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9 p, 625.2 KB A Self-Folding Polymer Film Based on Swelling Metal-Organic Frameworks / Troyano, Javier (Institut Català de Nanociència i Nanotecnologia) ; Carné-Sánchez, Arnau (Institut Català de Nanociència i Nanotecnologia) ; Pérez-Carvajal, Javier (Institut Català de Nanociència i Nanotecnologia) ; León Reina, Laura (Universidad de Málaga) ; Imaz, Inhar (Institut Català de Nanociència i Nanotecnologia) ; Cabeza, Aurelio (Universidad de Málaga) ; Maspoch Comamala, Daniel (Institut Català de Nanociència i Nanotecnologia)
Herein, we exploit the well-known swelling behaviour of metal-organic frameworks (MOFs) to create a self-folding polymer film. Namely, we show that incorporating crystals of the flexible MOF MIL-88A into a polyvinylidene difluoride (PVDF) matrix affords a polymer composite film that undergoes reversible shape transformations upon exposure to polar solvents and vapours. [...]
2018 - 10.1002/anie.201808433
Angewandte Chemie (International ed. Internet), Vol. 57, Issue 47 (November 2018) , p. 15420-15424  
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