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Pàgina inicial > Articles > Articles publicats > The structure of dichlorobis[μ-(3-dimethylamino-1-propanethiolato)-μ-S,N]-dipalladium(II), (I) [Pd2(C5H12NS)2Cl2], and ac,bd,eg, fh-tetrakis[μ-(3-piperidinemethanethiolato)-μ-S,N]-tripalladium(II) dichloride dihydrate, (II) [Pd3(C6H12NS)4]Cl2.2H2O |
Data: | 1983 |
Resum: | Mr=520. 15, monoclinic, P21/n, a=7. 207(2), B=20. 616(4), c=5. 854(1) A, β=96. 05(1)º, V=864. 9(6)A3, Z=2, Dx=2. 00 Mg m-3, Mo Ka, = 0. 71069 A, µ=2. 553 mm-1, F(000)=512, 298 K, R=0. 060 for 1492 reflections. (II): Mr=947. 07, triclinic, Pl, a=12. 666(7), b=10. 595(6), c=6. 572(5)A, a=98. 30(2), = 97. 04(2), = 99. 84(2)º, V=850(2)A3, Z=1, Dx=1. 85 Mg m-3, Mo Ka, =0. 71069 A, µ=1. 958 mm-1, F(000)=490, 298 K, R=0. 071 for 1879 reflections. (I) was solved by direct methods, using MULTAN and DIRDIF, (II) by the heavy-atom method. The four-membered Pd, S, Pd, S rings have a syn-exo conformation, with dihedral angles between the S, Pd, S planes of 154. 4(2) and 133. 0(3)º for (I) and (II), respectively. |
Drets: | Tots els drets reservats. |
Llengua: | Anglès |
Document: | Article ; Versió publicada |
Matèria: | Cristal·lografia ; Crystallography |
Publicat a: | Acta Crystallographica. Section C: Crystal Structure Communications, Vol. 39, Issue 12 (December 1983) , p. 1653-1655, ISSN 1600-5759 |
3 p, 259.6 KB |