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Destination: mk:title Children: Item: Title: 1 Introduction Destination: mk:H1_1 Item: Title: 2 Materials and methods Destination: mk:H1_2 Children: Item: Title: 2.1 Nanoparticles synthesis and characterization Destination: mk:H2_1 Item: Title: 2.2 Inoculum and substrate Destination: mk:H2_2 Item: Title: 2.3 Batch anaerobic digestion: experimental set-up and procedure Destination: mk:H2_3 Item: Title: 2.4 Semi-continuous anaerobic digestion: experimental set-up and procedure Destination: mk:H2_4 Item: Title: 2.5 Analytical methods Destination: mk:H2_5 Children: Item: Title: 2.5.1 Alkalinity Destination: mk:H3_6 Item: Title: 2.5.2 VFA Destination: mk:H3_7 Item: Title: 2.5.3 Total iron content Destination: mk:H3_8 Item: Title: 2.5.4 Biogas characterization Destination: mk:H3_9 Item: Title: 2.6 Microbial community analysis Destination: mk:H2_10 Item: Title: 2.7 Data analysis Destination: mk:H2_11 Children: Item: Title: 2.7.1 Statistical analysis Destination: mk:H3_12 Item: Title: 2.7.2 Data fitting Destination: mk:H3_13 Item: Title: 3 Results and discussion Destination: mk:H1_3 Children: Item: Title: 3.1 Nanoparticles characterization Destination: mk:H2_14 Item: Title: 3.2 Batch test for selecting nZVI dosing method Destination: mk:H2_15 Item: Title: 3.3 The influence of nZVI dosage under semi-continuous operation Destination: mk:H2_16 Children: Item: Title: 3.3.1 Overall performance Destination: mk:H3_17 Item: Title: 3.3.2 Effect of nZVI dosing Destination: mk:H3_18 Item: Title: 3.3.3 The effect of OLR on the effectiveness of nZVI Destination: mk:H3_19 Item: Title: 3.3.4 Sustained effect of nZVI after end of NPs addition Destination: mk:H3_20 Item: Title: 3.4 Microbial community analysis Destination: mk:H2_21 Item: Title: 4 Conclusions Destination: mk:H1_4 Item: Title: CRediT authorship contribution statement Destination: mk:H1_5 Item: Title: Declaration of Competing Interest Destination: mk:HH1_2 Item: Title: Acknowledgments Destination: mk:HH1_3 Item: Title: 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