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Articles, 4 records found
Articles 4 records found  
1.
A Self-Folding Polymer Film Based on Swelling Metal–Organic Frameworks / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; León Reina, Laura (Universidad de Málaga) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Cabeza, Aurelio (Universidad de Málaga) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein, we exploit the well-known swelling behaviour of metal–organic frameworks (MOFs) to create a self-folding polymer film. Namely, we show that incorporating crystals of the flexible MOF MIL-88A into a polyvinylidene difluoride (PVDF) matrix affords a polymer composite film that undergoes reversible shape transformations upon exposure to polar solvents and vapours. [...]
2018 - 10.1002/anie.201808433
Angewandte Chemie - International Edition, Vol. 57, Issue 47 (November 2018) , p. 15420-15424  
2.
19 p, 689.5 KB Reversible thermochromic polymeric thin films made of ultrathin 2D crystals of coordination polymers based on copper(I)-thiophenolates / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Castillo, Óscar. (Universidad del País Vasco. Departamento de Química Inorgánica) ; Martínez, José I. (Instituto de Ciencia de Materiales de Madrid) ; Fernández-Moreira, Vanesa (Universidad de Zaragoza. Departamento de Química Inorgánica) ; Ballesteros, Yolanda (Universidad Pontificia Comillas. Departamento de Ingeniería Mecánica) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Zamora, Félix (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Delgado, Salomé (Universidad Autónoma de Madrid. Departamento de Química Inorgánica)
A one-pot reaction between Cu(BF)·xHO and 4-mercaptobenzoic acid in acetone or methanol gives rise to the formation of lamellar microcrystals of two Cu(I)-thiophenolate-based coordination polymers (CPs) with the formulas [CuCT] (1) (CT = 4-carboxy-thiophenolate) and [CuMCT] (2) (MCT = 4-methoxycarbonyl-thiophenolate). [...]
2018 - 10.1002/adfm.201704040
Advanced functional materials, Vol. 28, issue 5 (Jan. 2018) , art. 1704040  
3.
Programmable self-assembling 3D architectures generated by patterning of swellable MOF-based composite films / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Carné Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
The integration of swellable metal–organic frameworks (MOFs) into polymeric composite films is a straightforward strategy to develop soft materials that undergo reversible shape transformations derived from the intrinsic flexibility of MOF crystals. [...]
2019 - 10.1002/adma.201808235
Advanced materials, Vol. 31, issue 21 (May 2019) , art. 1808235  
4.
19 p, 731.1 KB Aqueous production of spherical Zr-MOF beads : via continuous-flow spray-drying / Avci-Camur, Ceren (Institut Català de Nanociència i Nanotecnologia) ; Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; Legrand, Alexandre (Institut Català de Nanociència i Nanotecnologia) ; Farrusseng, David (Université de Lyon) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Porous metal-organic frameworks (MOFs) are attracting great attention from industry, thanks to their myriad potential applications in areas such as catalysis and gas storage. Zr-MOFs (also known as UiO-type MOFs) are especially promising, owing to their large surface areas, high chemical versatility and remarkable hydrothermal, chemical and thermal stabilities. [...]
2018 - 10.1039/c7gc03132g
Green Chemistry, Vol. 20, Núm. 4 (February 2018) , p. 873-878
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1 Troyano, J.
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