1e50af9283ad4d69955005f3522fcfff pmc_10421052.pdf 9652b195a5ff8fb6c3bc6c909296c5e10d1527cb pmc_10421052.pdf e91629aa5640ba0953cf8da24d871b6245b0b618ff5b0baefb0e395c8bafa8f0 pmc_10421052.pdf Title: Polyoxometalate-Stabilized Silver Nanoparticles and Hybrid Electrode Assembly Using Activated Carbon Subject: The intersection between the field of hybrid materials and that of electrochemistry is a quickly expanding area. Hybrid combinations usually consist of two constituents, but new routes toward more complex and versatile electroactive hybrid designs are quickly emerging. The objective of the present work is to explore novel triple hybrid material integrating polyoxometalates (POMs), silver nanoparticles (Ag0 NPs), and activated carbon (AC) and to demonstrate its use as a hybrid electrode in a symmetric supercapacitor. The tri-component nanohybrid (AC/POM-Ag0 NPs) was fabricated through the combination of AC with pre-synthesized 27 nm POM-protected Ag0 NPs (POM-Ag0 NPs). The POM-Ag0 NPs were prepared using a green electrochemical method and characterized via UV-vis and IR spectroscopy, electron microscopy, dynamic light scattering (DLS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). Afterward, the AC/POM-Ag0 NPs ternary nanocomposite material was constructed and characterized. The electrochemical behavior of AC/POM-Ag0 NPs’ modified electrodes reveal that the nanomaterial is electroactive and exhibits a moderately higher specific capacitance (81 F/g after 20 cycles) than bare AC electrodes (75 F/g) in a symmetrical supercapacitor configuration in the voltage range 0 to 0.75 V and 20 mV/s, demonstrating the potential use of this type of tri-component nanohybrid for electrochemical applications. Keywords: hybrid nanomaterials; triple hybrid materials; polyoxometalate; Ag nanoparticles; activated carbon; electroactive materials; supercapacitor Author: Sara Goberna-Ferrón, Laia Cots, Marta Perxés Perich, Jun-Jie Zhu and Pedro Gómez-Romero Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Thu Aug 3 08:04:22 2023 CEST ModDate: Thu Aug 3 08:12:21 2023 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 17 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 8430934 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- YWGGLO+VnURWPalladioL Type 1 Custom yes yes no 10 0 ZKLXOW+URWPalladioL-Bold Type 1 Custom yes yes no 15 0 CDPUCR+URWPalladioL-Roma Type 1 Custom yes yes no 20 0 TQOVHS+URWPalladioL-Ital Type 1 Custom yes yes no 24 0 DDGJVR+CMSY10 Type 1 Builtin yes yes no 28 0 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Size: 8430934 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 682 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Children: Item: Title: Synthesis of POM-Ag0 NPs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Children: Item: Title: Preparation of Reduced POM Solutions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Synthesis of NPs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: Preparation of Hybrid Material Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: Preparation of Hybrid Electrodes and Assembly of Coin Cells Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Item: Title: Instrumentation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1a3869f4 Item: Title: Results and Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@a38d7a3 Children: Item: Title: Synthesis and Morphological Characterization of POM-Ag0 NPs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77f99a05 Children: Item: Title: Influence of the Concentration of Ag+ Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@63440df3 Item: Title: Influence of the Reducing Power of the POM Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@3aeaafa6 Item: Title: Physicochemical Characterization of POM-Ag0 NPs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@76a3e297 Children: Item: Title: Identification of Metallic Silver on POM-Ag0 NPs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4d3167f4 Item: Title: Presence of POM on POM-Ag0 NPs Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@ed9d034 Item: Title: Preparation and Characterization of AC/POM-Ag0 NPs Hybrid Material Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@6121c9d6 Children: Item: Title: Physisorption of POM-Ag0 NPs on AC Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@87f383f Item: Title: Electrochemical Properties of Hybrid Electrodes Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@4eb7f003 Item: Title: Conclusions Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@eafc191 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@612fc6eb Info: Title: Polyoxometalate-Stabilized Silver Nanoparticles and Hybrid Electrode Assembly Using Activated Carbon Author: Sara Goberna-Ferrón, Laia Cots, Marta Perxés Perich, Jun-Jie Zhu and Pedro Gómez-Romero Subject: The intersection between the field of hybrid materials and that of electrochemistry is a quickly expanding area. Hybrid combinations usually consist of two constituents, but new routes toward more complex and versatile electroactive hybrid designs are quickly emerging. The objective of the present work is to explore novel triple hybrid material integrating polyoxometalates (POMs), silver nanoparticles (Ag0 NPs), and activated carbon (AC) and to demonstrate its use as a hybrid electrode in a symmetric supercapacitor. The tri-component nanohybrid (AC/POM-Ag0 NPs) was fabricated through the combination of AC with pre-synthesized 27 nm POM-protected Ag0 NPs (POM-Ag0 NPs). The POM-Ag0 NPs were prepared using a green electrochemical method and characterized via UV-vis and IR spectroscopy, electron microscopy, dynamic light scattering (DLS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV). Afterward, the AC/POM-Ag0 NPs ternary nanocomposite material was constructed and characterized. The electrochemical behavior of AC/POM-Ag0 NPs’ modified electrodes reveal that the nanomaterial is electroactive and exhibits a moderately higher specific capacitance (81 F/g after 20 cycles) than bare AC electrodes (75 F/g) in a symmetrical supercapacitor configuration in the voltage range 0 to 0.75 V and 20 mV/s, demonstrating the potential use of this type of tri-component nanohybrid for electrochemical applications. 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