of allanite grains in Les Guilleries lamprophyres. Keywords: allanite; geochemistry; EPMA; calc-alkaline lamprophyre; geochemistry; Les Guilleries massif; Variscan orogeny; U-Pb ages Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Tue Aug 02 12:59:51 CEST 2022 ModDate: Tue Aug 02 13:03:38 CEST 2022 ID: 0xf6f46214b45203ea65f555b771fb2db0, 0xf6f46214b45203ea65f555b771fb2db0 Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: WYEKQU+VnURWPalladioL-Bold FontSubset: true FirstChar: 177 LastChar: 177 FontDescriptor: FontName: WYEKQU+VnURWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: VDJERP+URWPalladioL-Roma FontSubset: true FirstChar: 2 LastChar: 252 FontDescriptor: FontName: VDJERP+URWPalladioL-Roma Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: XBYYUV+URWPalladioL-Ital FontSubset: true FirstChar: 2 LastChar: 150 FontDescriptor: FontName: 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