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19 p, 689.5 KB Reversible thermochromic polymeric thin films made of ultrathin 2D crystals of coordination polymers based on copper(I)-thiophenolates / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Castillo, Óscar. (Universidad del País Vasco. Departamento de Química Inorgánica) ; Martínez, José I. (Instituto de Ciencia de Materiales de Madrid) ; Fernández-Moreira, Vanesa (Universidad de Zaragoza. Departamento de Química Inorgánica) ; Ballesteros, Yolanda (Universidad Pontificia Comillas. Departamento de Ingeniería Mecánica) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Zamora, Félix (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Delgado, Salomé (Universidad Autónoma de Madrid. Departamento de Química Inorgánica)
A one-pot reaction between Cu(BF)·xHO and 4-mercaptobenzoic acid in acetone or methanol gives rise to the formation of lamellar microcrystals of two Cu(I)-thiophenolate-based coordination polymers (CPs) with the formulas [CuCT] (1) (CT = 4-carboxy-thiophenolate) and [CuMCT] (2) (MCT = 4-methoxycarbonyl-thiophenolate). [...]
2018 - 10.1002/adfm.201704040
Advanced functional materials, Vol. 28, issue 5 (Jan. 2018) , art. 1704040  

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