1.
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11 p, 2.7 MB |
Photoredox heterobimetallic dual catalysis using engineered covalent organic frameworks
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López Magano, Alberto (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ;
Ortín-Rubio, Borja (Institut Català de Nanociència i Nanotecnologia) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ;
Aleman Lara, Jose Julian (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ;
Mas Balleste, Ruben (Universidad Autónoma de Madrid. Departamento de Química Inorgánica)
The functionalization of an imine-based layered covalent organic framework (COF), containing phenanthroline units as ligands, has allowed the obtention of a heterobimetallated material. Photoactive Ir and Ni fragments were immobilized within the porous structure of the COF, enabling heterogeneous light-mediated Csp 3 -Csp 2 cross-couplings. [...]
2021 - 10.1021/acscatal.1c03634
ACS Catalysis, Vol. 11, Issue 19 (October 2021) , p. 12344-12354
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3.
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21 p, 1.0 MB |
Millimeter-shaped metal-organic framework/inorganic nanoparticle composite as a new adsorbent for home water-purification filters
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Boix, Gerard (Institut Català de Nanociència i Nanotecnologia) ;
Han, Xu (Institut Català de Nanociència i Nanotecnologia) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Heavy-metal contamination of water is a global problem with an especially severe impact in countries with old or poorly maintained infrastructure for potable water. An increasingly popular solution for ensuring clean and safe drinking water in homes is the use of adsorption-based water filters, given their affordability, efficacy, and simplicity. [...]
2021 - 10.1021/acsami.1c02940
ACS applied materials & interfaces, Vol. 13, issue 15 (April 2021) , p. 17835-17843
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4.
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10 p, 646.8 KB |
Synthesis of polycarboxylate rhodium(II) metal-organic polyhedra (MOPs) and their use as building blocks for highly connected metal-organic frameworks (MOFs)
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Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ;
Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ;
Zarekarizi, Farnoosh (Tarbiat Modares University. Department of Chemistry) ;
Hernández López, Laura (Institut Català de Nanociència i Nanotecnologia) ;
Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ;
Khobotov Bakishev, Akim (Institut Català de Nanociència i Nanotecnologia) ;
Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ;
Morsali, Ali (Tarbiat Modares University. Department of Chemistry) ;
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ;
Gándara, Felipe (Instituto de Ciencia de Materiales de Madrid) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. [...]
2021 - 10.1002/anie.202013839
Angewandte Chemie (International ed. Internet), Vol. 60, issue 11 (March 2021) , p. 5729-5733
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5.
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9 p, 357.9 KB |
Systematic study of the impact of MOF densification into tablets on textural and mechanical properties
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Dhainaut, Jérémy (Université Claude Bernard Lyon 1) ;
Camur, Ceren (Institut Català de Nanociència i Nanotecnologia) ;
Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ;
Legrand, Alexandre (Institut Català de Nanociència i Nanotecnologia) ;
Canivet, J. (Université Claude Bernard Lyon 1) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ;
Reinsch, Helge (MOFapps) ;
Farrusseng, David (Université Claude Bernard Lyon 1)
Four different metal-organic framework powders (UiO-66, UiO-66-NH, UiO-67, and HKUST-1) were shaped into tablets. The effect of the applied pressure on porous properties, mechanical resistance and tablet bulk density is reported. [...]
2017 - 10.1039/c7ce00338b
CrystEngComm, Vol. 19, issue 29 (August 2017) , p. 4211-4218
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10 p, 900.3 KB |
Structural deterioration of well-faceted MOFs upon H2S exposure and its effect in the adsorption performance
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Reljic, Snezana (Universitat d'Alacant. Departament de Química Inorgànica) ;
Broto-Ribas, Anna (Institut Català de Nanociència i Nanotecnologia) ;
Cuadrado, Carlos (Universitat d'Alacant. Departament de Química Inorgànica) ;
Jardim, Erika (Universitat d'Alacant. Departament de Química Inorgànica) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Silvestre-Albero, Joaquin (Universitat d'Alacant. Departament de Química Inorgànica)
The structural deterioration of archetypical, well-faceted metal-organic frameworks (MOFs) has been evaluated upon exposure to an acidic environment (HS). Experimental results show that the structural damage highly depends on the nature of the hybrid network (e. [...]
2020 - 10.1002/chem.202002473
Chemistry, Vol. 26, issue 71 (Dec. 2020) , p. 17110-17119
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38 p, 1.2 MB |
Spray-drying synthesis of MOFs, COFs, and related composites
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Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ;
Çamur, Ceren (Institut Català de Nanociència i Nanotecnologia) ;
Garzon-Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ;
Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Conspectus: Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are among the most attractive porous materials today. They exhibit outstanding porosity for countless applications such as gas storage, CO2 capture, gas separation, sensing, drug delivery, and catalysis. [...]
