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30 p, 1.4 MB New bioconjugated rhenium carbonyls by transmetalation reaction with zinc derivatives / Lecina i Veciana, Martí (Universitat Autònoma de Barcelona. Departament de Química) ; Carrer, Alessia (Università di Padova. Dipartimento di Scienze Farmaceutiche) ; Álvarez Larena, Ángel (Universitat Autònoma de Barcelona. Servei de Difracció de Raigs X) ; Mazzi, Ulderico (Università di Padova. Dipartimento di Scienze Farmaceutiche) ; Melendez Alafort, Laura (Istituto Oncologico Veneto) ; Suades Ortuño, Joan (Universitat Autònoma de Barcelona. Departament de Química)
The transmetallation reaction between zinc dithiocarbamates and rhenium carbonyls has been used as a new strategy to link biomolecules to transition metals. The zinc(II) dithiocarbamate of isonipecotic acid (1) and the succinimidyl ester derivative (2) were prepared by straight forward procedures and were fully characterized by spectroscopic and X-ray diffraction methods, showing in both cases the presence of dinuclear complexes. [...]
2012 - 10.1021/om300394v
Organometallics, Vol. 31, Issue 16 (July 2012) , p. 5884-5893  

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