4bcbd5da8b0bd4b7ae634f5c30125895 JouSyn_a2024v31n6p1505.pdf 4d50e5a9dd9f2362842a46049f5e5a1b64febadd JouSyn_a2024v31n6p1505.pdf bd114a4366b6d59882007f3fcc2074373722c831978eaf8ac9d7f18a437d60b2 JouSyn_a2024v31n6p1505.pdf Title: Development of hard X-ray photoelectron spectroscopy in liquid cells using optimized microfabricated silicon nitride membranes Creator: pdftk-java 3.2.2 Producer: International Union of Crystallography CreationDate: Tue Oct 15 14:00:00 2024 CEST ModDate: Thu Oct 31 13:52:19 2024 CET Custom Metadata: no Metadata Stream: yes Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 9 Encrypted: no Page size: 609.676 x 793.701 pts Page rot: 0 File size: 10779734 bytes Optimized: yes PDF version: 1.6 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- Optima_Bold Type 1 Builtin yes no yes 461 0 Optima_Italic Type 1 Builtin yes no yes 462 0 Optima_Roman Type 1 Builtin yes no yes 463 0 Times-93Roman Type 1 Builtin yes no yes 464 0 Times-93Italic Type 1 Builtin yes no yes 465 0 TeX_Times_Math_Symbol Type 1 Builtin yes no yes 369 0 PI_chars_1 Type 1 Builtin yes no yes 377 0 TeX_Times_Math_Italic Type 1 Builtin yes no yes 376 0 Times-93Bold Type 1 Builtin yes no yes 390 0 Jhove (Rel. 1.28.0, 2023-05-18) Date: 2025-09-30 03:48:25 CEST RepresentationInformation: JouSyn_a2024v31n6p1505.pdf ReportingModule: PDF-hul, Rel. 1.12.4 (2023-03-16) LastModified: 2025-09-29 15:51:19 CEST Size: 10779734 Format: PDF Version: 1.6 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf Profile: Linearized PDF PDFMetadata: Objects: 498 FreeObjects: 1 IncrementalUpdates: 1 DocumentCatalog: PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Abstract Destination: 1 Item: Title: 1. Introduction Destination: 1 Item: Title: 2. Experimental Destination: 1 Children: Item: Title: 2.1. HAXPES beamline and Scienta analyser Destination: 1 Item: Title: 2.2. Fabrication and characterization of silicon nitride membranes Destination: 1 Item: Title: 2.3. Static liquid cells (SLCs) Destination: 1 Item: Title: 2.4. Circulating liquid cells (CLCs) Destination: 1 Item: Title: 3. Results and discussion Destination: 1 Children: Item: Title: 3.1. 20 and 25 nm membranes using SLCs Destination: 1 Item: Title: 3.2. 15 nm membranes using CLCs Destination: 1 Item: Title: 4. Conclusions Destination: 1 Item: Title: 5. Related literature Destination: 1 Item: Title: Acknowledgements Destination: 1 Item: Title: Funding information Destination: 1 Item: Title: References Destination: 1 Info: Title: Development of hard X-ray photoelectron spectroscopy in liquid cells using optimized microfabricated silicon nitride membranes Creator: pdftk-java 3.2.2 Producer: International Union of Crystallography CreationDate: Tue Oct 15 14:00:00 CEST 2024 ModDate: Thu Oct 31 13:52:19 CET 2024 ID: 0xcdb19cb06a928911e873874c5c79d0d2, 0xdce7168246987de63a48c2985b99c451 Filters: FilterPipeline: FlateDecode FilterPipeline: DCTDecode Images: Image: NisoImageMetadata: FormatName: image/png ImageWidth: 897 ImageHeight: 347 ColorSpace: CMYK BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 1417 ImageHeight: 1102 BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 2141 ImageHeight: 293 BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/jpg CompressionScheme: JPEG ImageWidth: 211 ImageHeight: 208 ColorSpace: RGB BitsPerSample: 8 BitsPerSampleUnit: integer Image: NisoImageMetadata: FormatName: image/png ImageWidth: 1238 ImageHeight: 1022 BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 2196 ImageHeight: 1301 ColorSpace: RGB BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 1384 ImageHeight: 1257 ColorSpace: RGB BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 1102 ImageHeight: 895 ColorSpace: RGB BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 1384 ImageHeight: 1383 BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 1890 ImageHeight: 1592 ColorSpace: RGB BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Image: