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5 p, 2.2 MB An Artificial Heme Enzyme for Cyclopropanation Reactions / Villarino, Lara (University of Groningen. Stratingh Institute for Chemistry) ; Splan, Kathryn E. (Macalester College. Department of Chemistry) ; Reddem, Eswar (University of Groningen. Stratingh Institute for Chemistry) ; Alonso-Cotchico, Lur (Universitat Autònoma de Barcelona. Departament de Química) ; Gutiérrez de Souza, Cora (University of Groningen. Stratingh Institute for Chemistry) ; Lledós, Agustí (Lledós i Falcó) (Universitat Autònoma de Barcelona. Departament de Química) ; Maréchal, Jean-Didier (Universitat Autònoma de Barcelona. Departament de Química) ; Thunnissen, Andy-Mark W. H. (University of Groningen. Stratingh Institute for Chemistry) ; Roelfes, Gerard (University of Groningen. Stratingh Institute for Chemistry)
An artificial heme enzyme was created through self-assembly from hemin and the lactococcal multidrug resistance regulator (LmrR). The crystal structure shows the heme bound inside the hydrophobic pore of the protein, where it appears inaccessible for substrates. [...]
2018 - 10.1002/anie.201802946
Angewandte Chemie (International ed. Internet), Vol. 57, Issue 26 (June 2018) , p. 7785-7789  
Detailed record - Creative Commons

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