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Multiscale study of mononuclear Co" SMMs based on curcuminoid ligands / Díaz-Torres, Raúl (Universitat de Barcelona. Departament de Química Inorgànica) ; Menelaou, Melita (Universitat de Barcelona. Departament de Química Inorgànica) ; Roubeau, Olivier (Universidad de Zaragoza. Instituto de Ciencia de Materiales de Aragón) ; Sorrenti, Alessandro (Institut de Ciència de Materials de Barcelona) ; Brandariz de Pedro, Guillem (Universitat de Barcelona. Departament de Química Inorgànica) ; Sañudo, E. Carolina (Universitat de Barcelona. Departament de Química Inorgànica) ; Teat, Simon J. (Lawrence Berkeley National Laboratory. Advanced Light Source) ; Fraxedas, Jordi (Institut Català de Nanociència i Nanotecnologia) ; Ruiz, Eliseo (Universitat de Barcelona. Institut de Química Teòrica i Computacional) ; Aliaga-Alcalde, Núria (Institució Catalana de Recerca i Estudis Avançats)
This work introduces a novel family of Co" species having a curcuminoid (CCMoid) ligand, 9Accm, attached, namely [Co(9Accm)₂(py)₂] (1) and [Co(9Accm)₂(2,20-bpy)] (2), achieved in high yields by the use of a microwave reactor, and exhibiting two different arrangements for the 9Accm ligands, described as "cis"(2) and "trans"(1). [...]
2016 - DOI (Digital Object Identifier)

10.1039/c5sc03298a
Chemical science, Vol. 7, Issue 4 (January 2016) , p. 2793-2803

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