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4 p, 1.8 MB A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal–Organic Polyhedra / Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Craig, Gavin A. (Kyoto University. Institute for Integrated Cell-Material Science) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Urayama, Kenji (Kyoto Institute of Technology) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry)
Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining solubility often requires covalently bound functional groups that are unnecessary for porosity and which ultimately occupy free volume in the materials, decreasing their surface areas. [...]
2019 - 10.1002/anie.201901668
Angewandte Chemie - International Edition, Vol. 58, Issue 19 (May 2019) , p. 6347-6350  

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