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Polyamide-polyamine cryptand as dicarboxylate receptor : dianion binding studies in the solid state, in solution, and in the gas phase / Chakraborty, Sourav (Indian Association for the Cultivation of Science) ; Saha, Subrata (Indian Association for the Cultivation of Science) ; Lima, Luis M. P. (Universidade Nova de Lisboa) ; Warzok, Ulrike (Freie Universität Berlin) ; Sarkar, Sayan (Indian Association for the Cultivation of Science) ; Akhuli, Bidyut (Indian Association for the Cultivation of Science) ; Nandi, Mandira (Indian Association for the Cultivation of Science) ; Bej, Somnath (Indian Association for the Cultivation of Science) ; Adarsh, Nayarassery N. (Institut Català de Nanociència i Nanotecnologia) ; Schalley, Christoph A. (Freie Universität Berlin) ; Delgado, Rita (Universidade Nova de Lisboa) ; Ghosh, Pradyut (Indian Association for the Cultivation of Science)
Polyamide-polyamine hybrid macrobicycle L is explored with respect to its ability to bind α,?-dicarboxylate anions. Potentiometric studies of protonated L with the series of dianions from succinate (suc) through glutarate (glu), α-ketoglutarate (kglu), adipate (adi), pimelate (pim), suberate (sub), to azelate (aze) have shown adipate preference with association constant value of K = 4900 M-1 in a HO/DMSO (50:50 v/v) binary solvent mixture. [...]
2017 - DOI (Digital Object Identifier)

10.1021/acs.joc.7b01431
Journal of organic chemistry, Vol. 82, Issue 19 (October 2017) , p. 10007-10014

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