680879a00ce429c9a1a44fc58e739acd molbank-2025-M2113.pdf 643c267a43d5d5c162e2f511b49d582aed0a1c5f molbank-2025-M2113.pdf 58c6164980c78ca268ae4e84cfb764015b13b8c6173cef72399d8e7fee4c64e0 molbank-2025-M2113.pdf Title: Benzyl 2,4-dichlorophenyl sulfoxide Subject: Benzyl 2,4-dichlorophenyl sulfoxide was synthesized both in racemic and in an enantiopure form. This enantiopure sulfoxide is a further successful confirmation of our straightforward protocol to yield easily chiral aryl benzyl sulfoxides. We solved also the crystal structure of racemic benzyl 2,4-dichlorophenyl sulfoxide with a single crystal X-ray diffraction experiment. The main interactions building up the crystal structure were recognized and compared with other similar sulfoxides. Keywords: crystal structure; weak interactions; enantioselective oxidation; sulfoxide; titanium complex Author: Maria Annunziata M. Capozzi, Joan F. Piniella Febrer and Cosimo Cardellicchio Creator: LaTeX with hyperref Producer: pdfTeX-1.40.25; modified using OpenPDF 1.4.2 CreationDate: Tue Dec 16 13:17:22 2025 CET ModDate: Tue Dec 16 13:24:18 2025 CET Custom Metadata: yes Metadata Stream: no Tagged: no UserProperties: no Suspects: no Form: none JavaScript: no Pages: 7 Encrypted: no Page size: 595.276 x 841.89 pts (A4) Page rot: 0 File size: 1157369 bytes Optimized: no PDF version: 1.7 name type encoding emb sub uni object ID ------------------------------------ ----------------- ---------------- --- --- --- --------- ZRCLSW+URWPalladioL-Roma Type 1 Custom yes yes yes 95 0 SSXPJJ+VnURWPalladioL Type 1 Custom yes yes yes 96 0 CSTQEY+URWPalladioL-Ital Type 1 Custom yes yes yes 97 0 XGQDCL+URWPalladioL-Bold Type 1 Custom yes yes yes 98 0 DNODMN+PalatinoLinotype TrueType WinAnsi yes yes no 145 0 DNODMN+PalatinoLinotype TrueType WinAnsi yes yes no 155 0 AXWEOY+CMSY10 Type 1 Builtin yes yes yes 203 0 DNODMN+PalatinoLinotype TrueType WinAnsi yes yes no 179 0 DNODMN+PalatinoLinotype TrueType WinAnsi yes yes no 226 0 DNODMN+PalatinoLinotype TrueType WinAnsi yes yes no 198 0 FSCNAL+EURM10 Type 1 Builtin yes yes yes 246 0 Jhove (Rel. 1.28.0, 2023-05-18) Date: 2026-01-23 04:34:48 CET RepresentationInformation: molbank-2025-M2113.pdf ReportingModule: PDF-hul, Rel. 1.12.4 (2023-03-16) LastModified: 2026-01-22 11:48:42 CET Size: 1157369 Format: PDF Version: 1.7 Status: Well-Formed and valid SignatureMatches: PDF-hul MIMEtype: application/pdf PDFMetadata: Objects: 308 FreeObjects: 1 IncrementalUpdates: 0 DocumentCatalog: ViewerPreferences: HideToolbar: false HideMenubar: false HideWindowUI: false FitWindow: true CenterWindow: false DisplayDocTitle: false NonFullScreenPageMode: UseNone Direction: L2R ViewArea: CropBox ViewClip: CropBox PrintArea: CropBox PageClip: CropBox PageLayout: SinglePage PageMode: UseNone Outlines: Item: Title: Introduction Item: Title: Results Children: Item: Title: Synthesis of Racemic and Enantiopure Benzyl 2,4-dichlorophenyl sulfoxide Item: Title: Crystal Structure of Racemic Benzyl 2,4-dichlorophenyl sulfoxide Item: Title: Materials and Methods Item: Title: Appendix A Item: Title: References Info: Title: Benzyl 2,4-dichlorophenyl sulfoxide Author: Maria Annunziata M. Capozzi, Joan F. Piniella Febrer and Cosimo Cardellicchio Subject: Benzyl 2,4-dichlorophenyl sulfoxide was synthesized both in racemic and in an enantiopure form. This enantiopure sulfoxide is a further successful confirmation of our straightforward protocol to yield easily chiral aryl benzyl sulfoxides. We solved also the crystal structure of racemic benzyl 2,4-dichlorophenyl sulfoxide with a single crystal X-ray diffraction experiment. The main interactions building up the crystal structure were recognized and compared with other similar sulfoxides. 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