Results overview: Found 4 records in 0.02 seconds.
Articles, 4 records found
Articles 4 records found  
1.
11 p, 630.1 KB Phase Transfer of Rhodium(II)-Based Metal-Organic Polyhedra Bearing Coordinatively Bound Cargo Enables Molecular Separation / Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Hernández López, Laura (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia)
The transfer of nanoparticles between immiscible phases can be driven by externally triggered changes in their surface composition. Interestingly, phase transfers can enhance the processing of nanoparticles and enable their use as vehicles for transporting molecular cargo. [...]
2019 - 10.1021/jacs.9b10403
Journal of the American Chemical Society, Vol. 141, Issue 45 (November 2019) , p. 18349-18355  
2.
9 p, 1.3 MB Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs) : The cases of carboxylate: The amino-functionalised Rh(ii)-MOPs / Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Hernández López, Laura (Institut Català de Nanociència i Nanotecnologia) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. [...]
2019 - 10.1039/c9cc07083d
Chemical communications, Vol. 55, Issue 85 (November 2019) , p. 12785-12788  
3.
6 p, 767.9 KB Zigzag ligands for transversal design in reticular chemistry : unveiling new structural opportunities for metal-organic frameworks / Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein we describe the topological influence of zigzag ligands in the assembly of Zr(IV) metal-organic frameworks (MOFs). Through a transversal design strategy using reticular chemistry, we were able to synthesize a family of isoreticular Zr(IV)-based MOFs exhibiting the bcu - rather than the fcu - topology. [...]
2018 - 10.1021/jacs.8b07050
Journal of the American Chemical Society, Vol. 140, issue 32 (August 2018) , p. 10153-10157  
4.
12 p, 1.5 MB Postsynthetic covalent and coordination functionalization of rhodium(II)-based metal-organic polyhedra / Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia)
Metal-organic polyhedra (MOP) are ultrasmall (typically 1-4 nm) porous coordination cages made from the self-assembly of metal ions and organic linkers and are amenable to the chemical functionalization of its periphery; however, it has been challenging to implement postsynthetic functionalization due to their chemical instability. [...]
2019 - 10.1021/jacs.8b13593
Journal of the American Chemical Society, Vol. 141, issue 9 (March 2019) , p. 4094-4102  

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