8668f9a9b3b8888fe567d50492f69eed pmc_9920478.pdf 90f744b44d7190d4d47311207c0cc8069bfcf5d9 pmc_9920478.pdf a18c996d073f02456f0438c74dfa9186e29c86f84b20f1c0f438562d03771957 pmc_9920478.pdf Title: Electrochemical Synthesis, Magnetic and Optical Characterisation of FePd Dense and Mesoporous Nanowires Subject: Dense and mesoporous FePd nanowires (NWs) with 45 to 60 at.% Pd content were successfully fabricated by template- and micelle-assisted pulsed potentiostatic electrodeposition using nanoporous anodic alumina and polycarbonate templates of varying pore sizes. An FePd electrolyte was utilized for obtaining dense NWs while a block copolymer, P-123, was added to this electrolyte as the micelle-forming surfactant to produce mesoporous NWs. The structural and magnetic properties of the NWs were investigated by electron microscopy, X-ray diffraction, and vibrating sample magnetometry. The as-prepared NWs were single phase with a face-centered cubic structure exhibiting 3.1 m to 7.1 m of length. Mesoporous NWs revealed a core-shell structure where the porosity was only witnessed in the internal volume of the NW while the outer surface remained non-porous. Magnetic measurements revealed that the samples displayed a soft ferromagnetic behavior that depended on the shape anisotropy and the interwire dipolar interactions. The mesoporous core and dense shell structure of the NWs were seen to be slightly affecting the magnetic properties. Moreover, mesoporous NWs performed excellently as SERS substrates for the detection of 4,4'-bipyridine, showing a low detection limit of 10-12 M. The signal enhancement can be attributed to the mesoporous morphology as well as the close proximity of the embedded NWs being conducive to localized surface plasmon resonance. Keywords: nanowires; FePd; mesoporous; electrodeposition; SERS Author: Deepti Raj, Gabriele Barrera, Federico Scaglione, Federica Celegato, Matteo Cialone, Marco Coïsson, Paola Tiberto, Jordi Sort, Paola Rizzi and Eva Pellicer Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Thu Jan 19 03:57:06 2023 CET ModDate: Thu Jan 19 07:18:45 2023 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 18 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 4142233 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- ZPASQY+VnURWPalladioL Type 1 Custom yes yes no 10 0 YSCNED+EURM10 Type 1 Builtin yes yes no 15 0 SGDMIZ+URWPalladioL-Bold Type 1 Custom yes yes no 19 0 CFWFRM+URWPalladioL-Roma Type 1 Custom yes yes no 24 0 LPYMZX+URWPalladioL-Ital Type 1 Custom yes yes no 28 0 VMJQPT+CMSY10 Type 1 Builtin yes yes no 32 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BCDHEE+PalatinoLinotype-Roman CID TrueType Identity-H yes yes yes 386 0 Jhove (Rel. 1.28.0, 2023-05-18) Date: 2024-01-12 02:29:42 CET RepresentationInformation: pmc_9920478.pdf ReportingModule: PDF-hul, Rel. 1.12.4 (2023-03-16) LastModified: 2023-03-23 02:12:25 CET Size: 4142233 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 616 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: section.1 Item: Title: Materials and Methods Destination: section.2 Item: Title: Results and Discussion Destination: section.3 Children: Item: Title: Dense Nanowires Destination: subsection.3.1 Item: Title: Mesoporous Nanowires Destination: subsection.3.2 Item: Title: Magnetic Studies Destination: subsection.3.3 Item: Title: SERS Studies Destination: subsection.3.4 Item: Title: Conclusions Destination: section.4 Item: Title: References Destination: section.4 Info: Title: Electrochemical Synthesis, Magnetic and Optical Characterisation of FePd Dense and Mesoporous Nanowires Author: Deepti Raj, Gabriele Barrera, Federico Scaglione, Federica Celegato, Matteo Cialone, Marco Coïsson, Paola Tiberto, Jordi Sort, Paola Rizzi and Eva Pellicer Subject: Dense and mesoporous FePd nanowires (NWs) with 45 to 60 at.% Pd content were successfully fabricated by template- and micelle-assisted pulsed potentiostatic electrodeposition using nanoporous anodic alumina and polycarbonate templates of varying pore sizes. An FePd electrolyte was utilized for obtaining dense NWs while a block copolymer, P-123, was added to this electrolyte as the micelle-forming surfactant to produce mesoporous NWs. The structural and magnetic properties of the NWs were investigated by electron microscopy, X-ray diffraction, and vibrating sample magnetometry. The as-prepared NWs were single phase with a face-centered cubic structure exhibiting 3.1 m to 7.1 m of length. Mesoporous NWs revealed a core-shell structure where the porosity was only witnessed in the internal volume of the NW while the outer surface remained non-porous. Magnetic measurements revealed that the samples displayed a soft ferromagnetic behavior that depended on the shape anisotropy and the interwire dipolar interactions. The mesoporous core and dense shell structure of the NWs were seen to be slightly affecting the magnetic properties. Moreover, mesoporous NWs performed excellently as SERS substrates for the detection of 4,4'-bipyridine, showing a low detection limit of 10-12 M. The signal enhancement can be attributed to the mesoporous morphology as well as the close proximity of the embedded NWs being conducive to localized surface plasmon resonance. 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