e452e95b6f8c0d8611ace31bd62132f3 water-16-01905.pdf 30f5f4f7f82b482bf488f2c4560105facf4dc938 water-16-01905.pdf dba90bd7e795cb78465f4900e67ed16348ea282a2541b112ce33c415a9a72f1c water-16-01905.pdf Title: Cadmium Removal by Adsorption on Biochars Derived from Wood Industry and Craft Beer Production Wastes Subject: Cadmium pollution is a serious environmental issue that has an impact on both the ecosystem and human health. As a result, its removal from water is essential. Agro-industrial wastes are suggested as a sustainable adsorbent option, as they are among the most readily available renewable sources worldwide. Biochar is a carbonized biomass that has been shown to be a viable and novel adsorbent. This article compares the results of cadmium adsorption on biochars derived from wood industry and craft beer production wastes. Biochars were characterized before and after adsorption. Batch adsorption results of 0.18 mmol/L Cd(II) concentration solutions indicated adsorption percentages (A%) of 99.7% and 92.2% for sawdust biochar and barley biochar, respectively. For this cadmium concentration, the sawdust biochar presented an adsorption capacity (qm) of 0.0172 mmol/L, while the barley biochar presented a value of 0.0159 mmol/L. The influence of initial Cd(II) concentration on single and multimetal solutions was studied, and a decrease in Cd(II) adsorption on sawdust biochar was observed in the presence of Ni(II) and Zn(II). The Freundlich isotherm model was found to be the best fit to the data for Cd(II) adsorption isotherms on both biochars. According to the results of this article, sawdust biochar has the best performance as an adsorbent and can be safely disposed of in building bricks at the end of its useful life. Keywords: barley waste-derived biochar; sawdust waste-derived biochar; cadmium adsorption; multimetal solution; circular economy; spent adsorbents Author: Daiana Simón, Cristina Palet and Adrián Cristóbal Creator: LaTeX with hyperref Producer: pdfTeX-1.40.25 CreationDate: Wed Jul 3 13:23:17 2024 CEST ModDate: Wed Jul 3 13:32:07 2024 CEST Custom Metadata: no Metadata Stream: no Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 17 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 2387100 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- ENXZUH+VnURWPalladioL-Bold Type 1 Custom yes yes yes 10 0 XKWWDX+URWPalladioL-Bold Type 1 Custom yes yes yes 16 0 WZWBPV+URWPalladioL-Roma Type 1 Custom yes yes yes 22 0 IUDQNL+URWPalladioL-Ital Type 1 Custom yes yes yes 27 0 MJSSOL+CMSY10 Type 1 Builtin yes yes yes 32 0 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yes no 397 0 POMLCO+PalatinoLinotype TrueType MacRoman yes yes no 400 0 POMOAP+TimesNewRoman CID TrueType Identity-H yes yes yes 403 0 Jhove (Rel. 1.28.0, 2023-05-18) Date: 2024-09-27 02:40:48 CEST RepresentationInformation: water-16-01905.pdf ReportingModule: PDF-hul, Rel. 1.12.4 (2023-03-16) LastModified: 2024-09-23 13:40:42 CEST Size: 2387100 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 671 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Destination: section.1 Item: Title: Materials and Methods Destination: section.2 Children: Item: Title: Biochar Characterization Destination: subsection.2.1 Item: Title: Chemicals and Reagents Destination: subsection.2.2 Item: Title: Batch Adsorption Experiments Destination: subsection.2.3 Children: Item: Title: Adsorption of Cd(II) and Other Heavy Metals Destination: subsubsection.2.3.1 Item: Title: Effect of Initial Cd(II) Concentration in Single- and Multi-Metal Systems Destination: subsubsection.2.3.2 Item: Title: Adsorption Isotherms Destination: subsubsection.2.3.3 Item: Title: Clean Disposal of Spent Biochars Destination: subsection.2.4 Item: Title: Results and Discussions Destination: section.3 Children: Item: Title: Biochar Characterization Destination: subsection.3.1 Item: Title: Batch Adsorption Experiments Destination: subsection.3.2 Item: Title: Clean Disposal of Spent Biochars Destination: subsection.3.3 Item: Title: Conclusions Destination: section.4 Item: Title: References Destination: section.5 Info: Title: Cadmium Removal by Adsorption on Biochars Derived from Wood Industry and Craft Beer Production Wastes Author: Daiana Simón, Cristina Palet and Adrián Cristóbal Subject: Cadmium pollution is a serious environmental issue that has an impact on both the ecosystem and human health. As a result, its removal from water is essential. Agro-industrial wastes are suggested as a sustainable adsorbent option, as they are among the most readily available renewable sources worldwide. Biochar is a carbonized biomass that has been shown to be a viable and novel adsorbent. This article compares the results of cadmium adsorption on biochars derived from wood industry and craft beer production wastes. Biochars were characterized before and after adsorption. Batch adsorption results of 0.18 mmol/L Cd(II) concentration solutions indicated adsorption percentages (A%) of 99.7% and 92.2% for sawdust biochar and barley biochar, respectively. For this cadmium concentration, the sawdust biochar presented an adsorption capacity (qm) of 0.0172 mmol/L, while the barley biochar presented a value of 0.0159 mmol/L. The influence of initial Cd(II) concentration on single and multimetal solutions was studied, and a decrease in Cd(II) adsorption on sawdust biochar was observed in the presence of Ni(II) and Zn(II). The Freundlich isotherm model was found to be the best fit to the data for Cd(II) adsorption isotherms on both biochars. According to the results of this article, sawdust biochar has the best performance as an adsorbent and can be safely disposed of in building bricks at the end of its useful life. 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