e436d6ee57f06cebae4402c178f4322c pmc_9960183.pdf 498106a0b484525e92a292f3f650084f57469d94 pmc_9960183.pdf c83202b9efc568091500e7fc48e3b25ea2dd248f9a94d25346bd7ab0ab4dd23d pmc_9960183.pdf Title: 13C, 25Mg, and 43Ca Solid-State NMR for the Purpose of Dolomitic Marbles Provenance Elucidation Subject: The study of the provenance of dolomitic marble artefacts has become relevant since it was discovered that quarries of this marble other than that of Cape-Vathy located on the island of Thasos have been exploited since Antiquity. To improve our knowledge about the provenance of materials and the extent of their dispersion, multiple archaeometric studies were performed in the past including isotope analyses, petrography, cathodoluminescence, and elemental analyses. In the present work, solid-state nuclear magnetic resonance (NMR) spectroscopy has been added to this panel of techniques. NMR allows the characterization of the material at a molecular level by looking at different nuclei: carbon, magnesium, and calcium. Statistical analysis of the data collected on both quarry samples and archaeologic items was also implemented and clearly demonstrates the efficiency of a holistic approach for provenance elucidation. Finally, the first 25Mg NMR tests have shown the potential of this technique to discriminate between dolomitic marbles of different provenance. The results are discussed in terms of their historical meaning and illustrate the exploitation of sources of dolomitic marbles other than the Greek Thasos source. Keywords: marble; dolomite; elemental analysis; principal component analysis; NMR; provenance Author: Isabelle Pianet, Anna Gutiérrez Garcia-Moreno, Marie-Claire Savin, Nicolas Frerebeau, Julien Trebosc, Pierre Florian and M. Pilar Lapuente Mercadal Creator: LaTeX with hyperref Producer: pdfTeX-1.40.21 CreationDate: Tue Feb 21 08:50:37 2023 CET ModDate: Tue Feb 21 08:56:04 2023 CET Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 14 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 4102837 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- YSPQJI+VnURWPalladioL-Bold Type 1 Custom yes yes no 10 0 WKXZYH+VnURWPalladioL Type 1 Custom yes yes no 15 0 DBFGHS+URWPalladioL-Bold Type 1 Custom yes yes no 19 0 ALJYHV+URWPalladioL-Roma Type 1 Custom yes yes no 24 0 NEVYUL+URWPalladioL-Ital Type 1 Custom yes yes no 28 0 YOTXCC+TimesNewRomanPS-BoldItalicMT Type 1C WinAnsi yes yes no 47 0 QMDDXF+CMSY10 Type 1 Builtin yes yes no 72 0 GWVEJJ+EURM10 Type 1 Builtin yes yes no 76 0 MPUDFL+PazoMath Type 1 Builtin yes yes no 86 0 IVAZRX+EURB10 Type 1 Builtin yes yes no 99 0 PDXFNG+PazoMath-Bold Type 1 Builtin yes yes no 103 0 LELMNU+VnURWPalladioL-Italic Type 1 Custom yes yes no 141 0 Jhove (Rel. 1.22.1, 2019-04-17) Date: 2023-03-24 02:33:18 CET RepresentationInformation: pmc_9960183.pdf ReportingModule: PDF-hul, Rel. 1.12.1 (2019-04-17) LastModified: 2023-03-09 02:13:54 CET Size: 4102837 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 294 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@44c8afef Item: Title: Materials and Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7b69c6ba Children: Item: Title: Materials Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@46daef40 Item: Title: Analytical Methods Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@12f41634 Children: Item: Title: NMR Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@13c27452 Item: Title: Elemental Analysis Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@262b2c86 Item: Title: Statistical Software Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@371a67ec Item: Title: Results Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@5ed828d Children: Item: Title: Solid-State NMR Investigation Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@50d0686 Item: Title: Elemental Analysis Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@7a3d45bd Item: Title: Statistical Analysis Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1e7c7811 Item: Title: Discussion Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@77ec78b9 Item: Title: References Destination: edu.harvard.hul.ois.jhove.module.pdf.PdfSimpleObject@1a3869f4 Info: Title: 13C, 25Mg, and 43Ca Solid-State NMR for the Purpose of Dolomitic Marbles Provenance Elucidation Author: Isabelle Pianet, Anna Gutiérrez Garcia-Moreno, Marie-Claire Savin, Nicolas Frerebeau, Julien Trebosc, Pierre Florian and M. Pilar Lapuente Mercadal Subject: The study of the provenance of dolomitic marble artefacts has become relevant since it was discovered that quarries of this marble other than that of Cape-Vathy located on the island of Thasos have been exploited since Antiquity. To improve our knowledge about the provenance of materials and the extent of their dispersion, multiple archaeometric studies were performed in the past including isotope analyses, petrography, cathodoluminescence, and elemental analyses. In the present work, solid-state nuclear magnetic resonance (NMR) spectroscopy has been added to this panel of techniques. NMR allows the characterization of the material at a molecular level by looking at different nuclei: carbon, magnesium, and calcium. Statistical analysis of the data collected on both quarry samples and archaeologic items was also implemented and clearly demonstrates the efficiency of a holistic approach for provenance elucidation. Finally, the first 25Mg NMR tests have shown the potential of this technique to discriminate between dolomitic marbles of different provenance. The results are discussed in terms of their historical meaning and illustrate the exploitation of sources of dolomitic marbles other than the Greek Thasos source. 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