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12 p, 288.8 KB Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst / Borja Rodríguez, Guadalupe (Universitat Autònoma de Barcelona. Departament de Química) ; Pleixats i Rovira, Roser (Universitat Autònoma de Barcelona. Departament de Química) ; Alibes, Ramón (Universitat Autònoma de Barcelona. Departament de Química) ; Cattoën, Xavier (Institut Charles Gerhardt Montpellier (Montpellier, França)) ; Wong Chi Man, Michel (Institut Charles Gerhardt Montpellier (Montpellier, França))
The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.
2010 - 10.3390/molecules15085756
Molecules, Vol. 15 N. 8 (August 2010) , p. 5756-5767  
Detailed record - Creative Commons

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