42a50465dba6b079df99dbeda73c8783 staf1191.pdf cff8a5ed31d722a8462ccfaf39777823ec467085 staf1191.pdf cda1a6ae5ab5721a290aea7000ba632f296bee9f3de26c0acafa353cb55bf821 staf1191.pdf Title: Quantum mechanical investigation on the formation of silicate building blocks on interstellar ice mantles Subject: DOI: 10.1093/mnras/staf1191 Monthly Notices of the Royal Astronomical Society, 541, 4, 21-07-2025. Abstract: Silicon monoxide (SiO), a diatomic molecule present in the interstellar medium, probably contributes to the formation of silicate dust grains since orthosilicic acid (Si(OH)), a SiO derivative, is a precursor of silica and silicates. The formation of Si(OH) is investigated here by means of quantum chemical computations, characterizing the interaction and reactivity of SiO with water ice mantles (modelled through different cluster systems) that coat interstellar dust grains in dense clouds. Several reaction pathways involving SiO and HO were simulated with the aim of forming Si(OH) and subsequently Si(OH). Results highlight that the ice mantle not only supplies a reactant, HO, but also acts as a chemical catalyst, reducing the energy barrier of the process. The formation of the Si(OH) precursor is a crucial step, occurring easily by reaction of SiO with HO. Subsequently, both the Si(OH) OSi(OH) Si(OH) and Si(OH) OSi(OH) Si(OH) paths have been found to be energetically favourable towards Si(OH) formation due to being barrierless, although formation of HSi(OH) by H addition to Si(OH) is a potential competitive channel. This study provides evidence that orthosilicic acid can form due to the addition of HO, O, and H to SiO on water ice mantles, indicating that silicate grains can potentially form and grow in cold interstellar regions, in addition to originating from material ejected by asymptotic giant branch stars and supernovae remnants. Our results show that grain surface reactions in dense clouds are important not only in the synthesis of volatile molecular species but also in the formation of silicate refractory material precursors. Keywords: Author: Gelli A., Perrero J., Ferrero S., Enrique-Romero J., Ceccarelli C., Ugliengo P., Balucani N., Rimola A. 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Subject: DOI: 10.1093/mnras/staf1191 Monthly Notices of the Royal Astronomical Society, 541, 4, 21-07-2025. Abstract: Silicon monoxide (SiO), a diatomic molecule present in the interstellar medium, probably contributes to the formation of silicate dust grains since orthosilicic acid (Si(OH)), a SiO derivative, is a precursor of silica and silicates. The formation of Si(OH) is investigated here by means of quantum chemical computations, characterizing the interaction and reactivity of SiO with water ice mantles (modelled through different cluster systems) that coat interstellar dust grains in dense clouds. Several reaction pathways involving SiO and HO were simulated with the aim of forming Si(OH) and subsequently Si(OH). Results highlight that the ice mantle not only supplies a reactant, HO, but also acts as a chemical catalyst, reducing the energy barrier of the process. The formation of the Si(OH) precursor is a crucial step, occurring easily by reaction of SiO with HO. Subsequently, both the Si(OH) OSi(OH) Si(OH) and Si(OH) OSi(OH) Si(OH) paths have been found to be energetically favourable towards Si(OH) formation due to being barrierless, although formation of HSi(OH) by H addition to Si(OH) is a potential competitive channel. This study provides evidence that orthosilicic acid can form due to the addition of HO, O, and H to SiO on water ice mantles, indicating that silicate grains can potentially form and grow in cold interstellar regions, in addition to originating from material ejected by asymptotic giant branch stars and supernovae remnants. Our results show that grain surface reactions in dense clouds are important not only in the synthesis of volatile molecular species but also in the formation of silicate refractory material precursors. 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Published by Oxford University Press on behalf of Royal Astronomical Society. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited. All Rights Reserved application/pdf doi:10.1093/mnras/staf1191 © The Author(s) 2025. Published by Oxford University Press on behalf of Royal Astronomical Society. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited. Quantum mechanical investigation on the formation of silicate building blocks on interstellar ice mantles DOI: 10.1093/mnras/staf1191 Monthly Notices of the Royal Astronomical Society, 541, 4, 21-07-2025. Abstract: Silicon monoxide (SiO), a diatomic molecule present in the interstellar medium, probably contributes to the formation of silicate dust grains since orthosilicic acid (Si(OH)), a SiO derivative, is a precursor of silica and silicates. The formation of Si(OH) is investigated here by means of quantum chemical computations, characterizing the interaction and reactivity of SiO with water ice mantles (modelled through different cluster systems) that coat interstellar dust grains in dense clouds. Several reaction pathways involving SiO and HO were simulated with the aim of forming Si(OH) and subsequently Si(OH). Results highlight that the ice mantle not only supplies a reactant, HO, but also acts as a chemical catalyst, reducing the energy barrier of the process. The formation of the Si(OH) precursor is a crucial step, occurring easily by reaction of SiO with HO. Subsequently, both the Si(OH) OSi(OH) Si(OH) and Si(OH) OSi(OH) Si(OH) paths have been found to be energetically favourable towards Si(OH) formation due to being barrierless, although formation of HSi(OH) by H addition to Si(OH) is a potential competitive channel. This study provides evidence that orthosilicic acid can form due to the addition of HO, O, and H to SiO on water ice mantles, indicating that silicate grains can potentially form and grow in cold interstellar regions, in addition to originating from material ejected by asymptotic giant branch stars and supernovae remnants. Our results show that grain surface reactions in dense clouds are important not only in the synthesis of volatile molecular species but also in the formation of silicate refractory material precursors. Gelli A. Perrero J. Ferrero S. Enrique-Romero J. Ceccarelli C. Ugliengo P. Balucani N. Rimola A. 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