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Articles, 5 records found
Articles 5 records found  
1.
12 p, 11.3 MB Influence of the surface chemistry of metal-organic polyhedra in their assembly into ultrathin films for gas separation / Tejedor, Inés (Universidad de Zaragoza. Departamento de Química Física) ; Andrés, Miguel A. (Instituto de Ciencia de Materiales de Aragón) ; Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Arjona, Mónica (Universidad de Zaragoza. Departamento de Química Física) ; Pérez-Miana, Marta (Universidad de Zaragoza. Departamento de Ingeniería Química y Tecnologías del Medio Ambiente) ; Sanchez-Lainez, Javier (Instituto de Nanociencia y Materiales de Aragón) ; Coronas, Joaquin (Instituto de Nanociencia y Materiales de Aragón) ; Fontaine, Philippe (Synchrotron SOLEIL) ; Goldmann, Michel (Synchrotron SOLEIL) ; Roubeau, Olivier (Instituto de Nanociencia y Materiales de Aragón) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia) ; Gascón, Ignacio (Universidad de Zaragoza. Departamento de Química Física)
The formation of ultrathin films of Rh-based porous metal-organic polyhedra (Rh-MOPs) by the Langmuir-Blodgett method has been explored. Homogeneous and dense monolayer films were formed at the air-water interface either using two different coordinatively alkyl-functionalized Rh-MOPs (HRhMOP(diz)and HRhMOP(oiz)) or by in situ incorporation of aliphatic chains to the axial sites of dirhodium paddlewheels of another Rh-MOP (OHRhMOP) at the air-liquid interface. [...]
2022 - 10.1021/acsami.2c06123
ACS applied materials & interfaces, Vol. 14, issue 23 (June 2022) , p. 27495-27506  
Detailed record - Creative Commons
2.
30 p, 2.2 MB Stabilizing edge fluorination in graphene nanoribbons / Panighel, Mirco (Institut Català de Nanociència i Nanotecnologia) ; Peña, Diego (Universidade de Santiago de Compostela. Departamento de Química Orgánica) ; Brandimarte Mendonça, Pedro (Donostia International Physics Center) ; Moreno, Cesar (Institut Català de Nanociència i Nanotecnologia) ; Garcia-Lekue, Aran. (Ikerbasque) ; Vilas-Varela, Manuel (Universidade de Santiago de Compostela. Departamento de Química Orgánica) ; Rey, Dulce (Universidade de Santiago de Compostela. Departamento de Química Orgánica) ; Sauthier, Guillaume (Institut Català de Nanociència i Nanotecnologia) ; Ceballos, Gustavo (Institut Català de Nanociència i Nanotecnologia) ; Peña, Diego (Universidade de Santiago de Compostela. Departamento de Química Orgánica) ; Mugarza, Aitor (Institut Català de Nanociència i Nanotecnologia)
The on-surface synthesis of edge-functionalized graphene nanoribbons (GNRs) is challenged by the stability of the functional groups throughout the thermal reaction steps of the synthetic pathway. Edge fluorination is a particularly critical case in which the interaction with the catalytic substrate and intermediate products can induce the complete cleavage of the otherwise strong C-F bonds before the formation of the GNR. [...]
2020 - 10.1021/acsnano.0c01837
ACS nano, Vol. 14, issue 9 (Sep. 2020) , p. 11120-11129  
Detailed record -
3.
17 p, 1.3 MB Porous materials as carriers of gasotransmitters towards gas biology and therapeutic applications / Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Carmona Fernández, Francisco Jesús (Kyoto University. Institute for Integrated Cell-Material Sciences) ; Kim, Chiwon (Kyoto University. Institute for Integrated Cell-Material) ; Furukawa, Shuhei (Kyoto University. Department of Synthetic Chemistry and Biological Chemistry)
The discovery of NO, CO, and H2S as gasotransmitters and their beneficial role in multiple physiological functions opened an era of research devoted to exogenously delivering them as therapeutic agents. [...]
2020 - 10.1039/d0cc03740k
Chemical communications, Vol. 56, issue 68 (Sep. 2020) , p. 9750-9766  
Detailed record -
4.
8 p, 855.0 KB Covalent Grafting of Coordination Polymers on Surfaces : The Case of Hybrid Valence Tautomeric Interphases / Gonzalez Monje, Pablo (Institut Català de Nanociència i Nanotecnologia) ; Novio Vázquez, Fernando (Institut Català de Nanociència i Nanotecnologia) ; Ruiz-Molina, Daniel (Institut Català de Nanociència i Nanotecnologia)
We have developed a novel approach for grafting coordination polymers, structured as nanoparticles bearing surface reactive carboxylic groups, to amino-functionalized surfaces through a simple carbodiimide-mediated coupling reaction. [...]
2015 - 10.1002/chem.201500671
Chemistry, Vol. 21, Issue 28 (July 2015) , p. 10094-10099  
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5.
26 p, 4.4 MB Surface cis Effect : Influence of an Axial Ligand on Molecular Self-Assembly / Knaak, Thomas (Christian-Albrechts-Universität zu Kiel (Alemanya)) ; Gopakumar, Thiruvancheril G. (Indian Institute of Technology Kanpur) ; Schwager, Bettina (Christian-Albrechts-Universität zu Kiel (Alemanya)) ; Tuczek, Felix (Christian-Albrechts-Universität zu Kiel (Alemanya)) ; Robles, Roberto (Institut Català de Nanociència i Nanotecnologia) ; Lorente Palacios, Nicolás (Centro de Física de Materiales (Sant Sebastià, País Basc)) ; Berndt, Richard (Christian-Albrechts-Universität zu Kiel (Alemanya))
Adding ligands to molecules can have drastic and unforeseen consequences in the final products of a reaction. Recently a surface trans effect due to the weakening of a molecule-surface bond was reported. [...]
2016 - 10.1021/jacs.6b03710
Journal of the American Chemical Society, Vol. 138, Núm. 24 (June 2016) , p. 7544-7550  
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