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Articles, 6 records found
Articles 6 records found  
1.
Biomimetic synthesis of sub-20 nm covalent organic frameworks in water / Franco, Carlos (ETH Zurich. Department of Chemistry and Applied Biosciences) ; Rodríguez-San-Miguel, David (IFIMAC - Condensed Matter Physics Center) ; Sorrenti, Alessandro (ETH Zurich. Department of Chemistry and Applied Biosciences) ; Sevim, Semih (ETH Zurich. Department of Chemistry and Applied Biosciences) ; Pons, Ramon (Institut de Química Avançada de Catalunya) ; Platero-Prats, Ana Eva (IFIMAC - Condensed Matter Physics Center) ; Pavlovic, Marko (Max-Planck Institute of Colloids and Interfaces. Department of Colloid Chemistry) ; Szilágyi, Istvan (University of Szeged. Department of Physical Chemistry and Materials Science) ; Ruiz Gonzalez, M. Luisa (Universidad Complutense de Madrid. Departamento de Quĺmica Inorgánica) ; González-Calbet, José M. (Universidad Complutense de Madrid. Departamento de Quĺmica Inorgánica) ; Bochicchio, Davide (University of Applied Sciences and Arts of Southern Switzerland. Department of Innovative Technologies) ; Pesce, Luca (University of Applied Sciences and Arts of Southern Switzerland. Department of Innovative Technologies) ; Pavan, Giovanni M. (University of Applied Sciences and Arts of Southern Switzerland. Department of Innovative Technologies) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Cano-Sarabia, Mary (Institut Català de Nanociència i Nanotecnologia) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Pané, Salvador (ETH Zurich. Multi-Scale Robotics Lab) ; De Mello, Andrew J. (ETH Zurich. Department of Chemistry and Applied Biosciences) ; Zamora, Felix (IFIMAC - Condensed Matter Physics Center) ; Puigmarti-Luis, Josep (ETH Zurich. Department of Chemistry and Applied Biosciences)
Covalent organic frameworks (COFs) are commonly synthesized under harsh conditions yielding unprocessable powders. Control in their crystallization process and growth has been limited to studies conducted in hazardous organic solvents. [...]
2020 - 10.1021/jacs.9b12389
Journal of the American Chemical Society, Vol. 142, issue 7 (Feb. 2020) , p. 3540-3547  
2.
Green synthesis of imine-based covalent organic frameworks in water / Martín-Illán, Jesús A. (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Rodríguez-San-Miguel, David (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Franco, Carlos (ETH Zurich. Department of Chemistry and Applied Biosciences) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Puigmartí-Luis, Josep (ETH Zurich. Department of Chemistry and Applied Biosciences) ; Zamora, Félix (Instituto Madrileño de Estudios Avanzados en Nanociencia)
Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield "one-pot"green synthesis of imine-based COFs in water. [...]
2020 - 10.1039/d0cc02033h
Chemical communications, Vol. 56, issue 49 (June 2020) , p. 6704-6707  
3.
7 p, 804.7 KB Confining Functional Nanoparticles into Colloidal Imine-Based COF Spheres by a Sequential Encapsulation-Crystallization Method / Rodríguez-San-Miguel, David (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Yazdi, Amirali (Institut Català de Nanociència i Nanotecnologia) ; Guillerm, Vincent (Institut Català de Nanociència i Nanotecnologia) ; Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; Puntes, Víctor (Institut Català de Nanociència i Nanotecnologia) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Zamora, Félix (Universidad Autónoma de Madrid. Departamento de Química Inorgánica)
Here, a two-step method is reported that enables imparting new functionalities to covalent organic frameworks (COFs) by nanoparticle confinement. The direct reaction between 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-benzenetricarbaldehyde in the presence of a variety of metallic/metal-oxide nanoparticles resulted in embedding of the nanoparticles in amorphous and non-porous imine-linked polymer organic spheres (NP@a-1). [...]
2017 - 10.1002/chem.201702072
Chemistry, Vol. 23, Issue 36 (June 2017) , p. 8623-8627  
4.
7 p, 661.1 KB A MOF@COF Composite with Enhanced Uptake through Interfacial Pore Generation / Garzón Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ; Pérez Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; Yazdi, Amirali (Institut Català de Nanociència i Nanotecnologia) ; Hernández Muñoz, José (Universidad Autónoma de Madrid. Departamento de Física Teórica de la Materia Condensada) ; Tarazona, Pedro (Universidad Autónoma de Madrid. Departamento de Física Teórica de la Materia Condensada) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Zamora, Félix (Instituto Madrileño de Estudios Avanzados en Nanociencia) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein, we describe a new class of porous composites comprising metal-organic framework (MOF) crystals confined in single spherical matrices made of packed covalent-organic framework (COF) nanocrystals. [...]
2019 - 10.1002/anie.201904766
Angewandte Chemie (International ed. Internet), Vol. 58, Issue 28 (July 2019) , p. 9512-9516  
5.
19 p, 689.5 KB Reversible thermochromic polymeric thin films made of ultrathin 2D crystals of coordination polymers based on copper(I)-thiophenolates / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Castillo, Óscar. (Universidad del País Vasco. Departamento de Química Inorgánica) ; Martínez, José I. (Instituto de Ciencia de Materiales de Madrid) ; Fernández-Moreira, Vanesa (Universidad de Zaragoza. Departamento de Química Inorgánica) ; Ballesteros, Yolanda (Universidad Pontificia Comillas. Departamento de Ingeniería Mecánica) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Zamora, Félix (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Delgado, Salomé (Universidad Autónoma de Madrid. Departamento de Química Inorgánica)
A one-pot reaction between Cu(BF)·xHO and 4-mercaptobenzoic acid in acetone or methanol gives rise to the formation of lamellar microcrystals of two Cu(I)-thiophenolate-based coordination polymers (CPs) with the formulas [CuCT] (1) (CT = 4-carboxy-thiophenolate) and [CuMCT] (2) (MCT = 4-methoxycarbonyl-thiophenolate). [...]
2018 - 10.1002/adfm.201704040
Advanced functional materials, Vol. 28, issue 5 (Jan. 2018) , art. 1704040  
6.
5 p, 626.4 KB Spray drying for making covalent chemistry II : synthesis of covalent-organic framework superstructures and related composites / Garzón Tovar, Luis (Institut Català de Nanociència i Nanotecnologia) ; Avci-Camur, Ceren (Institut Català de Nanociència i Nanotecnologia) ; Rodríguez-San-Miguel, David (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Zamora, Félix (Universidad Autónoma de Madrid. Departamento de Química Inorgánica) ; Maspoch, Daniel (Institut Català de Nanociència i Nanotecnologia)
Here we report a method that combines the spray-drying technique with a dynamic covalent chemistry process to synthesize zero-dimensional, spherical and microscale superstructures made from the assembly of imine-based COF nanocrystals. [...]
2017 - 10.1039/c7cc07052g
Chemical communications, Vol. 53, issue 82 (Oct. 2017) , p. 11372-11375
2 documents

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3 Zamora, F.
6 Zamora, Felix
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