c0a71bd9a947e08d2184939bfc759aa7 pmc_10051431.pdf 60b5a8737d1205bbba6c0801c2add678290fda10 pmc_10051431.pdf 431685f898e236719abab84abf6a7dc17f32b676db4e5f2e0c2d0e0340e3b4ec pmc_10051431.pdf Title: Asymmetrical Plasmon Distribution in Hybrid AuAg Hollow/Solid Coded Nanotubes Subject: Morphological control at the nanoscale paves the way to fabricate nanostructures with desired plasmonic properties. In this study, we discuss the nanoengineering of plasmon resonances in 1D hollow nanostructures of two different AuAg nanotubes, including completely hollow nanotubes and hybrid nanotubes with solid Ag and hollow AuAg segments. Spatially resolved plasmon mapping by electron energy loss spectroscopy (EELS) revealed the presence of high order resonator-like modes and localized surface plasmon resonance (LSPR) modes in both nanotubes. The experimental findings accurately correlated with the boundary element method (BEM) simulations. Both experiments and simulations revealed that the plasmon resonances are intensely present inside the nanotubes due to plasmon hybridization. Based on the experimental and simulated results, we show that the novel hybrid AuAg nanotubes possess two significant coexisting features: (i) LSPRs are distinctively generated from the hollow and solid parts of the hybrid AuAg nanotube, which creates a way to control a broad range of plasmon resonances with one single nanostructure, and (ii) the periodicity of the high-order modes are disrupted due to the plasmon hybridization by the interaction of solid and hollow parts, resulting in an asymmetrical plasmon distribution in 1D nanostructures. The asymmetry could be modulated/engineered to control the coded plasmonic nanotubes. Keywords: plasmon coded; nanotubes; nanowires; asymmetrical distribution; metal nanotubes; electron energy-loss spectroscopy; AuAg; localized surface plasmon resonances; boundary element method Author: Aziz Genç, Javier Patarroyo, Jordi Sancho-Parramon, Raul Arenal, Neus G. Bastús, Victor Puntes and Jordi Arbiol Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Thu Mar 9 12:15:23 2023 CET ModDate: Thu Mar 9 12:19:01 2023 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 12 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2577399 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- RVAGIN+VnURWPalladioL Type 1 Custom yes yes no 10 0 PLKFHV+URWPalladioL-Bold Type 1 Custom yes yes no 15 0 CPDNGV+URWPalladioL-Roma Type 1 Custom yes yes no 20 0 QJDZXM+URWPalladioL-Ital Type 1 Custom yes yes no 24 0 ENLEMO+VnURWPalladioL-Bold Type 1 Custom yes yes no 28 0 NPLVPL+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 46 0 OVNEXW+EURM10 Type 1 Builtin yes yes no 68 0 JDUPKS+CMSY10 Type 1 Builtin yes yes no 75 0 HOHPPH+PalatinoLinotype-Bold CID TrueType Identity-H yes yes yes 85 0 HOIAAI+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 91 0 HOIACI+PalatinoLinotype-Italic CID TrueType Identity-H yes yes yes 97 0 HOIACJ+PalatinoLinotype-Italic TrueType WinAnsi yes yes no 103 0 HOIACK+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 106 0 HOIACL+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 109 0 HOHPPH+PalatinoLinotype-Bold CID TrueType Identity-H yes yes yes 118 0 HOIAAI+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 124 0 HOIACI+PalatinoLinotype-Italic CID TrueType Identity-H yes yes yes 130 0 HOIACJ+PalatinoLinotype-Italic TrueType WinAnsi yes yes no 136 0 HOIACK+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 