2020 - 10.1021/acs.accounts.0c00133
Accounts of chemical research, Vol. 53, issue 6 (June 2020) , p. 1206-1217
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8 p, 1.0 MB |
Net-clipping : an approach to deduce the topology of metal-organic frameworks built with zigzag ligands
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Ortín-Rubio, Borja (Institut Català de Nanociència i Nanotecnologia) ;
Ghasempour, Hosein (Tarbiat Modares University. Department of Chemistry) ;
Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ;
Morsali, Ali (Tarbiat Modares University. Department of Chemistry) ;
Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein we propose a new approach for deducing the topology of metal-organic frameworks (MOFs) assembled from organic ligands of low symmetry, which we call net-clipping. It is based on the construction of nets by rational deconstruction of edge-transitive nets comprising higher-connected molecular building blocks (MBBs). [...]
2020 - 10.1021/jacs.0c03404
Journal of the American Chemical Society, Vol. 142, issue 20 (May 2020) , p. 9135-9140
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20 p, 1.7 MB |
Biomimetic synthesis of sub-20 nm covalent organic frameworks in water
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Franco, Carlos (ETH Zurich. Department of Chemistry and Applied Biosciences) ;
Rodríguez-San-Miguel, David (Universidad Autónoma de Madrid. Instituto de Física de la Materia Condensada-IFIMAC) ;
Sorrenti, Alessandro (ETH Zurich. Department of Chemistry and Applied Biosciences) ;
Sevim, Semih (ETH Zurich. Department of Chemistry and Applied Biosciences) ;
Pons, Ramon (Institut de Química Avançada de Catalunya) ;
Platero-Prats, Ana Eva (Universidad Autónoma de Madrid. Instituto de Física de la Materia Condensada-IFIMAC) ;
Pavlovic, Marko (Max-Planck Institute of Colloids and Interfaces. Department of Colloid Chemistry) ;
Szilágyi, Istvan (University of Szeged. Department of Physical Chemistry and Materials Science) ;
Ruiz Gonzalez, M. Luisa (Universidad Complutense de Madrid. Departamento de Quĺmica Inorgánica) ;
González-Calbet, José M. (Universidad Complutense de Madrid. Departamento de Quĺmica Inorgánica) ;
Bochicchio, Davide (University of Applied Sciences and Arts of Southern Switzerland. Department of Innovative Technologies) ;
Pesce, Luca (University of Applied Sciences and Arts of Southern Switzerland. Department of Innovative Technologies) ;
Pavan, Giovanni M. (University of Applied Sciences and Arts of Southern Switzerland. Department of Innovative Technologies) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Cano-Sarabia, Mary (Institut Català de Nanociència i Nanotecnologia) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ;
Pané, Salvador (ETH Zurich. Multi-Scale Robotics Lab) ;
De Mello, Andrew J. (ETH Zurich. Department of Chemistry and Applied Biosciences) ;
Zamora, Felix (Universidad Autónoma de Madrid. Instituto de Física de la Materia Condensada-IFIMAC) ;
Puigmarti-Luis, Josep (ETH Zurich. Department of Chemistry and Applied Biosciences)
Covalent organic frameworks (COFs) are commonly synthesized under harsh conditions yielding unprocessable powders. Control in their crystallization process and growth has been limited to studies conducted in hazardous organic solvents. [...]
2020 - 10.1021/jacs.9b12389
Journal of the American Chemical Society, Vol. 142, issue 7 (Feb. 2020) , p. 3540-3547
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23 p, 1.3 MB |
Tuning the supramolecular isomerism of MOF-74 by controlling the synthesis conditions
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Gheorghe, Andreea (Van't Hoff Institute for Molecular Sciences) ;
Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ;
Van Der Vlugt, Jarl Ivar (Van't Hoff Institute for Molecular Sciences) ;
Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ;
Tanase, Stefania (Van't Hoff Institute for Molecular Sciences)
Supramolecular isomerism of metal-organic frameworks (MOFs) is known for several MOF structures, having direct implications on the properties of these materials. Although the synthesis of MOF isomers is mainly serendipitous in nature, achieving controlled formation of a target framework is highly relevant for practical applications. [...]
2019 - 10.1039/c9dt01572h
Dalton transactions, Vol. 48, issue 27 (July 2019) , p. 10043-10050
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