5893407e2632879e2edbfb8223672d59 Mat_a2023v16p3439.pdf de2190823d2f2c9363a0c02df94d9712cf4199e7 Mat_a2023v16p3439.pdf 8248e5ce5fed8ba0e1ca731b38bc5539ea4749c9a1a6d7cc878102fec5777422 Mat_a2023v16p3439.pdf Title: Nanostructured Thick Electrode Strategies toward Enhanced Electrode–Electrolyte Interfaces Subject: This article addresses the issue of bulk electrode design and the factors limiting the performance of thick electrodes. Indeed, one of the challenges for achieving improved performance in electrochemical energy storage devices (batteries or supercapacitors) is the maximization of the ratio between active and non-active components while maintaining ionic and electronic conductivity of the assembly. In this study, we developed and compared supercapacitor thick electrodes using commercially available carbons and utilising conventional, easily scalable methods such as spray coating and freeze-casting. We also compared different binders and conductive carbons to develop thick electrodes and analysed factors that determine the performance of such thick electrodes, such as porosity and tortuosity. The spray-coated electrodes showed high areal capacitances of 1428 mF cm-2 at 0.3 mm thickness and 2459 F cm-2 at 0.6 mm thickness. Keywords: nanostructure; thick electrode; electrolyte–electrode interface; energy storage; energy density; supercapacitor Author: Anukriti Pokhriyal, Rosa M. González-Gil, Leandro N. Bengoa and Pedro Gómez-Romero Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Fri Apr 28 08:59:29 2023 CEST ModDate: Fri Apr 28 09:20:48 2023 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 17 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 4285112 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- OYABSF+URWPalladioL-Bold Type 1 Custom yes yes no 10 0 WQQJZF+URWPalladioL-Roma Type 1 Custom yes yes no 15 0 CODXQP+URWPalladioL-Ital Type 1 Custom yes yes no 19 0 NAPAFE+CMSY10 Type 1 Builtin yes yes no 23 0 ENXZUH+VnURWPalladioL-Bold Type 1 Custom yes yes no 27 0 YOTXCC+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 47 0 RTEGSV+EURM10 Type 1 Builtin yes yes no 69 0 BCDEEE+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 81 0 BCDFEE+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 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QRADTQ+VnURWPalladioL Type 1 Custom yes yes no 400 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2023-09-27 02:36:29 CEST RepresentationInformation: Mat_a2023v16p3439.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2023-09-26 18:32:22 CEST Size: 4285112 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 586 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Children: Item: Title: Materials Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: Active Slurry for Electrode Preparation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Coating Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Children: Item: Title: Spray Coating Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: Freeze Casting Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Item: Title: Cell Assembly Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1a3869f4 Item: Title: SEM Analysis Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@a38d7a3 Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77f99a05 Children: Item: Title: Morphology Characterization Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@63440df3 Item: Title: Porosity Analysis Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@3aeaafa6 Item: Title: EIS and Tortuosity Calculation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@76a3e297 Item: Title: Electrochemical Characterization Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4d3167f4 Children: Item: Title: Capacitance Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@ed9d034 Item: Title: Specific Energy and Power Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@6121c9d6 Item: Title: Impact of Carbon Additives, Binders and Thickness Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@87f383f Item: Title: Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4eb7f003 Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@eafc191 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@612fc6eb Info: Title: Nanostructured Thick Electrode Strategies toward Enhanced Electrode Electrolyte Interfaces Author: Anukriti Pokhriyal, Rosa M. González-Gil, Leandro N. Bengoa and Pedro Gómez-Romero Subject: This article addresses the issue of bulk electrode design and the factors limiting the performance of thick electrodes. Indeed, one of the challenges for achieving improved performance in electrochemical energy storage devices (batteries or supercapacitors) is the maximization of the ratio between active and non-active components while maintaining ionic and electronic conductivity of the assembly. In this study, we developed and compared supercapacitor thick electrodes using commercially available carbons and utilising conventional, easily scalable methods such as spray coating and freeze-casting. We also compared different binders and conductive carbons to develop thick electrodes and analysed factors that determine the performance of such thick electrodes, such as porosity and tortuosity. The spray-coated electrodes showed high areal capacitances of 1428 mF cm-2 at 0.3 mm thickness and 2459 F cm-2 at 0.6 mm thickness. 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