139 0 HOIACL+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 142 0 HOHPPH+PalatinoLinotype-Bold CID TrueType Identity-H yes yes yes 160 0 HOIAAI+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 166 0 HOIACI+PalatinoLinotype-Italic CID TrueType Identity-H yes yes yes 172 0 HOIACJ+PalatinoLinotype-Italic TrueType WinAnsi yes yes no 178 0 HOIACK+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 181 0 HOIACL+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 184 0 HOHPPH+PalatinoLinotype-Bold CID TrueType Identity-H yes yes yes 194 0 HOIAAI+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 200 0 HOIACI+PalatinoLinotype-Italic CID TrueType Identity-H yes yes yes 206 0 HOIACJ+PalatinoLinotype-Italic TrueType WinAnsi yes yes no 212 0 HOIACK+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 215 0 HOIACL+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 218 0 HOHPPH+PalatinoLinotype-Bold CID TrueType Identity-H yes yes yes 228 0 HOIAAI+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 234 0 HOIACI+PalatinoLinotype-Italic CID TrueType Identity-H yes yes yes 240 0 HOIACJ+PalatinoLinotype-Italic TrueType WinAnsi yes yes no 246 0 HOIACK+PalatinoLinotype-Bold TrueType WinAnsi yes yes no 249 0 HOIACL+PalatinoLinotype-Roman TrueType WinAnsi yes yes no 252 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2023-10-18 02:23:21 CEST RepresentationInformation: pmc_10051431.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2023-09-22 02:16:43 CEST Size: 2577399 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 472 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Children: Item: Title: Synthesis of 1D AuAg Nanostructures Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Item: Title: EELS Acquisition and Data Processing Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Simulations Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1a3869f4 Info: Title: Asymmetrical Plasmon Distribution in Hybrid AuAg Hollow/Solid Coded Nanotubes Author: Aziz Genç, Javier Patarroyo, Jordi Sancho-Parramon, Raul Arenal, Neus G. Bastús, Victor Puntes and Jordi Arbiol Subject: Morphological control at the nanoscale paves the way to fabricate nanostructures with desired plasmonic properties. In this study, we discuss the nanoengineering of plasmon resonances in 1D hollow nanostructures of two different AuAg nanotubes, including completely hollow nanotubes and hybrid nanotubes with solid Ag and hollow AuAg segments. Spatially resolved plasmon mapping by electron energy loss spectroscopy (EELS) revealed the presence of high order resonator-like modes and localized surface plasmon resonance (LSPR) modes in both nanotubes. The experimental findings accurately correlated with the boundary element method (BEM) simulations. Both experiments and simulations revealed that the plasmon resonances are intensely present inside the nanotubes due to plasmon hybridization. Based on the experimental and simulated results, we show that the novel hybrid AuAg nanotubes possess two significant coexisting features: (i) LSPRs are distinctively generated from the hollow and solid parts of the hybrid AuAg nanotube, which creates a way to control a broad range of plasmon resonances with one single nanostructure, and (ii) the periodicity of the high-order modes are disrupted due to the plasmon hybridization by the interaction of solid and hollow parts, resulting in an asymmetrical plasmon distribution in 1D