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5 p, 2.3 MB Ligand Migration from Cluster to Support : A Crucial Factor for Catalysis by Thiolate-protected Gold Clusters / Zhang, Bei (University of Geneva) ; Sels, Annelies (University of Geneva) ; Salassa, Giovanni (University of Geneva) ; Pollitt, Stephan (Technische Universität Wien) ; Truttmann, Vera (Technische Universität Wien) ; Rameshan, Christoph (Technische Universität Wien) ; Llorca, Jordi (Universitat Politècnica de Catalunya. Institut de Tècniques Energètiques) ; Olszewski, Wojciech (ALBA Laboratori de Llum de Sincrotró) ; Rupprechter, Günther (Technische Universität Wien) ; Bürgi, Thomas (University of Geneva) ; Barrabés, Noelia (Technische Universität Wien)
Thiolate protected metal clusters are valuable precursors for the design of tailored nanosized catalysts. Their performance can be tuned precisely at atomic level, e. g. by the configuration/type of ligands or by partial/complete removal of the ligand shell through controlled pre-treatment steps. [...]
2018 - 10.1002/cctc.201801474
ChemCatChem, Vol. 10, Issue 23 (December 2018) , p. 5372-5376  

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