5a30591537e28ddf39068df960d5f9fb nanomaterials_a2022m1v12n2p273.pdf 8c526e5b768928aae384a7dfacbc129b3e54cd4d nanomaterials_a2022m1v12n2p273.pdf eb6593867ab4ac158efb95a022e0e5cc0f13e9fa75c35c3971ec45a94a165310 nanomaterials_a2022m1v12n2p273.pdf Title: Sustainable and Printable Nanocellulose-Based Ionogels as Gel Polymer Electrolytes for Supercapacitors Subject: A new gel polymer electrolyte (GPE) based supercapacitor with an ionic conductivity up to 0.32–0.94 mS cm-2 has been synthesized from a mixture of an ionic liquid (IL) with nanocellulose (NC). The new NC-ionogel was prepared by combining the IL 1-ethyl-3-methylimidazolium dimethyl phosphate (EMIMP) with carboxymethylated cellulose nanofibers (CNFc) at different ratios (CNFc ratio from 1 to 4). The addition of CNFc improved the ionogel properties to become easily printable onto the electrode surface. The new GPE based supercapacitor cell showed good electrochemical performance with specific capacitance of 160 F g-1 and an equivalent series resistance (ESR) of 10.2 cm-2 at a current density of 1 mA cm-2. The accessibility to the full capacitance of the device is demonstrated after the addition of CNFc in EMIMP compared to the pristine EMIMP (99 F g-1 and 14.7 cm-2). Keywords: nanocellulose; ionic liquid; ionogel; gel polymer electrolyte; renewable energy storage; supercapacitors Author: Rosa M. González-Gil, Mateu Borràs, Aiman Chbani, Tiffany Abitbol, Andreas Fall, Christian Aulin, Christophe Aucher and Sandra Martínez-Crespiera Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Sat Jan 15 09:39:56 2022 CET ModDate: Sat Jan 15 09:44:03 2022 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 14 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 3285505 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- BAMNYG+VnURWPalladioL Type 1 Custom yes yes no 10 0 VNOPVN+URWPalladioL-Bold Type 1 Custom yes yes no 15 0 FVHSZP+URWPalladioL-Roma Type 1 Custom yes yes no 20 0 DRRFOC+URWPalladioL-Ital Type 1 Custom yes yes no 24 0 TRXZTX+CMSY10 Type 1 Builtin yes yes no 28 0 SPXLNH+PazoMath Type 1 Builtin yes yes no 32 0 OTZEDH+VnURWPalladioL-Bold Type 1 Custom yes yes no 36 0 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yes yes no 247 0 CHHFFG+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 250 0 CHHFFC+PalatinoLinotype,Bold TrueType WinAnsi yes yes no 260 0 CHHFFD+PalatinoLinotype CID TrueType Identity-H yes yes yes 263 0 CHHFFE+PalatinoLinotype TrueType WinAnsi yes yes no 269 0 CHHFFG+PalatinoLinotype,Italic TrueType WinAnsi yes yes no 272 0 FVGOTS+EURB10 Type 1 Builtin yes yes no 279 0 TSEGZF+PazoMath-Bold Type 1 Builtin yes yes no 283 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2022-11-04 02:26:20 CET RepresentationInformation: nanomaterials_a2022m1v12n2p273.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2022-11-03 12:47:56 CET Size: 3285505 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 439 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4923ab24 Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@44c8afef Children: Item: Title: Materials Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7b69c6ba Item: Title: Carboxymethylated Cellulose Nanofibers (CNFc) Fabrication Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@46daef40 Item: Title: CNFc Based Ionogel Preparation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@12f41634 Item: Title: Supercapacitor Preparation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Item: Title: Characterization Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Info: Title: Sustainable and Printable Nanocellulose-Based Ionogels as Gel Polymer Electrolytes for Supercapacitors Author: Rosa M. González-Gil, Mateu Borràs, Aiman Chbani, Tiffany Abitbol, Andreas Fall, Christian Aulin, Christophe Aucher and Sandra Martínez-Crespiera Subject: A new gel polymer electrolyte (GPE) based supercapacitor with an ionic conductivity up to 0.32 0.94 mS cm-2 has been synthesized from a mixture of an ionic liquid (IL) with nanocellulose (NC). The new NC-ionogel was prepared by combining the IL 1-ethyl-3-methylimidazolium dimethyl phosphate (EMIMP) with carboxymethylated cellulose nanofibers (CNFc) at different ratios (CNFc ratio from 1 to 4). The addition of CNFc improved the ionogel properties to become easily printable onto the electrode surface. The new GPE based supercapacitor cell showed good electrochemical performance with specific capacitance of 160 F g-1 and an equivalent series resistance (ESR) of 10.2 cm-2 at a current density of 1 mA cm-2. The accessibility to the full capacitance of the device is demonstrated after the addition of CNFc in EMIMP compared to the pristine EMIMP (99 F g-1 and 14.7 cm-2). Keywords: nanocellulose; ionic liquid; ionogel; gel polymer electrolyte; renewable energy storage; supercapacitors Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Sat Jan 15 09:39:56 CET 2022 ModDate: Sat Jan 15 09:44:03 CET 2022 ID: 0xf8dc42198dd22370a908357fbbdb0fd5, 0xf8dc42198dd22370a908357fbbdb0fd5 Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: SPXLNH+PazoMath FontSubset: true FirstChar: 87 LastChar: 87 FontDescriptor: FontName: SPXLNH+PazoMath Flags: Symbolic FontBBox: -40, -283, 878, 946 FontFile: true Font: BaseFont: LTRRAV+VnURWPalladioL-Italic FontSubset: true FirstChar: 160 LastChar: 177 FontDescriptor: FontName: LTRRAV+VnURWPalladioL-Italic Flags: Symbolic FontBBox: -170, -305, 1010, 941 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: OTZEDH+VnURWPalladioL-Bold FontSubset: true FirstChar: 160 LastChar: 189 FontDescriptor: FontName: OTZEDH+VnURWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 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