Universitat Autònoma de Barcelona

Universitat Autònoma de Barcelona 1 records found  Search took 0.02 seconds. 
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17 p, 1.2 MB Postsynthetic Selective Ligand Cleavage by Solid-Gas Phase Ozonolysis Fuses Micropores into Mesopores in Metal-Organic Frameworks / Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Xu, Heng (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein we report a novel, ozone-based method for postsynthetic generation of mesoporosity in metal-organic frameworks (MOFs). By carefully selecting mixed-ligand Zr-fcu-MOFs based on organic ligand pairs in which one ligand has ozone-cleavable olefin bonds and the other ligand is ozone-resistant, we were able to selectively break the cleavable ligand via ozonolysis to trigger fusion of micropores into mesopores within the MOF framework. [...]
2018 - 10.1021/jacs.8b09682
Journal of the American Chemical Society, Vol. 140, Issue 44 (November 2018) , p. 15022-15030  

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