nanostructures. The asymmetry could be modulated/engineered to control the coded plasmonic nanotubes. Keywords: plasmon coded; nanotubes; nanowires; asymmetrical distribution; metal nanotubes; electron energy-loss spectroscopy; AuAg; localized surface plasmon resonances; boundary element method Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Thu Mar 09 12:15:23 CET 2023 ModDate: Thu Mar 09 12:19:01 CET 2023 ID: 0x3403097d4ad98d07c4fd518c926ccfe5, 0x3403097d4ad98d07c4fd518c926ccfe5 Filters: FilterPipeline: FlateDecode Fonts: Type1: Font: BaseFont: CPDNGV+URWPalladioL-Roma FontSubset: true FirstChar: 2 LastChar: 252 FontDescriptor: FontName: CPDNGV+URWPalladioL-Roma Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: OVNEXW+EURM10 FontSubset: true FirstChar: 22 LastChar: 22 FontDescriptor: FontName: OVNEXW+EURM10 Flags: Symbolic FontBBox: -32, -243, 1060, 720 FontFile: true Font: BaseFont: QJDZXM+URWPalladioL-Ital FontSubset: true FirstChar: 45 LastChar: 121 FontDescriptor: FontName: QJDZXM+URWPalladioL-Ital Flags: Symbolic FontBBox: -170, -305, 1010, 941 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: RVAGIN+VnURWPalladioL FontSubset: true FirstChar: 160 LastChar: 243 FontDescriptor: FontName: RVAGIN+VnURWPalladioL Flags: Symbolic FontBBox: -166, -283, 1021, 943 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: JDUPKS+CMSY10 FontSubset: true FirstChar: 0 LastChar: 6 FontDescriptor: FontName: JDUPKS+CMSY10 Flags: Symbolic FontBBox: -29, -960, 1116, 775 FontFile: true Font: BaseFont: ENLEMO+VnURWPalladioL-Bold FontSubset: true FirstChar: 243 LastChar: 243 FontDescriptor: FontName: ENLEMO+VnURWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Font: BaseFont: PLKFHV+URWPalladioL-Bold FontSubset: true FirstChar: 3 LastChar: 231 FontDescriptor: FontName: PLKFHV+URWPalladioL-Bold Flags: Symbolic FontBBox: -152, -301, 1000, 935 FontFile: true EncodingDictionary: Differences: true Pages: Page: Sequence: 1 Annotations: Annotation: Subtype: Link Rect: 79, 291, 152, 300 Annotation: Subtype: Link Rect: 34, 280, 106, 288 Annotation: Subtype: Link Rect: 34, 164, 96, 186 Annotation: Subtype: Link Rect: 126, 90, 154, 99 Annotation: Subtype: Link Rect: 34, 78, 147, 87 Annotation: Subtype: Link Rect: 34, 756, 171, 792 Annotation: Subtype: Link Rect: 515, 756, 560, 792 Annotation: Subtype: Link Rect: 88, 662, 99, 676 Annotation: Subtype: Link Rect: 182, 662, 193, 676 Annotation: Subtype: Link Rect: 389, 662, 400, 676 Annotation: Subtype: Link Rect: 479, 662, 490, 676 Annotation: Subtype: Link Rect: 213, 650, 224, 663 Annotation: Subtype: Link Rect: 375, 200, 382, 209 ActionDest: 257 Annotation: Subtype: Link Rect: 458, 174, 465, 183 ActionDest: 257 Annotation: Subtype: Link Rect: 465, 174, 472, 183 ActionDest: 257 Annotation: Subtype: Link Rect: 298, 162, 305, 171 ActionDest: 257 Annotation: Subtype: Link Rect: 306, 162, 313, 171 ActionDest: 257 Annotation: Subtype: Link Rect: 382, 162, 389, 171 ActionDest: 257 Annotation: Subtype: Link Rect: 483, 162, 490, 171 ActionDest: 257 Annotation: Subtype: Link Rect: 491, 162, 498, 171 ActionDest: 257 Annotation: Subtype: Link Rect: 355, 137, 362, 146 ActionDest: 257 Annotation: Subtype: Link Rect: 362, 137, 374, 146 ActionDest: 257 Annotation: Subtype: Link Rect: 412, 99, 424, 108 ActionDest: 257 Annotation: Subtype: Link Rect: 427, 99, 439, 108 ActionDest: 257 Annotation: Subtype: Link Rect: 237, 74, 249, 83 ActionDest: 257 Annotation: Subtype: Link Rect: 249, 74, 261, 83 