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12 p, 1.5 MB Postsynthetic covalent and coordination functionalization of rhodium(II)-based metal-organic polyhedra / Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Albalad, Jorge (Institut Català de Nanociència i Nanotecnologia) ; Grancha, Thais (Institut Català de Nanociència i Nanotecnologia) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Juanhuix, Judith (ALBA Laboratori de Llum de Sincrotró) ; Larpent, Patrick (Kyoto University. Institute for Integrated Cell-Material Science) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Metal-organic polyhedra (MOP) are ultrasmall (typically 1-4 nm) porous coordination cages made from the self-assembly of metal ions and organic linkers and are amenable to the chemical functionalization of its periphery; however, it has been challenging to implement postsynthetic functionalization due to their chemical instability. [...]
2019 - 10.1021/jacs.8b13593
Journal of the American Chemical Society, Vol. 141, issue 9 (March 2019) , p. 4094-4102  

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