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16 p, 2.8 MB Replacing nitrogen by sulfur : From structurally disordered eumelanins to regioregular thiomelanin polymers / Iacomino, Mariagrazia (University of Naples "Federico II". Department of Chemical Sciences) ; Mancebo Aracil, Juan (Institut Català de Nanociència i Nanotecnologia) ; Guardingo Melián, Mireia (Universitat Autònoma de Barcelona. Department de Química) ; Martín, Raquel (Universitat Autònoma de Barcelona. Department de Química) ; D'Errico, Gerardino (University of Naples "Federico II". Department of Chemical Sciences) ; Perfetti, Marco (University of Naples "Federico II". Department of Chemical Sciences) ; Manini, Paola (University of Naples "Federico II". Department of Chemical Sciences) ; Crescenzi, Orlando (University of Naples "Federico II". Department of Chemical Sciences) ; Busqué Sánchez, Félix (Universitat Autònoma de Barcelona. Departament de Química) ; Napolitano, Alessandra (University of Naples "Federico II". Department of Chemical Sciences) ; d'Ischia, Marco (University of Naples "Federico II". Department of Chemical Sciences) ; Sedó, Josep (Institut Català de Nanociència i Nanotecnologia) ; Ruiz Molina, Daniel (Institut Català de Nanociència i Nanotecnologia)
The oxidative polymerization of 5,6-dihydroxybenzothiophene (DHBT), the sulfur analog of the key eumelanin building block 5,6-dihydroxyindole (DHI), was investigated to probe the role of nitrogen in eumelanin build-up and properties. [...]
2017 - 10.3390/ijms18102169
International journal of molecular sciences, Vol. 18, Núm. 10 (October 2017) , art. 2169  

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