ActionDest: 257 Annotation: Subtype: Link Rect: 132, 17, 274, 28 Annotation: Subtype: Link Rect: 386, 17, 560, 28 Annotation: Subtype: Link Rect: 34, 377, 87, 396 Page: Sequence: 2 Annotations: Annotation: Subtype: Link Rect: 279, 736, 291, 744 ActionDest: 257 Annotation: Subtype: Link Rect: 291, 736, 303, 744 ActionDest: 260 Annotation: Subtype: Link Rect: 481, 710, 488, 719 ActionDest: 257 Annotation: Subtype: Link Rect: 488, 710, 500, 719 ActionDest: 260 Annotation: Subtype: Link Rect: 501, 710, 513, 719 ActionDest: 260 Annotation: Subtype: Link Rect: 309, 685, 321, 694 ActionDest: 260 Annotation: Subtype: Link Rect: 324, 685, 336, 694 ActionDest: 260 Annotation: Subtype: Link Rect: 402, 660, 414, 669 ActionDest: 260 Annotation: Subtype: Link Rect: 417, 660, 429, 669 ActionDest: 260 Annotation: Subtype: Link Rect: 252, 635, 264, 644 ActionDest: 260 Annotation: Subtype: Link Rect: 267, 635, 279, 644 ActionDest: 260 Annotation: Subtype: Link Rect: 360, 610, 372, 619 ActionDest: 260 Annotation: Subtype: Link Rect: 375, 610, 387, 619 ActionDest: 260 Annotation: Subtype: Link Rect: 462, 597, 474, 606 ActionDest: 260 Annotation: Subtype: Link Rect: 544, 597, 556, 606 ActionDest: 260 Annotation: Subtype: Link Rect: 383, 560, 395, 569 ActionDest: 260 Annotation: Subtype: Link Rect: 192, 535, 204, 544 ActionDest: 260 Annotation: Subtype: Link Rect: 181, 270, 193, 279 ActionDest: 260 Annotation: Subtype: Link Rect: 212, 245, 224, 254 ActionDest: 260 Page: Sequence: 3 Annotations: Annotation: Subtype: Link Rect: 275, 647, 287, 656 ActionDest: 260 Annotation: Subtype: Link Rect: 349, 572, 361, 581 ActionDest: 260 Annotation: Subtype: Link Rect: 361, 572, 373, 581 ActionDest: 260 Annotation: Subtype: Link Rect: 296, 534, 308, 543 ActionDest: 260 Annotation: Subtype: Link Rect: 308, 534, 320, 543 ActionDest: 260 Annotation: Subtype: Link Rect: 323, 534, 335, 543 ActionDest: 264 Annotation: Subtype: Link Rect: 544, 534, 556, 543 ActionDest: 264 Annotation: Subtype: Link Rect: 479, 484, 491, 493 ActionDest: 264 Annotation: Subtype: Link Rect: 491, 484, 503, 493 ActionDest: 264 Annotation: Subtype: Link Rect: 520, 446, 532, 455 ActionDest: 264 Annotation: Subtype: Link Rect: 483, 433, 495, 443 ActionDest: 264 Annotation: Subtype: Link Rect: 248, 421, 260, 430 ActionDest: 264 Annotation: Subtype: Link Rect: 294, 383, 306, 392 ActionDest: 264 Annotation: Subtype: Link Rect: 207, 330, 214, 342 ActionDest: 79 Annotation: Subtype: Link Rect: 319, 330, 326, 342 ActionDest: 79 Annotation: Subtype: Link Rect: 542, 217, 549, 229 ActionDest: 79 Annotation: Subtype: Link Rect: 195, 142, 202, 154 ActionDest: 79 Annotation: Subtype: Link Rect: 400, 119, 412, 128 ActionDest: 260 Annotation: Subtype: Link Rect: 544, 119, 556, 128 ActionDest: 264 Page: Sequence: 4 Annotations: Annotation: Subtype: Link Rect: 505, 472, 512, 484 ActionDest: 79 Annotation: Subtype: Link Rect: 408, 446, 415, 458 ActionDest: 79 Annotation: Subtype: Link Rect: 388, 421, 395, 433 ActionDest: 79 Annotation: Subtype: Link Rect: 439, 421, 446, 433 ActionDest: 79 Annotation: Subtype: Link Rect: 500, 409, 507, 421 ActionDest: 79 Annotation: Subtype: Link Rect: 408, 374, 420, 383 ActionDest: 264 Page: Sequence: 5 Annotations: Annotation: Subtype: Link Rect: 444, 720, 451, 732 ActionDest: 79 Annotation: Subtype: Link Rect: 220, 673, 232, 682 ActionDest: 264 Annotation: Subtype: Link Rect: 195, 657, 202, 669 ActionDest: 79 Annotation: Subtype: Link Rect: 442, 657, 449, 