Results overview: Found 8 records in 0.02 seconds.
Articles, 7 records found
Research literature, 1 records found
Articles 7 records found  
1.
13 p, 3.0 MB Protecting metal-organic framework crystals from hydrolytic degradation by spray-dry encapsulating them into polystyrene microspheres / Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Stylianou, Kyriakos C. (Institut Català de Nanociència i Nanotecnologia) ; Carbonell Fernández, Carlos (Institut Català de Nanociència i Nanotecnologia) ; Naderi, Majid (Surface Measurement Systems) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
A one-step, alternative, rapid, and scalable spray-drying (SD) synthesis of metal-organic frameworks (MOF)@polymer composites with enhanced hydrolytic stabilities was reported. SD was used to encapsulate preformed MOF crystals in a polymeric matrix to generate microscale MOF@polymer spheres. [...]
2015 - 10.1002/adma.201403827
Advanced materials, Vol. 27, Issue 5 (February 2015) , p. 869-873  
2.
9 p, 625.2 KB A Self-Folding Polymer Film Based on Swelling Metal–Organic Frameworks / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; León Reina, Laura (Universidad de Málaga) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Cabeza, Aurelio (Universidad de Málaga) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein, we exploit the well-known swelling behaviour of metal–organic frameworks (MOFs) to create a self-folding polymer film. Namely, we show that incorporating crystals of the flexible MOF MIL-88A into a polyvinylidene difluoride (PVDF) matrix affords a polymer composite film that undergoes reversible shape transformations upon exposure to polar solvents and vapours. [...]
2018 - 10.1002/anie.201808433
Angewandte Chemie - International Edition, Vol. 57, Issue 47 (November 2018) , p. 15420-15424  
3.
11 p, 852.8 KB Photothermal Activation of Metal-Organic Frameworks Using a UV-Vis Light Source / Espín Martí, Jordi (Institut Català de Nanociència i Nanotecnologia) ; Garzón Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Metal-organic frameworks (MOFs) usually require meticulous removal of the solvent molecules to unlock their potential porosity. Herein, we report a novel one-step method for activating MOFs based on the photothermal effect induced by directly irradiating them with a UV-vis lamp. [...]
2018 - 10.1021/acsami.8b00557
ACS applied materials and interfaces, Vol. 10, Issue 11 (February 2018) , p. 9555-9562  
4.
4 p, 1.8 MB A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal–Organic Polyhedra / Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Craig, Gavin A. (Kyoto University. Institute for Integrated Cell-Material Science) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Urayama, Kenji (Kyoto Institute of Technology) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry)
Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining solubility often requires covalently bound functional groups that are unnecessary for porosity and which ultimately occupy free volume in the materials, decreasing their surface areas. [...]
2019 - 10.1002/anie.201901668
Angewandte Chemie - International Edition, Vol. 58, Issue 19 (May 2019) , p. 6347-6350  
5.
Programmable self-assembling 3D architectures generated by patterning of swellable MOF-based composite films / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
The integration of swellable metal–organic frameworks (MOFs) into polymeric composite films is a straightforward strategy to develop soft materials that undergo reversible shape transformations derived from the intrinsic flexibility of MOF crystals. [...]
2019 - 10.1002/adma.201808235
Advanced materials, Vol. 31, issue 21 (May 2019) , art. 1808235  
6.
Postsynthetic covalent and coordination functionalization of rhodium(II)-based metal-organic polyhedra / Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Metal-organic polyhedra (MOP) are ultrasmall (typically 1-4 nm) porous coordination cages made from the self-assembly of metal ions and organic linkers and are amenable to the chemical functionalization of its periphery; however, it has been challenging to implement postsynthetic functionalization due to their chemical instability. [...]
2019 - 10.1021/jacs.8b13593
Journal of the American Chemical Society, Vol. 141, issue 9 (March 2019) , p. 4094-4102  
7.
26 p, 1.3 MB Self-assembly of polyhedral metal–organic framework particles into three-dimensional ordered superstructures / Avci-Camur, Ceren (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Pariente, José Ángel (Instituto de Ciencia de Materiales de Madrid) ; Tasios, Nikos (Debye Instituut voor Nanomaterialen Wetenschap) ; Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; Alonso, María Isabel (Institut de Ciència de Materials de Barcelona) ; Blanco, Álvaro. (Instituto de Ciencia de Materiales de Madrid) ; Dijkstra, Marjolein (Debye Instituut voor Nanomaterialen Wetenschap) ; López, Cefe (Instituto de Ciencia de Materiales de Madrid) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Self-assembly of particles into long-range, three-dimensional, ordered superstructures is crucial for the design of a variety of materials, including plasmonic sensing materials, energy or gas storage systems, catalysts and photonic crystals. [...]
2018 - 10.1038/NCHEM.2875
Nature chemistry, Vol. 10, issue 1 (Jan. 2018) , p. 78-84  

Research literature 1 records found  
1.
195 p, 5.9 MB A new synthetic method for nanoscale metal-organic frameworks and their application as contrast agents for magnetic resonance imaging / Carné Sánchez, Arnau ; Maspoch Comamala, Daniel, dir. (Institut Català de Nanociència i Nanotecnologia) ; Imaz Gabilondo, Inhar, dir. (Institut Català de Nanociència i Nanotecnologia) ; Busqué Sánchez, Félix, tutor (Universitat Autònoma de Barcelona. Departament de Química) ; Universitat Autònoma de Barcelona. Departament de Química
La present Tesis ha estat dedicada a la síntesis de materials Metal·lorgànics a la nanoescala (NMOFs, fent servir l'acrònim anglès) i l'estudi de les seves potencials aplicacions com a Agents de Contrast (AC) en Imatgeria per Ressonància Magnètica. [...]
The present Thesis has been dedicated to the synthesis of nanoscale Metal-Organic Frameworks (NMOFs) and the study of their potential application as Contrast Agents (CAs). Accordingly, two main lines of work can be distinguished through the lecture of this Thesis: i) the development of a novel synthetic methodology to synthesise NMOFs; and ii) the synthesis of new NMOFs that meet the specific requirements for their use as CAs. [...]

[Barcelona] : Universitat Autònoma de Barcelona, 2014  

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