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13 p, 1.7 MB Kauniolide synthase is a P450 with unusual hydroxylation and cyclization-elimination activity / Liu, Qing (University of Copenhagen. Department of Plant and Environmental Sciences) ; Beyraghdar Kashkooli, Arman (Wageningen University and Research. Laboratory of Plant Physiology) ; Manzano, David (Centre de Recerca en Agrigenòmica) ; Pateraki, Irini (University of Copenhagen. Department of Plant and Environmental Sciences) ; Richard, Lea (Wageningen University and Research. Laboratory of Plant Physiology) ; Kolkman, Pim (Wageningen University and Research. Laboratory of Plant Physiology) ; Lucas, Maria Fátima (Barcelona Supercomputing Center (BSC)) ; Guallar, Victor (Institució Catalana de Recerca i Estudis Avançats) ; de Vos, Ric C.H. (Wageningen University and Research. Wageningen Plant Research) ; Franssen, Maurice C.R. (Wageningen University. Laboratory of Organic Chemistry) ; van der Krol, Alexander (Wageningen University and Research. Laboratory of Plant Physiology) ; Bouwmeester, Harro (University of Amsterdam. Swammerdam Institute for Life Sciences)
Guaianolides are an important class of sesquiterpene lactones with unique biological and pharmaceutical properties. They have been postulated to be derived from germacranolides, but for years no progress has been made in the elucidation of their biosynthesis that requires an unknown cyclization mechanism. [...]
2018 - 10.1038/s41467-018-06565-8
Nature communications, Vol. 9 (November 2018) , art. 4657  

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