669 ActionDest: 79 Annotation: Subtype: Link Rect: 312, 635, 324, 644 ActionDest: 264 Annotation: Subtype: Link Rect: 261, 509, 273, 519 ActionDest: 260 Annotation: Subtype: Link Rect: 543, 469, 551, 481 ActionDest: 79 Annotation: Subtype: Link Rect: 388, 384, 400, 393 ActionDest: 257 Annotation: Subtype: Link Rect: 401, 384, 412, 393 ActionDest: 257 Annotation: Subtype: Link Rect: 413, 384, 425, 393 ActionDest: 257 Annotation: Subtype: Link Rect: 425, 384, 437, 393 ActionDest: 260 Annotation: Subtype: Link Rect: 231, 281, 238, 293 ActionDest: 154 Annotation: Subtype: Link Rect: 425, 243, 432, 255 ActionDest: 79 Annotation: Subtype: Link Rect: 197, 206, 204, 218 ActionDest: 154 Annotation: Subtype: Link Rect: 267, 193, 274, 205 ActionDest: 154 Annotation: Subtype: Link Rect: 373, 133, 385, 142 ActionDest: 264 Annotation: Subtype: Link Rect: 241, 108, 253, 117 ActionDest: 264 Annotation: Subtype: Link Rect: 254, 108, 266, 117 ActionDest: 264 Page: Sequence: 6 Annotations: Annotation: Subtype: Link Rect: 395, 733, 402, 745 ActionDest: 154 Annotation: Subtype: Link Rect: 361, 695, 368, 707 ActionDest: 79 Annotation: Subtype: Link Rect: 459, 635, 471, 644 ActionDest: 264 Annotation: Subtype: Link Rect: 474, 635, 486, 644 ActionDest: 264 Annotation: Subtype: Link Rect: 497, 620, 504, 632 ActionDest: 154 Annotation: Subtype: Link Rect: 301, 570, 308, 582 ActionDest: 154 Annotation: Subtype: Link Rect: 218, 406, 225, 418 ActionDest: 188 Annotation: Subtype: Link Rect: 515, 394, 523, 406 ActionDest: 188 Annotation: Subtype: Link Rect: 197, 369, 204, 381 ActionDest: 188 Annotation: Subtype: Link Rect: 211, 356, 218, 368 ActionDest: 188 Annotation: Subtype: Link Rect: 218, 243, 225, 255 ActionDest: 188 Annotation: Subtype: Link Rect: 250, 206, 257, 218 ActionDest: 188 Annotation: Subtype: Link Rect: 476, 206, 483, 218 ActionDest: 188 Page: Sequence: 7 Annotations: Annotation: Subtype: Link Rect: 219, 735, 231, 744 ActionDest: 260 Annotation: Subtype: Link Rect: 218, 698, 230, 707 ActionDest: 264 Annotation: Subtype: Link Rect: 494, 673, 506, 682 ActionDest: 260 Annotation: Subtype: Link Rect: 507, 673, 519, 682 ActionDest: 264 Annotation: Subtype: Link Rect: 522, 673, 534, 682 ActionDest: 264 Annotation: Subtype: Link Rect: 275, 660, 287, 669 ActionDest: 264 Page: Sequence: 8 Annotations: Annotation: Subtype: Link Rect: 217, 424, 224, 436 ActionDest: 222 Annotation: Subtype: Link Rect: 256, 412, 263, 424 ActionDest: 188 Annotation: Subtype: Link Rect: 304, 336, 311, 348 ActionDest: 222 Annotation: Subtype: Link Rect: 325, 286, 333, 298 ActionDest: 222 Annotation: Subtype: Link Rect: 457, 261, 464, 273 ActionDest: 188 Annotation: Subtype: Link Rect: 281, 135, 288, 147 ActionDest: 222 Annotation: Subtype: Link Rect: 206, 88, 218, 97 ActionDest: 264 Page: Sequence: 9 Annotations: Annotation: Subtype: Link Rect: 489, 371, 501, 380 ActionDest: 264 Annotation: Subtype: Link Rect: 536, 81, 560, 92 Annotation: Subtype: Link Rect: 165, 69, 377, 80 Page: Sequence: 10 Annotations: Annotation: Subtype: Link Rect: 353, 723, 364, 732 ActionDest: 260 Annotation: Subtype: Link Rect: 364, 723, 375, 732 ActionDest: 260 Annotation: Subtype: Link Rect: 375, 723, 386, 732 ActionDest: 264 Annotation: Subtype: Link Rect: 386, 723, 397, 732 ActionDest: 264 Annotation: Subtype: Link Rect: 165, 457, 332, 468 Annotation: Subtype: Link Rect: 481, 348, 519, 359 Annotation: Subtype: Link Rect: 475, 336, 513, 347 Annotation: Subtype: Link Rect: 417, 