a3bb15ab856b047046b1f3de3e34c10e pmc_10609106.pdf 63e390d8ed35d73ffade6ee64df0425f0c884f4a pmc_10609106.pdf 0c939dac047af3248ee06c96af5533469c44aef88141b6a13676cad8bedfa284 pmc_10609106.pdf Title: Recent Advances in the Catalytic Conversion of Methane to Methanol: From the Challenges of Traditional Catalysts to the Use of Nanomaterials and Metal-Organic Frameworks Subject: Methane and carbon dioxide are the main contributors to global warming, with the methane effect being 25 times more powerful than carbon dioxide. Although the sources of methane are diverse, it is a very volatile and explosive gas. One way to store the energy content of methane is through its conversion to methanol. Methanol is a liquid under ambient conditions, easy to transport, and, apart from its use as an energy source, it is a chemical platform that can serve as a starting material for the production of various higher-value products. Accordingly, the transformation of methane to methanol has been extensively studied in the literature, using traditional catalysts as different types of zeolites. However, in the last few years, a new generation of catalysts has emerged to carry out this transformation with higher conversion and selectivity, and more importantly, under mild temperature and pressure conditions. These new catalysts typically involve the use of a highly porous supporting material such as zeolite, or more recently, metal-organic frameworks (MOFs) and graphene, and metallic nanoparticles or a combination of different types of nanoparticles that are the core of the catalytic process. In this review, recent advances in the porous supports for nanoparticles used for methane oxidation to methanol under mild conditions are discussed. Keywords: methane oxidation; catalysis; global warming; nanoparticles; metal-organic frameworks; renewable energy; zeolite; methanol synthesis Author: Seyed Alireza Vali, Ahmad Abo Markeb, Javier Moral-Vico, Xavier Font and Antoni Sánchez Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Fri Oct 13 11:27:54 2023 CEST ModDate: Fri Oct 13 11:35:29 2023 CEST Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 24 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2349971 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- BCTLSH+URWPalladioL-Bold Type 1 Custom yes yes no 10 0 GIOGPZ+URWPalladioL-Roma Type 1 Custom yes yes no 15 0 EEXYLG+URWPalladioL-Ital Type 1 Custom yes yes no 19 0 AIQCCL+VnURWPalladioL-Bold Type 1 Custom yes yes no 23 0 ARIQJE+VnURWPalladioL Type 1 Custom yes yes no 28 0 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application/pdf PDFMetadata: Objects: 698 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: section.1 Item: Title: Conversion of Methane to Methanol Routes Destination: section.2 Children: Item: Title: Direct and Indirect Routes Destination: subsection.2.1 Item: Title: Challenging Parameters in Methane to Methanol Catalysis Destination: subsection.2.2 Children: Item: Title: Activation of C-H Bonds and Its Connection to Selectivity Destination: subsubsection.2.2.1 Item: Title: Activation of Catalyst Destination: subsubsection.2.2.2 Item: Title: Temperature and Pressure Destination: subsubsection.2.2.3 Item: Title: Traditional Catalysts Destination: section.3 Item: Title: Nanoparticles-Based Novel Catalysts Destination: section.4 Children: Item: Title: Nanomaterials Used with Zeolite Destination: subsection.4.1 Item: Title: Graphene-Based Catalysts Destination: subsection.4.2 Item: Title: Nanomaterials Used with MOFs Destination: subsection.4.3 Children: Item: Title: General Characteristics Destination: subsubsection.4.3.1 Item: Title: Potentials and Limitations Destination: subsubsection.4.3.2 Item: Title: Other Nanocatalysts Destination: subsection.4.4 Item: Title: Stability and Reusability of Catalysts Destination: section.5 Item: Title: Reactors Used for Methane to Methanol Catalysis Destination: section.6 Children: Item: Title: Fixed-Bed Reactor Destination: subsection.6.1 Item: Title: Fluidized-Bed Reactor Destination: subsection.6.2 Item: Title: Wall-Coated Reactors Destination: subsection.6.3 Children: Item: Title: Tubular Reactor Type Destination: subsubsection.6.3.1 Item: Title: Monolithic Reactor Type Destination: subsubsection.6.3.2 Item: Title: Plate-Type Reactor Type Destination: subsubsection.6.3.3 Item: Title: Microchannel Plate Type Reactor Destination: subsubsection.6.3.4 Item: Title: Membrane Reactor Destination: subsection.6.4 Item: Title: Summaries and Perspectives Destination: section.7 Item: Title: References Destination: section.8 Info: Title: Recent Advances in the Catalytic Conversion of Methane to Methanol: From the Challenges of Traditional Catalysts to the Use of Nanomaterials and Metal-Organic Frameworks Author: Seyed Alireza Vali, Ahmad Abo Markeb, Javier Moral-Vico, Xavier Font and Antoni Sánchez Subject: Methane and carbon dioxide are the main contributors to global warming, with the methane effect being 25 times more powerful than carbon dioxide. Although the sources of methane are diverse, it is a very volatile and explosive gas. One way to store the energy content of methane is through its conversion to methanol. Methanol is a liquid under ambient conditions, easy to transport, and, apart from its use as an energy source, it is a chemical platform that can serve as a starting material for the production of various higher-value products. Accordingly, the transformation of methane to methanol has been extensively studied in the literature, using traditional catalysts as different types of zeolites. However, in the last few years, a new generation of catalysts has emerged to carry out this transformation with higher conversion and selectivity, and more importantly, under mild temperature and pressure conditions. These new catalysts typically involve the use of a highly porous supporting material such as zeolite, or more recently, metal-organic frameworks (MOFs) and graphene, and metallic nanoparticles or a combination of different types of nanoparticles that are the core of the catalytic process. In this review, recent advances in the porous supports for nanoparticles used for methane oxidation to methanol under mild conditions are discussed. 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