NisoImageMetadata: FormatName: image/png ImageWidth: 2835 ImageHeight: 802 BitsPerSample: 8 BitsPerSampleUnit: integer Filter: FlateDecode Fonts: Type1: Font: BaseFont: Times-93Roman FirstChar: 32 LastChar: 251 FontDescriptor: FontName: Times-93Roman Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: Times-93Italic FirstChar: 32 LastChar: 251 FontDescriptor: FontName: Times-93Italic Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: TeX_Times_Math_Symbol FirstChar: 1 LastChar: 138 FontDescriptor: FontName: TeX_Times_Math_Symbol Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: Times-93Bold FirstChar: 32 LastChar: 251 FontDescriptor: FontName: Times-93Bold Flags: Symbolic, ForceBold FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: TeX_Times_Math_Italic FirstChar: 1 LastChar: 127 FontDescriptor: FontName: TeX_Times_Math_Italic Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: PI_chars_1 FirstChar: 33 LastChar: 126 FontDescriptor: FontName: PI_chars_1 Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: Optima_Bold FirstChar: 33 LastChar: 251 FontDescriptor: FontName: Optima_Bold Flags: Symbolic, ForceBold FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: Optima_Italic FirstChar: 33 LastChar: 251 FontDescriptor: FontName: Optima_Italic Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true Font: BaseFont: Optima_Roman FirstChar: 33 LastChar: 251 FontDescriptor: FontName: Optima_Roman Flags: Symbolic FontBBox: -50, -180, 1000, 720 FontFile: true ToUnicode: true XMP: True This work is licensed under a <a rel="license" href="http://creativecommons.org/licenses/by/4.0/">Creative Commons Attribution 4.0 UK: England & Wales License</a>. This work is licensed under a <a rel="license" href="http://creativecommons.org/licenses/by/4.0/">Creative Commons Attribution 4.0 UK: England & Wales License</a>. 2024-10-15 true 10.1107/S1600577524008865 10.1107/S1600577524008865 noindex 2024-10-15 true iucr.org iucr.org 10.1107/S1600577524008865 VoR doi:10.1107/S1600577524008865 J. Synchrotron Rad (2024). 31, 1505-1513 [doi:10.1107/S1600577524008865] research papers application/pdf Development of hard X-ray photoelectron spectroscopy in liquid cells using optimized microfabricated silicon nitride membranes en We present first hard X-ray photoelectron spectroscopy (HAXPES) results of aqueous salt solutions and dispersions of gold nanoparticles in liquid cells equipped with specially designed microfabricated thin silicon nitride membranes, with thickness in the 15–25 nm range, mounted in a high-vacuum-compatible environment. The experiments have been performed at the HAXPES endstation of the GALAXIES beamline at the SOLEIL synchrotron radiation facility. The low-stress membranes are fabricated from 100 mm silicon wafers using standard lithography techniques. Platinum alignment marks are added to the chips hosting the membranes to facilitate the positioning of the X-ray beam on the membrane by detecting the corresponding photoemission lines. Two types of liquid cells have been used, a static one built on an Omicron-type sample holder with the liquid confined in the cell container, and a circulating liquid cell, in which the liquid can flow in order to mitigate the effects due to beam damage. We demonstrate that the membranes are mechanically robust and able to withstand 1 bar pressure difference between the liquid inside the cell and vacuum, and the intense synchrotron radiation beam during data acquisition. This opens up new opportunities for spectroscopic studies of liquids. 2024-10-15 International Union of Crystallography HARD X-RAY PHOTOELECTRON SPECTROSCOPY SILICON NITRIDE MEMBRANES MICROFABRICATION AQUEOUS SOLUTIONS NANOPARTICLES BEAM DAMAGE SYNCHROTRON RADIATION Capone, F. Muntada, O. Ramirez, J.C. Esplandiu, M.J. Dedryvere, R. Grimaud, A. Lassalle-Kaiser, B. Ceolin, D. Perez-Murano, F. Rueff, J.-P. Fraxedas, J. 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