313, 454, 324 Annotation: Subtype: Link Rect: 280, 290, 318, 301 Annotation: Subtype: Link Rect: 248, 267, 285, 278 Annotation: Subtype: Link Rect: 520, 255, 557, 266 Annotation: Subtype: Link Rect: 467, 244, 505, 255 Annotation: Subtype: Link Rect: 175, 222, 212, 232 Annotation: Subtype: Link Rect: 475, 209, 513, 220 Annotation: Subtype: Link Rect: 231, 186, 269, 197 Annotation: Subtype: Link Rect: 434, 175, 472, 186 Annotation: Subtype: Link Rect: 358, 163, 396, 174 Annotation: Subtype: Link Rect: 95, 130, 132, 140 Annotation: Subtype: Link Rect: 397, 106, 434, 117 Annotation: Subtype: Link Rect: 364, 83, 401, 94 Annotation: Subtype: Link Rect: 304, 60, 341, 71 Page: Sequence: 11 Annotations: Annotation: Subtype: Link Rect: 439, 722, 477, 733 Annotation: Subtype: Link Rect: 59, 699, 96, 710 Annotation: Subtype: Link Rect: 494, 676, 531, 687 Annotation: Subtype: Link Rect: 95, 653, 133, 664 Annotation: Subtype: Link Rect: 268, 630, 306, 640 Annotation: Subtype: Link Rect: 237, 607, 274, 617 Annotation: Subtype: Link Rect: 184, 584, 222, 594 Annotation: Subtype: Link Rect: 104, 561, 142, 571 Annotation: Subtype: Link Rect: 245, 527, 282, 537 Annotation: Subtype: Link Rect: 359, 503, 397, 514 Annotation: Subtype: Link Rect: 484, 480, 522, 491 Annotation: Subtype: Link Rect: 362, 457, 399, 468 Annotation: Subtype: Link Rect: 299, 435, 336, 445 Annotation: Subtype: Link Rect: 173, 412, 211, 422 Annotation: Subtype: Link Rect: 471, 388, 508, 399 Annotation: Subtype: Link Rect: 95, 354, 133, 364 Annotation: Subtype: Link Rect: 452, 330, 490, 341 Annotation: Subtype: Link Rect: 122, 297, 160, 307 Annotation: Subtype: Link Rect: 423, 273, 460, 284 Annotation: Subtype: Link Rect: 164, 251, 202, 261 Annotation: Subtype: Link Rect: 226, 228, 264, 238 Annotation: Subtype: Link Rect: 339, 204, 377, 215 Annotation: Subtype: Link Rect: 227, 181, 265, 192 Annotation: Subtype: Link Rect: 409, 158, 446, 169 Annotation: Subtype: Link Rect: 446, 146, 483, 157 Annotation: Subtype: Link Rect: 95, 124, 133, 134 Annotation: Subtype: Link Rect: 490, 100, 527, 111 Annotation: Subtype: Link Rect: 182, 78, 219, 88 Annotation: Subtype: Link Rect: 491, 66, 529, 77 Page: Sequence: 12 Annotations: Annotation: Subtype: Link Rect: 173, 710, 211, 721 Annotation: Subtype: Link Rect: 406, 687, 443, 698 Annotation: Subtype: Link Rect: 247, 664, 285, 675 Annotation: Subtype: Link Rect: 95, 642, 133, 652 Annotation: Subtype: Link Rect: 104, 619, 141, 629 Annotation: Subtype: Link Rect: 449, 606, 486, 617 Annotation: Subtype: Link Rect: 230, 583, 267, 594 Annotation: Subtype: Link Rect: 239, 560, 277, 571 Annotation: Subtype: Link Rect: 193, 527, 231, 537 Annotation: Subtype: Link Rect: 359, 492, 397, 502 Annotation: Subtype: Link Rect: 438, 468, 476, 479 Annotation: Subtype: Link Rect: 122, 446, 159, 456 Annotation: Subtype: Link Rect: 329, 422, 367, 433 Annotation: Subtype: Link Rect: 210, 399, 248, 410 Annotation: Subtype: Link Rect: 483, 376, 520, 387 Annotation: Subtype: Link Rect: 104, 343, 142, 353 Annotation: Subtype: Link Rect: 386, 319, 423, 330 Annotation: Subtype: Link Rect: 298, 296, 335, 307 Annotation: Subtype: Link Rect: 270, 261, 308, 272 Annotation: Subtype: Link Rect: 161, 239, 199, 249 Annotation: Subtype: Link Rect: 357, 215, 395, 226 Annotation: Subtype: Link Rect: 108, 182, 146, 192 Checksum: 4f322a49 Type: CRC32 Checksum: c0a71bd9a947e08d2184939bfc759aa7 Type: MD5 Checksum: 60b5a8737d1205bbba6c0801c2add678290fda10 Type: SHA-1